Ceramic membrane filter and method for producing the same

Patent metadata

Field	Value
Publication number	US-10974203-B2
Application number	US-201816142474-A
Country	US
Kind code	B2
Filing date	Sep 26, 2018
Priority date	Mar 30, 2016
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

A ceramic membrane filter includes a porous substrate including cells through which a fluid flows, an intermediate membrane formed on the porous substrate, and a separation membrane formed on the intermediate membrane. In this ceramic membrane filter, the percentage of the number of cells having cracks with a size of 4 μm or less relative to the total number of cells is 9% or less.

First claim

What is claimed is:

1. A ceramic membrane filter comprising:
a substrate including cells through which a fluid flows;
an intermediate membrane formed on the substrate; and
a separation membrane formed on the intermediate membrane,
wherein a percentage of the number of cells having cracks with a size of 4 μm or less relative to the total number of cells is 9% or less.

2. The ceramic membrane filter according to claim 1 , wherein an initial bubbling pressure in water is 0.08 MPa or more and a percentage of the number of bubbling cells relative to the total number of cells is 9% or less.

3. The ceramic membrane filter according to claim 1 , wherein the separation membrane has an average thickness of 5 μm or more and 20 μm or less.

4. The ceramic membrane filter according to claim 1 , wherein the intermediate membrane has an average thickness of 120 μm or more and 450 μm or less.

5. The ceramic membrane filter according to claim 1 , wherein the intermediate membrane has an average pore size of 0.1 μm or more and 0.6 μm or less.

6. The ceramic membrane filter according to claim 1 , wherein the intermediate membrane contains aluminum oxide or titanium oxide as a main raw material and contains clay or titanium oxide as a sintering agent.

7. The ceramic membrane filter according to claim 1 , wherein the intermediate membrane has an average thickness of 170 μm or more and 450 μm or less.

8. The ceramic membrane filter according to claim 7 , wherein the intermediate membrane is a single layer.

9. The ceramic membrane filter according to claim 1 , wherein the intermediate membrane is a single layer.

10. A method for producing a ceramic membrane filter, the method comprising:
a formation step of forming a raw material layer for an intermediate membrane on a substrate using a raw material slurry prepared by mixing an organic binder, a ceramic raw material, and a solvent, the organic binder containing a dry crack inhibitor that is a resin having a chain structure and a molecular weight of 1000 or less, a deflocculant, and a polysaccharide compound,
wherein in the formation step, the raw material layer is formed so as to have an average thickness of 150 μm or more and 480 μm or less by adding the dry crack inhibitor in an amount of 0.20 parts by mass or more and 0.95 parts by mass or less relative to 100 parts by mass of the ceramic raw material, adding the deflocculant in an amount of 0.15 parts by mass or more and 0.25 parts by mass or less relative to 100 parts by mass of the ceramic raw material, and adding the polysaccharide compound in an amount of 0.95 parts by mass or less relative to 100 parts by mass of the ceramic raw material to prepare the raw material slurry,
wherein a separation membrane is formed on the intermediate membrane; and
wherein the ceramic membrane filter has a percentage of the number of cells having cracks with a size of 4 μm or less relative to the total number of cells is 9% or less.

11. The method for producing a ceramic membrane filter according to claim 10 , wherein in the formation step, the polysaccharide compound is added in an amount of 0.2 parts by mass or more and 0.95 parts by mass or less relative to 100 parts by mass of the ceramic raw material.

12. The method for producing a ceramic membrane filter according to claim 10 , wherein in the formation step, a main raw material and a sintering agent are used as the ceramic raw material.

13. The method for producing a ceramic membrane filter according to claim 10 , wherein in the formation step, at least one of clay and titanium oxide is used as the sintering agent.

14. The method for producing a ceramic membrane filter according to claim 10 , wherein in the formation step, a main raw material and a sintering agent are used as the ceramic raw material, and titanium oxide is used as the sintering agent in an amount of 1 mass % or more and 35 mass % or less relative to the total amount of the ceramic raw material.

15. The method for producing a ceramic membrane filter according to claim 10 , wherein in the formation step, polyvinyl alcohol is used as the dry crack inhibitor.

16. The method for producing a ceramic membrane filter according to claim 10 , wherein in the formation step, the ceramic raw material contains aluminum oxide or titanium oxide as a main raw material.

17. The method for producing a ceramic membrane filter according to claim 10 , wherein in the formation step, the ceramic raw material is prepared by mixing a first main raw material A having a first particle size that is an average particle size and a second main raw material B having a second particle size that is an average particle size and is smaller than the first particle size at a mass ratio A/B of 0.6 or more and 2 or less.

Assignees

• Ngk Insulators Ltd

Inventors

• Hieda koji
• Iwabuchi Muneyuki

Classifications

• B01D71/02 Primary

  Inorganic material · CPC title

• B01D2325/02834

  more than 0.1 and up to 1 µm · CPC title

• B01D69/108

  Inorganic support material · CPC title

• B01D69/02 Primary

  characterised by their properties · CPC title

• C04B41/90

  at least one coating being a metal · CPC title