Composition for removing radionuclide and method for removing radionuclide using the same

Patent metadata

Field	Value
Publication number	US-10971276-B2
Application number	US-201815928697-A
Country	US
Kind code	B2
Filing date	Mar 22, 2018
Priority date	Nov 6, 2017
Publication date	Apr 6, 2021
Grant date	Apr 6, 2021

Abstract

The present invention relates to a composition for removing a radionuclide, including: a first polymer including a hydroxy group; a second polymer into which a boronic acid group is introduced as a functional group; and an adsorbent for removing the radionuclide, and a method for removing a radionuclide using the same.

First claim

What is claimed is:

1. A method for removing a radionuclide, the method comprising:
(a) preparing a first aqueous solution containing a first polymer comprising a hydroxy group;
(b) preparing a second aqueous solution containing a second polymer into which a boronic acid group is introduced as a functional group via a covalent bond;
(c) forming a reversibly cross-linked hydrogel in which the radionuclide is adsorbed by spraying or applying each of the first solution and the second solution onto a radionuclide-contaminated surface, and then reversibly cross-linking the first polymer and the second polymer to each other via a dehydration condensation reaction under a pH condition of 5 to 12, wherein the boronic acid group is in an anionic state, and wherein a borate-ester bond is formed between the first polymer and the second polymer from the hydroxy group and the boronic acid group; and
(d) selectively dissolving only the hydrogel by disintegrating the cross-linking via an immersion of the hydrogel in which the radionuclide is adsorbed in water,
wherein an adsorbent for removing the radionuclide is further contained in the first solution or the second solution,
wherein in step (c), at a frequency of 100 rad/s, the hydrogel in which the radionuclide is adsorbed has a storage modulus of 2,000 Pa to 10,000 Pa and a loss modulus of 100 Pa to 5,000 Pa.

2. The method of claim 1 , wherein in step (c), the hydrogel in which the radionuclide is adsorbed is formed, and then a monovalent, divalent or trivalent ion solution for being additionally cross-linked to the second polymer is further sprayed.

3. The method of claim 1 , wherein the first polymer is one or more selected from a group consisting of polyvinyl alcohol, arabic gum, guar gum, locust bean gum, and a derivative thereof.

4. The method of claim 1 , wherein the second polymer comprises a skeleton comprising a carboxyl group or a carbonyl group.

5. The method of claim 4 , wherein the skeleton is one or more selected from a group consisting of an alginate, poly(succinimide), poly(methyl vinyl ether-alt-maleic anhydride), polyacrylic acid, polyacrylamide, poly(N,N-dimethylacrylamide), and polyvinylpyrrolidone.

6. The method of claim 1 , wherein the hydrogel comprises the first polymer and the second polymer in an amount of 3 parts by weight to 10 parts by weight and 1 part by weight to 5 parts by weight, respectively, based on 100 parts by weight of the hydrogel.

Assignees

• Korea Atomic Energy Res

Inventors

• Hee-Man Yang
• Park Chanwoo
• Kune-Woo Lee
• Kim Ilgook
• Yoon In-Ho
• Seo Bumkyoung

Classifications

• B01D71/40

  Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters · CPC title

• B01D71/381

  Polyvinylalcohol · CPC title

• C08F220/54

  Amides {, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide} · CPC title

• C08F220/56

  Acrylamide; Methacrylamide · CPC title

• G21F9/001

  Decontamination of contaminated objects, apparatus, clothes, food; Preventing contamination thereof · CPC title