Bonding of substrates induced by ionizing radiation

Patent metadata

Field	Value
Publication number	US-10974493-B2
Application number	US-201815896654-A
Country	US
Kind code	B2
Filing date	Feb 14, 2018
Priority date	Dec 11, 2012
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

A reactive polymer composition is provided, containing a (co)polymer that forms one or more reactive moities, either directly or indirectly, upon application of an ionizing radiation; and a multifunctional curing coagent, along with systems and methods for bonding substrates to one another using such a composition.

First claim

The invention claimed is:

1. A system for bonding materials having different coefficients of thermal expansion, comprising:
a first substrate having at least one surface containing a first reactive polymer composition;
a second substrate, optionally having at least one surface containing a second reactive polymer composition;
wherein the first substrate and the second substrate are different from one another and have different coefficients of thermal expansion from one another, wherein the first reactive polymer composition and the second reactive polymer composition may be the same or different, and each comprises a (co)polymer that forms one or more reactive moieties selected from the group consisting of free-radicals, cations, anions, carbenes, and nitrenes, either directly or indirectly, upon application of an ionizing radiation and a multifunctional curing coagent to reduce oxygen inhibition, minimize or curb chain scission, or both, wherein the multifunctional curing coagent is a di-, tri-, or tetra-functional alcohol compound; and
a source of ionizing radiation.

2. The system of claim 1 , wherein the one or more reactive moieties are one or more free-radicals.

3. The system of claim 1 , wherein the alcohol compound is a tetra-functional alcohol.

4. The system of claim 1 , wherein the first reactive polymer composition comprises a (co)polymer formed from one or more monomers selected from the group consisting of acrylates, methacrylates, olefins, ethers, styrenes, fluoroolefins, esters, carbonates, urethanes, vinyl chlorides, vinyl chloride acetates, amides, imides, acetals, methylpentenes, sulfones, acrylics, styrene acrylics, and acrylonitriles.

5. A method for bonding materials having different coefficients of thermal expansion, comprising:
providing a first substrate and a second substrate to be bonded together, wherein the first and second substrates are different from one another and have different coefficients of thermal expansion from one another;
providing a first reactive polymer composition comprising a (co)polymer that forms one or more reactive moieties selected from the group consisting of free-radicals, cations, anions, carbenes, and nitrenes, either directly or indirectly, upon application of an ionizing radiation and a multifunctional curing coagent to reduce oxygen inhibition, minimize or curb chain scission, or both, wherein the multifunctional curing coagent is a di-, tri-, or tetra-functional alcohol compound, wherein the first reactive polymer composition is in contact with at least one of the first and second substrates;
placing the first and second substrates in close proximity to one another; and
applying the ionizing radiation, thus forming the one or more reactive moieties in the first reactive polymer composition which react to form a bond between the first and second substrates.

6. The method of claim 5 , wherein the one or more reactive moieties are one or more free-radicals.

7. The method of claim 5 , wherein the alcohol compound is a tetra-functional alcohol.

8. The method of claim 5 , wherein the first reactive polymer composition comprises a (co)polymer formed from one or more monomers selected from the group consisting of acrylates, methacrylates, olefins, ethers, styrenes, fluoroolefins, esters, carbonates, urethanes, vinyl chlorides, vinyl chloride acetates, amides, imides, acetals, methylpentenes, sulfones, acrylics, styrene acrylics, and acrylonitriles.

9. A method for bonding materials having different coefficients of thermal expansion, comprising:
providing a first substrate and a second substrate to be bonded together, wherein the first and second substrates are different from one another and have different coefficients of thermal expansion from one another;
providing a first reactive polymer composition comprising a (co)polymer that forms one or more reactive moieties selected from the group consisting of free-radicals, cations, anions, carbenes, and nitrenes, either directly or indirectly, upon application of an ionizing radiation and a multifunctional curing coagent to reduce oxygen inhibition, minimize or curb chain scission, or both, wherein the multifunctional curing coagent is a di-, tri-, or tetra-functional alcohol compound;
placing the first and second substrates in close proximity to one another and having the first reactive polymer composition therebetween; and
applying the ionizing radiation, thus forming the one or more reactive moieties in the first reactive polymer composition which react to form a bond between the first and second substrates.

10. The method of claim 9 , wherein the one or more reactive moieties are one or more free-radicals.

11. The method of claim 9 , wherein the alcohol compound is a tetra-functional alcohol.

12. The method of claim 9 , wherein the first reactive polymer composition comprises a (co)polymer formed from one or more monomers selected from the group consisting of acrylates, methacrylates, olefins, ethers, styrenes, fluoroolefins, esters, carbonates, urethanes, vinyl chlorides, vinyl chloride acetates, amides, imides, acetals, methylpentenes, sulfones, acrylics, styrene acrylics, and acrylonitriles.

Assignees

• Immunolight Llc

Inventors

• Fathi Zakaryae

Classifications

• C09J5/00 Primary

  Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers · CPC title

• C09J2301/416

  use of irradiation · CPC title

• B32B2310/0881

  using ion-radiation, e.g. alpha-rays · CPC title

• B32B37/12

  characterised by using adhesives · CPC title

• C09J133/12

  Homopolymers or copolymers of methyl methacrylate · CPC title