Catalytic process for oxidative coupling of methane

Patent metadata

Field	Value
Publication number	US-10974226-B2
Application number	US-201916579024-A
Country	US
Kind code	B2
Filing date	Sep 23, 2019
Priority date	Sep 24, 2018
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

Supported oxidative coupling of methane (OCM) catalysts, methods of making the catalysts, and uses thereof are described. A supported OCM) catalyst can include a nonporous inert support having a high thermal conductivity and an OCM mixed metal oxide material in contact with surface of the nonporous inert support.

First claim

The invention claimed is:

1. A supported oxidative coupling of methane (OCM) catalyst comprising:
a nonporous inert support having a high thermal conductivity; and
an OCM mixed metal oxide material in contact with a surface of the nonporous inert support;
wherein the nonporous inert support has a thermal conductivity of 55 to 500 W/m-K; and
wherein the nonporous inert support is in particulate form and has a particle size of 300 to 500 micrometers.

2. The supported OCM catalyst of claim 1 , wherein the OCM mixed metal oxide material is a p-type semiconductor material.

3. The supported OCM catalyst of claim 1 , wherein the nonporous inert support has a thermal conductivity of 75 to 300 W/m-K.

4. The supported OCM catalyst of claim 1 , wherein the nonporous inert support comprises nonporous silicon carbide.

5. The supported OCM catalyst of claim 4 , wherein the silicon carbide has a thermal conductivity of 50 to 200 W/m-K.

6. The supported OCM catalyst of claim 1 , wherein the nonporous inert support has a thermal conductivity of 100 to 200 W/m-K.

7. The supported OCM catalyst of claim 1 , wherein the OCM mixed metal oxide material forms a layer that covers at least a portion of the surface of the nonporous inert support, and wherein the metal oxide layer is from 0.1 to up to 100 microns thick.

8. The supported OCM catalyst of claim 1 , wherein the OCM mixed metal oxide material comprises at least one lanthanide doped with at least one of a Column 2 metal, a Column 4 metal, a Column 13 metal, or any oxide thereof.

9. The supported OCM catalyst of claim 1 , wherein the OCM mixed metal oxide comprises a lanthanide doped with a column 2 metal.

10. The supported OCM catalyst of claim 9 , wherein the lanthanide is selected from the group consisting of lanthanum (La), cerium (Ce), ytterbium (Yb), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho) and erbium (Er), or oxides thereof, or any combination thereof.

11. The supported OCM catalyst of claim 9 , wherein the a Column 2 metal is strontium.

12. The supported OCM catalyst of claim 9 , wherein the silicon carbide is nonporous and has a thermal conductivity of 50 to 200 W/m-K.

13. The supported OCM catalyst of claim 1 , wherein the nonporous inert support comprises silicon carbide.

14. The supported OCM catalyst of claim 13 , wherein the OCM mixed metal oxide material has a fluorite type structure, a spinel type structure, a brownmillerite type structure or a pyrochlore type structure.

15. The supported OCM catalyst of claim 1 , wherein OCM the mixed metal oxide material comprises nanoparticles having a particle size of 0.1 micrometers to 10 micrometers.

16. The supported OCM catalyst of claim 1 , wherein the OCM mixed metal oxide material does not include n-type semiconductor material.

17. The supported OCM catalyst of claim 1 , wherein the nonporous inert support is in particulate form and has a particle size of 300 to 500 micrometers.

18. A supported oxidative coupling of methane (OCM) catalyst comprising:
a nonporous inert support having a high thermal conductivity; and
an QCM mixed metal oxide material in contact with a surface of the nonporous inert support;
wherein the nonporous inert support has a thermal conductivity of 55 to 500 W/m-K and wherein the OCM mixed metal oxide material comprises SrLa0.9Yb0.1Nd0.70δ, where δ is a number that varies such that the catalyst is charge neutral.

19. A method of preparing the oxidative coupling of methane (OEM) catalyst of claim 1 , the method comprising:
contacting the OCM mixed metal oxide material with the nonporous inert support to form a supported OCM mixed metal oxide material; and
heat-treating the supported OCM mixed metal oxide material under conditions sufficient to form the supported OEM catalyst.

20. A process for the oxidative coupling of methane (OCM), the process comprising contacting a reactant feed comprising methane (CH4) with the OCM catalyst of claim 1 in the presence of an oxidant to produce a product stream comprising C 2+ hydrocarbons.

Assignees

• Sabic Global Technologies Bv

Inventors

• Schucker Robert C
• Gautam Pankaj S
• Derrickson Katarzyna
• Nguyen Hoang

Classifications

• B01J35/45

  Nanoparticles · CPC title

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J23/10 Primary

  of rare earths · CPC title

• C07C2521/06

  Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof · CPC title