Process for conversion of plastics into fuel

Patent metadata

Field	Value
Publication number	US-10968394-B2
Application number	US-201716309870-A
Country	US
Kind code	B2
Filing date	Jun 19, 2017
Priority date	Jun 23, 2016
Publication date	Apr 6, 2021
Grant date	Apr 6, 2021

Abstract

A process for thermal cracking of a feedstock of plastic materials, in particular waste materials, includes the steps of melting the feedstock, conveying melted feedstock in a pyrolysis chamber where the melted feedstock is heated in a substantially oxygen purged environment, to convert it into pyrolysis gases, the process further comprising the steps of: driving pyrolysis gases from the pyrolysis chamber into a tray reflux column comprising a partial condenser at its upper extremity, returning pyrolysis gases condensed in the tray reflux column into the pyrolysis chamber, distilling pyrolysis gases exiting the partial condenser of the reflux column, to provide one or more fuel products.

First claim

The invention claimed is:

1. A process for thermal cracking of a feedstock of plastic materials in an apparatus, the apparatus comprising:
a mixing and melting device;
a pyrolysis chamber; and
a reflux column connected to a gas exit of the pyrolysis chamber, wherein the reflux column comprises an upper extremity and a plurality of crossflow trays, the plurality of crossflow trays including an upper tray disposed above a lower tray, the reflux column comprises a partial condenser disposed in the upper extremity of the reflux column, wherein the plurality of crossflow trays are valve trays, the valve trays having a plurality of valves, each valve of the plurality of valves having a corresponding cap disposed thereupon; and
wherein the process comprises the steps of melting the feedstock in the mixing and melting device, conveying melted feedstock in the pyrolysis chamber, where said melted feedstock is heated in a substantially oxygen purged environment to convert it into pyrolysis gases, said process further comprising the steps of:
driving pyrolysis gases from the pyrolysis chamber into the reflux column, returning pyrolysis gases condensed in the reflux column into the pyrolysis chamber, distilling pyrolysis gases exiting the partial condenser of the reflux column, to provide one or more fuel products;
wherein distilling pyrolysis gases exiting the partial condenser is done by flash distillation in a flash distillation column, the flash distillation column having an upper portion disposed above a lower portion; and
wherein the flash distillation step comprises partial recirculation of liquid heavy hydrocarbons obtained at the bottom of the flash distillation column in the lower portion of the flash distillation column by spraying said heavy hydrocarbons.

2. The process according to claim 1 , wherein the reflux column comprises a demister pad between the upper tray and the partial condenser.

3. The process according to claim 1 , wherein the partial condenser of the reflux column is a tube heat exchanger.

4. The process according to claim 1 , comprising the step of injecting liquid water or liquid hydrocarbons at the bottom of the reflux column.

5. The process according to claim 1 , comprising the step of condensing pyrolysis gases exiting the partial condenser of the reflux column in a condenser before distilling said gases.

6. The process according to claim 1 , wherein the flash distillation step comprises condensation of the vapor phase at the head of the flash distillation column and partial recirculation of condensed light hydrocarbons in the upper portion of the flash distillation column.

7. The process according to claim 1 , wherein the crossflow trays comprise down comers.

8. The process according to claim 1 , wherein the upper tray of the reflux column is a chimney tray.

9. The process according to claim 1 , further comprising an extruder configured to heat the feedstock.

10. The process according to claim 9 , wherein the extruder is configured to extrude the feedstock into the pyrolysis chamber.

11. The process according to claim 1 , comprising a flash distillation column downstream of the partial condenser of the tray reflux column.

12. The process according to claim 11 , comprising a condenser positioned between the partial condenser of the tray reflux column and the flash distillation column.

13. The process according to claim 11 , wherein the flash distillation column comprises a condenser and a reflux drum at a top end of the flash distillation column, and a recirculation loop for recirculating condensed light hydrocarbons of the reflux drum in the upper part of the flash distillation column.

14. The process according to claim 11 , wherein the flash distillation column comprises a recirculation loop for liquid heavy hydrocarbons obtained at the bottom of the flash distillation column, said recirculation loop being equipped with spray nozzles for spraying the liquid in the flash distillation column.

Assignees

• Suez Groupe

Inventors

• Posmyk Andrzej
• Gray James
• Hall Jonathan

Classifications

• B01D3/225

  Dual-flow sieve trays · CPC title

• C10B47/18

  with moving charge · CPC title

• Y02P20/143

  the feedstock being recycled material, e.g. plastics · CPC title

• C10G1/06

  by destructive hydrogenation · CPC title

• C10G1/10

  from rubber or rubber waste · CPC title