Process for combustion coke from coked catalyst

Patent metadata

Field	Value
Publication number	US-10974238-B2
Application number	US-201816039091-A
Country	US
Kind code	B2
Filing date	Jul 18, 2018
Priority date	Mar 31, 2016
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

A counter-current catalyst regenerator with at least two stages of counter-current contact is proposed. Each stage may comprise a permeable barrier that allows upward passage of oxygen-containing gas and downward passage of coked catalyst into each stage, but inhibits upward movement of catalyst to mitigate back mixing and approximate true counter-current contact and efficient combustion of coke from catalyst.

First claim

The invention claimed is:

1. A process for combusting coke from coked catalyst comprising:
passing a first stream of coked catalyst downwardly through a first permeable barrier into a first stage;
propelling a first stream of oxygen-containing gas upwardly through said first stage in counter-current contact with said first stream of coked catalyst to combust coke from said first stream of coked catalyst to provide a second stream of coked catalyst including regenerated catalyst and a stream of flue gas;
propelling said stream of flue gas upwardly from said first stage; inhibiting upward movement of said first stream of coked catalyst in said first stage;
passing said second stream of coked catalyst downwardly from said first stage to a second stage below said first stage;
propelling a second stream of oxygen-containing gas upwardly through said second stage in counter-current contact with said second stream of coked catalyst to combust coke from said second stream of coked catalyst to provide a third stream of coked catalyst including regenerated catalyst and said first stream of oxygen-containing gas including flue gas; and
propelling said first stream of oxygen-containing gas from said second stage to said first stage; and inhibiting upward movement of said second stream of coked catalyst in said second stage.

2. The process of claim 1 wherein said first permeable barrier inhibits upward movement of said first stream of coked catalyst in said first stage.

3. The process of claim 2 wherein a second permeable barrier inhibits upward movement of said second stream of coked catalyst in said second stage.

4. The process of claim 3 wherein said second permeable barrier is spaced below said first permeable barrier.

5. The process of claim 1 further comprising delivering said first stream of coked catalyst above said first stage and distributing said second stream of oxygen-containing gas below said second stage.

6. The process of claim 1 further comprising discharging said stream of flue gas from a flue gas outlet above said first stage and removing a stream of regenerated catalyst from an outlet below said second stage.

7. The process of claim 1 further comprising:
passing said third stream of coked catalyst downwardly from said second stage to a third stage below said second stage;
propelling a third stream of oxygen-containing gas upwardly through said third stage in counter-current contact with said stream of coked catalyst to combust coke from said coked catalyst to provide a fourth stream of coked catalyst comprising regenerated catalyst and said second stream of oxygen-containing gas including flue gas; and
inhibiting upward movement of said third stream of coked catalyst in said third stage.

8. The process of claim 1 wherein a CO 2 to CO ratio is smaller in the first stage than in the second stage.

9. The process of claim 1 further comprising cooling a stream of coked catalyst and delivering cooled catalyst at or below said first stage.

10. The process of claim 1 further comprising feeding fresh oxygen-containing gas to said first stage separately from said first stream of oxygen-containing gas from said second stage.

11. A process for combusting coke from coked catalyst comprising:
passing a first stream of coked catalyst downwardly through a first permeable barrier defining a first stage;
propelling a first stream of oxygen-containing gas upwardly through said first stage in counter-current contact with said first stream of coked catalyst to combust coke from said first stream of coked catalyst to provide a second stream of coked catalyst including regenerated catalyst and a stream of flue gas;
propelling said stream of flue gas upwardly from said first stage through said first permeable barrier;
inhibiting upward movement of said first stream of coked catalyst in said first stage by said first permeable barrier;
passing said second stream of coked catalyst downwardly from said first stage through a second permeable barrier to a second stage, said second permeable barrier defining said second stage below said first stage;
propelling a second stream of oxygen-containing gas upwardly through said second stage in counter-current contact with said second stream of coked catalyst to combust coke from said second stream of coked catalyst to provide a third stream of coked catalyst including regenerated catalyst and said first stream of oxygen-containing gas including flue gas;
propelling said first said stream of oxygen-containing gas through said second permeable barrier from said second stage to said first stage; and
inhibiting upward movement of said second stream of coked catalyst in said second stage by said second permeable barrier.

12. The process of claim 11 wherein said second permeable barrier is spaced below said first permeable barrier.

13. The process of claim 11 further comprising delivering said first stream of coked catalyst above said first permeable barrier and distributing said second stream of oxygen-containing gas below said second stage.

14. The process of claim 11 further comprising: passing said third stream of coked catalyst downwardly from said second stage through a third permeable barrier to a third stage below said second stage, said third permeable barrier defining said third stage below said second stage; propelling a third stream of oxygen-containing gas upwardly through said third stage in counter-current contact with said third stream of coked catalyst to combust coke from said coked catalyst to provide a fourth stream of coked catalyst comprising regenerated catalyst and said second stream of oxygen-containing gas including flue gas; and inhibiting upward movement of said third stream of coked catalyst in said third stage by said third permeable barrier.

15. The process of claim 14 wherein said third permeable barrier is spaced below said second permeable barrier.

Assignees

• Uop Llc

Inventors

• Fei Zhihao
• Wolschlag Lisa M
• Hedrick Brian W

Classifications

• B01J38/34 Primary

  with plural distinct serial combustion stages · CPC title

• B01J8/008

  Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction (B01J8/0285, B01J8/067, B01J8/087, B01J8/1836 take precedence) · CPC title

• B01J2208/00769

  Details of feeding or discharging · CPC title

• B01J8/003

  in a downward flow · CPC title

• B01J38/04

  Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst · CPC title