Catalytic remedy for advanced UCO bleed reduction in recycle hydrocracking operations

Patent metadata

Field	Value
Publication number	US-10968405-B2
Application number	US-201916533545-A
Country	US
Kind code	B2
Filing date	Aug 6, 2019
Priority date	Aug 7, 2018
Publication date	Apr 6, 2021
Grant date	Apr 6, 2021

Abstract

A catalyst system has been designed that disrupts the sedimentation process. The catalyst system achieves this by saturating key feed components before the feed components are stripped into their incompatible aromatic cores. The efficacy of this disruptive catalyst system is particularly evident in a hydrocracker configuration that runs in two-stage-recycle operation. The catalyst is a self-supported multi-metallic catalyst prepared from a precursor in the hydroxide form, and the catalyst must be toward the top level of the second stage of the two-stage system.

First claim

What is claimed is:

1. A two-stage hydrocracking process with recycle for converting a petroleum feed to lower boiling products, which process comprises:
(i) hydrotreating a petroleum feed comprising ARDS VGO in a first stage reaction column in the presence of hydrogen to produce a hydrotreated effluent stream comprising a liquid product;
(ii) passing at least a portion of the hydrotreated stream effluent to a hydrocracking stage comprising more than one reaction zone in a second reaction column, with the effluent passed to a first reaction zone in the hydrocracking stage in the second reaction column, with the first reaction zone comprising a self-supported multi-metallic catalyst prepared from a precursor in the hydroxide form, and with the first reaction zone being the top level of the second reaction column, to produce a first hydrocracked effluent stream;
(iii) passing the first hydrocracked effluent stream to a second reaction zone of the hydrocracking stage;
(iv) passing bottoms from the hydrocracking stage to a distillation column;
(v) recovering a bottoms fraction from the distillation column and recycling at least a portion of the bottoms fraction to the hydrotreating first stage and/or to the hydrocracking stage; and
(vi) passing a minimized portion of the bottoms fraction in (v) to an FCC unit.

2. The process of claim 1 , wherein the hydrocracking stage comprises four reaction zones.

3. The process of claim 1 , wherein the hydrocracking stage comprises at least one reaction zone below the first reaction zone which is a hydrodesulfurization zone.

4. The process of claim 2 , wherein the bottom reaction zone is a hydrodesulfurization zone.

5. The process of claim 3 , wherein the hydrodesulfurization zone comprises a bulk multimetallic catalyst comprised of one Group VIII noble metal and two Group VIB metals.

6. The process of claim 1 , wherein cuts of light naphtha, heavy naphtha, kerosene and diesel are recovered from the distillation column.

7. The process of claim 1 , wherein the self-supported multi-metallic catalyst in the first reaction zone of the hydrocracking stage is a self-supported multi-metallic catalyst prepared by sulfiding a precursor catalyst in the hydroxide form of the general formula:
A v [(M P )OH) x (L) n y ] z (M VIB O 4 ), wherein:
A is one monovalent cationic species;
M P is a promoter metal with an oxidation state of +2 or +4 selected from one or more of Group IIA, Group IIB, Group IVA, and Group VIII metals (especially a Group VIII, such as Ni);
L is an organic oxygen-containing ligand; and
M VIB is a Group VIB metal.

8. The process of claim 7 , wherein the catalyst precursor M P :M VIB has an atomic ratio between 100:1 and 1:100.

9. The process of claim 7 , wherein M P is nickel (Ni), M VIB is selected from molybdenum (Mo), tungsten (W) or a combination thereof.

10. The process of claim 9 , wherein the catalyst precursor comprises Ni—Mo—W.

11. The process of claim 10 , wherein Ni:(Mo+W) has a molar ratio of 10:1 to 1:10.

12. The process of claim 7 , wherein L is a maleate ligand.

Assignees

• Chevron Usa Inc

Inventors

• Maesen Theodoras Ludovicus Michael
• Blackwell Derek
• Duma Viorel
• Komalarajun Varut
• Kuperman Alexander E
• Ryu Hyunuk
• Trevino Horacio
• Yoon Alex
• Mukherjee Ujjal

Classifications

• B01J2531/847

  Nickel · CPC title

• B01J2531/845

  Cobalt · CPC title

• B01J2531/66

  Tungsten · CPC title

• B01J2531/64

  Molybdenum · CPC title

• B01J2523/00

  Constitutive chemical elements of heterogeneous catalysts · CPC title