Blue phases on patterned surfaces

Patent metadata

Field	Value
Publication number	US-10969642-B2
Application number	US-201816048891-A
Country	US
Kind code	B2
Filing date	Jul 30, 2018
Priority date	Jul 30, 2017
Publication date	Apr 6, 2021
Grant date	Apr 6, 2021

Abstract

Stable, macroscopic single-crystal chiral liquid crystal compositions are described. The compositions include a single-crystal chiral liquid crystal material on a patterned surface. The patterned surface seeds a particular crystallographic orientation at the substrate-liquid crystal interface. Also described are methods of forming the single-crystal chiral liquid crystal compositions.

First claim

What is claimed is:

1. An article, comprising:
a substrate having a surface, wherein the surface is patterned with a surface pattern that extends over a first area; and
a monocrystalline liquid crystalline material that extends over the first area wherein the surface pattern comprises regions that induce planar orientation of molecules in the monocrystalline liquid crystalline material and regions that induce homeotropic orientation of molecules in the monocrystalline liquid crystalline material.

2. The article of claim 1 , wherein the monocrystalline liquid crystalline material is a blue phase liquid crystal.

3. The article of claim 1 , wherein the monocrystalline material is a cholesteric liquid crystal.

4. The article of claim 1 , wherein the surface pattern is a stripe pattern or a hexagonal array.

5. The article of claim 1 , wherein the first area is at least 1 mm 2 .

6. The article of claim 1 , wherein the monocrystalline material is at least 20 μm thick.

7. The article of claim 1 , wherein the surface pattern is a periodic pattern characterized by a pattern period L s , wherein the surface pattern is a pattern of stripes, the pattern period L s is the width of two adjacent stripes, and the pattern period L s is equal to the lattice constant of a unit cell of the monocrystalline liquid crystalline material.

8. The article of claim 1 , wherein the surface pattern is a periodic pattern characterized by a pattern period L s , wherein the surface pattern is a hexagonal array of features, the pattern period L s is the center-to-center distance of adjacent features, and the pattern period L s is equal to the square root of two times the lattice constant of a unit cell of the monocrystalline liquid crystalline material.

9. The article of claim 1 , wherein the surface comprises a second surface pattern that extends over a second area and a monocrystalline liquid crystalline material that extends over the second area, wherein the monocrystalline liquid crystalline material that extends over the first area has a first unit cell orientation, the monocrystalline liquid material that extends over the second area has a second unit cell orientation and is separated by the monocrystalline liquid material that extends over the first area by a single defect line.

10. The article of claim 1 , wherein the monocrystalline liquid crystalline material overlies a surface that comprises patterned regions separated by an unpatterned region.

11. A liquid crystal cell comprising:
the article of claim 1 , wherein the surface is a first substrate surface;
a second substrate having a second substrate surface,

wherein the monocrystalline liquid crystalline material is disposed between the and second substrate surfaces.

12. The liquid crystal cell of claim 11 , wherein the second substrate surface is homogenous.

13. The liquid crystal cell of claim 11 , wherein the second substrate surface has a second surface pattern.

14. The liquid crystal cell of claim 11 , wherein the surface pattern is co-extensive with the first substrate surface.

15. The liquid crystal cell of claim 11 , further comprising electrodes on the substrate and the second substrate.

16. The article of claim 1 , wherein the monocrystalline liquid crystalline material is switchable on application of an external field.

17. The article of claim 1 , wherein the surface pattern comprises a polymer brush or self-assembled monolayer.

18. The article of claim 1 , wherein the surface pattern relieves elastic distortions that would be induced by a homogenous surface.

Assignees

• Univ Chicago

Inventors

• De Pablo Juan Jose
• Nealey Paul Franklin
• Li Xiao
• Martinez-Gonzalez Jose A
• Sadati Monirosadat
• Zhang Rui
• Zhou Ye

Classifications

• G02F1/137 Primary

  characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering · CPC title

• G02F1/1393 Primary

  the birefringence of the liquid crystal being electrically controlled, e.g. ECB-, DAP-, HAN-, PI-LC cells (G02F1/1396, G02F1/141 take precedence) · CPC title

• G02F1/1396

  the liquid crystal being selectively controlled between a twisted state and a non-twisted state, e.g. TN-LC cell (G02F1/141 takes precedence) · CPC title

• C09K19/00

  Liquid crystal materials · CPC title

• G02F1/1333

  Constructional arrangements; {Manufacturing methods}(G02F1/135, G02F1/136 take precedence) · CPC title