Process for preparing an aqueous dispersion of multistage polymer particles

Patent metadata

Field	Value
Publication number	US-10968342-B2
Application number	US-201916511069-A
Country	US
Kind code	B2
Filing date	Jul 15, 2019
Priority date	Jul 19, 2018
Publication date	Apr 6, 2021
Grant date	Apr 6, 2021

Abstract

The present invention relates to a process for preparing an aqueous dispersion of neutralized multistage polymer particles comprising the steps of contacting under emulsion polymerization conditions a) an aqueous dispersion of first polymer particles with b) first monomers to form an aqueous dispersion of 2-stage polymer particles; then contacting under emulsion polymerization conditions the aqueous dispersion of 2-stage polymer particles with second monomers comprising to form an unneutralized aqueous dispersion of 3-stage polymer particles; then neutralizing the unneutralized aqueous dispersion of 3-stage polymer particles with a base to form an aqueous dispersion of neutralized 3-stage polymer particles, wherein the first and second monomers form a shell having a calculated T g of less than 50° C. The process of the present invention is useful in preparing a composition that is useful as an open time additive in coatings formulations.

First claim

The invention claimed is:

1. A process for preparing an aqueous dispersion of neutralized multistage polymer particles comprising the steps of:
1) contacting under emulsion polymerization conditions a) an aqueous dispersion of first polymer particles comprising from 25 to 65 weight percent structural units of a carboxylic acid monomer, and from 40 to 75 weight percent structural units of a nonionic monomer with b) first monomers comprising, based on the weight of the first monomers, i) from 80 to 99.5 weight percent styrene or methyl methacrylate or a combination thereof, and ii) from 0.5 to 20 weight percent of a carboxylic acid monomer; to form an aqueous dispersion of 2-stage polymer particles; then
2) contacting under emulsion polymerization conditions the aqueous dispersion of the 2-stage polymer particles with second monomers comprising, based on the weight of the second monomers a) from 1 to 60 weight percent methyl methacrylate, b) from 35 to 98.5 weight percent n-butyl acrylate, 2-ethylhexyl acrylate, ethyl acrylate, or n-butyl methacrylate, or a combination thereof; c) from 0.5 to 5 weight percent of a carboxylic acid monomer; and d) less than 20 weight percent styrene, to convert the 2-stage polymer particles to unneutralized 3-stage polymer particles; then
3) neutralizing the unneutralized aqueous dispersion of the 3-stage polymer particles with a base to form an aqueous dispersion of neutralized 3-stage polymer particles having an average particle size in the range of 150 nm to 400 nm;
wherein the weight-to-weight ratio of the first polymer particles to the first and second monomers is in the range of from 1:2 to 1:9; and the weight-to-weight ratio of the first monomers to second monomers is in the range of from 3:2 to 1:8;
wherein the first and second monomers form a shell having a calculated T g of less than 50° C.

2. The process of claim 1 wherein the first polymer particles comprise, based on the weight of the first polymer particles, from 30 to 50 weight percent structural units of a carboxylic acid monomer, and from 50 to 70 weight percent of a nonionic ethylenically unsaturated monomer; and further comprise less than 0.04 weight percent structural units of a multiethylenically unsaturated monomer.

3. The process of claim 2 wherein the first monomers comprise styrene or methyl methacrylate or a combination thereof, and from 0.5 to 20 weight percent of a carboxylic acid monomer; and the second monomers comprise from 35 to 60 weight percent methyl methacrylate; less than 20 weight percent styrene; and from 40 to 65 weight percent n-butyl acrylate, 2-ethylhexyl acrylate, ethyl acrylate, or n-butyl methacrylate, or a combination thereof.

4. The process of claim 3 wherein the second monomers further comprises a sulfur acid containing monomer or a salt thereof; and less than 10 weight percent styrene.

5. The process of claim 4 wherein the first monomers comprise from 0.5 to 20 weight percent of a carboxylic acid monomer and from 80 to 99.5 weight percent styrene; and the second monomers comprise from 50 to 60 weight percent n-butyl acrylate, 2-ethylhexyl acrylate, ethyl acrylate, or n-butyl methacrylate, or a combination thereof; from 35 to 50 weight percent methyl methacrylate; and less than 5 weight percent styrene; wherein the first and second monomers comprises less than 0.2 weight percent of a multiethylenically unsaturated monomer, based on weight of the first and second monomers.

6. The process of claim 1 wherein the process further includes the step of contacting the aqueous dispersion of neutralized 3-stage polymer particles with an ancillary additive which is
a) a phenyl glycidyl ether represented by Structure I:

where the fragment

is a structural unit of a C 2 -C 60 linear or a C 3 -C 60 branched or cyclic diol, triol, or tetrol optionally functionalized with O atoms or aryl groups or both, or a structural unit of an unsubstituted aromatic diol, triol, or tetrol, or a structural unit of an aromatic diol, triol, or tetrol substituted with from 1 to 3 C 1 -C 6 alkyl groups;
each R 1 is independently H or C 1 -C 6 alkyl;
E is represented by the following structure:

m, n, and q are each independently from 1 to 20; x, y, and z are each independently from 1 to 50;
p is 0 or 1; s is 0 or 1; and
each Ar 1 is independently unsubstituted phenyl or naphthyl, or phenyl or naphthyl substituted with from 1 to 3 C 1 -C 6 alkyl groups; or
b) a phenyl glycidyl ether represented by the structure II:

where m is from 1 to 20; and n is from 1 to 100; or
c) a secondary alcohol ethoxylate; or
d) an ethoxylated sorbitan ester; or
e) a polyoxyethylene alkyl phosphate; or
f) an alkyne ethoxylate; or
g) an ethylene oxide/propylene oxide polylol block copolymer.

7. The process of claim 6 wherein the ancillary additive represented by the phenyl glycidyl ether of Structure I is either of the following compounds:

wherein, for compound 1a, m+n is in the range of 2 to 8; and x+y is in the range of 25 to 50; and for compound 1b, m+n+q is in the range of from 4 to 8; and x+y+z is in the range of from 30 to 50.

8. The process of claim 1 wherein the process further includes the step of contacting the neutralized aqueous dispersion of the 3-stage polymer particles with one or more of a dispersant, a pigment, a defoamer, a surfactant, a solvent, an extender, a coalescent, a biocide, an opaque polymers, or a colorant.

9. The process of claim 7 wherein a mixture of the neutralized aqueous dispersion of the 3-stage polymer particles and the ancillary additive is blended with a binder, a defoamer, a surfactant, a biocide, a dispersant, TiO 2 , a coalescent, and a rheology modifier to form a pigmented coating composition, wherein the dry weight concentration of the 3-stage polymer particles is in the range of 0.5 to 5 weight percent, and the concentration of the ancillary additive is in the range of from 0.1 to 1 weight percent, based on the weight of the composition, with the proviso that the concentration of the ancillary additive is less than 25 weight percent of the dry weight of the 3-stage polymer particles.

Assignees

• Rohm & Haas

Inventors

• Derocher Jonathan
• Hejl Andrew
• Levin Jessica
• Rabasco John J
• Van Dyk Antony K
• Yeung Kimy

Classifications

• C08F285/00 Primary

  Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers · CPC title

• C08L33/12 Primary

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C09D151/003

  grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds (C09D151/04, C09D151/06 take precedence) · CPC title

• C08L71/00

  Compositions of polyethers obtained by reactions forming an ether link in the main chain (of polyacetals C08L59/00; of epoxy resins C08L63/00; of polythioether-ethers C08L81/02; of polyether-sulfones C08L81/06); Compositions of derivatives of such polymers · CPC title

• C08L51/003

  grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds (C08L51/04, C08L51/06 take precedence) · CPC title