Method for producing water absorbent resin

Patent metadata

Field	Value
Publication number	US-10974223-B2
Application number	US-201616066509-A
Country	US
Kind code	B2
Filing date	Dec 28, 2016
Priority date	Dec 28, 2015
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

[Object] To provide a method for producing a water-absorbent resin in powder form or particle form, which has excellent physical properties such as water absorption performance and the like, at high productivity.
[Solution] A method for producing a water-absorbent resin includes: a polymerization step of polymerizing a monomer, which is a raw material of the water-absorbent resin, to obtain a hydrous gel crosslinked polymer dispersed in an organic solvent; and a separation step of separating the organic solvent and the hydrous gel crosslinked polymer. The separation step includes transfer, compression, and discharge of the hydrous gel crosslinked polymer.

First claim

The invention claimed is:

1. A method for producing a water-absorbent resin comprising:
a polymerization step of polymerizing a monomer, which is a raw material of the water-absorbent resin, to obtain a hydrous gel crosslinked polymer dispersed in an organic solvent; and
a separation step of separating the organic solvent and the hydrous gel crosslinked polymer from each other, wherein
the separation step includes transfer, compression, and discharge of the hydrous gel crosslinked polymer by a discharge device having an input port receiving said hydrous gel crosslinked polymer dispersed in the organic solvent and a discharge port for discharging the hydrous gel crosslinked polymer, wherein the hydrous gel crosslinked polymer is transferred from the input port to the discharge port, and the organic solvent is transferred in a direction opposite a direction of transfer of the hydrous gel crosslinked polymer from the discharge port toward the input port, and the hydrous gel crosslinked polymer discharged in the separation step has a residual liquid ratio of not greater than 10% by mass.

2. The method according to claim 1 , wherein, in the separation step, the hydrous gel crosslinked polymer is squeezed while being transferred.

3. The method according to claim 1 , wherein the compression in the separation step is to apply a pressure of not less than 0.1 MPa to the hydrous gel crosslinked polymer.

4. The method according to claim 1 , wherein, in the separation step, a screw extruder including a screw having a compression ratio of not less than 1.5 is used.

5. The method according to claim 1 , wherein the organic solvent contains a surfactant and/or a polymeric dispersing agent.

6. The method according to claim 1 , wherein the organic solvent separated in the separation step is reused in the polymerization step.

7. The method according to claim 1 , wherein a reaction device is used in the polymerization step of obtaining the hydrous gel crosslinked polymer and in the separation step of separating the organic solvent and the hydrous gel crosslinked polymer from each other, and where said reaction device comprises the discharge device capable of transferring, compressing and discharging the hydrous gel crosslinked polymer.

8. The method of claim 1 , further comprising adjusting a pressure applied to the hydrous gel crosslinked polymer at the discharge port of the discharge device by an adjustment mechanism.

9. The method of claim 1 , wherein the residual liquid ratio of the hydrous gel crosslinked polymer is not less than 0.5% by mass and not greater than 10% by mass.

10. The method of claim 1 , wherein the residual liquid ratio is calculated according to the following formula after extracting the organic solvent in the hydrous gel crosslinked polymer with ethyl acetate and measuring the concentration of the organic solvent in ethyl acetate by gas chromatography:
R= 100× s×A/M

wherein R is the residual liquid ratio (% by mass), s is the concentration of the organic solvent in the ethyl acetate (g/L), M is the mass of the hydrous gel (g) and A is the volume of the ethyl acetate used for extraction (L).

11. The method of claim 1 , wherein a solid content ratio of the hydrous gel crosslinked polymer discharged in the separation step is not less than 20% by mass and not greater than 80% by mass.

12. The method of claim 1 , wherein a ratio W/O of a volume W of a monomer composition containing the monomer as a main component to a volume O of the organic solvent is 1% by volume to 40% by volume.

Assignees

• Nippon Catalytic Chem Ind

Inventors

• SHUTO Tokio
• Imura Motohiro
• Fujino Shin-Ichi
• Honda Koji
• Wakabayashi Ryota

Classifications

• B29B9/12

  characterised by structure or composition · CPC title

• B29B9/06

  in the form of filamentary material, e.g. combined with extrusion · CPC title

• B29B7/726

  Measuring properties of mixture, e.g. temperature or density (B29B7/724 takes precedence) · CPC title

• B29B7/484

  with two shafts provided with screws, e.g. one screw being shorter than the other (B29B7/482 takes precedence) · CPC title

• B29B7/424

  with conical screw surrounded by conical casing · CPC title