Olefin polymerization process in a gas-phase reactor comprising a riser unit and a downcomer

Patent metadata

Field	Value
Publication number	US-10968291-B2
Application number	US-201716348636-A
Country	US
Kind code	B2
Filing date	Nov 9, 2017
Priority date	Nov 10, 2016
Publication date	Apr 6, 2021
Grant date	Apr 6, 2021

Abstract

A process for preparing an ethylene polymer including the step of homopolymerizing ethylene or copolymerizing ethylene with one or more comonomers in a gas-phase polymerization reactor including a riser unit wherein growing polymer particles flow upwards under fluidization, fast fluidization or transport conditions and a downcomer wherein growing polymer particles flow downward in a densified form, wherein the hold-up of polymer particles in the downcomer is from 55 wt. % to 80 wt. % of the total hold-up of polymer particles in the gas-phase polymerization reactor.

First claim

What is claimed is:

1. A process for preparing an ethylene polymer comprising the step of:
homopolymerizing ethylene or copolymerizing ethylene with a comonomer in the presence of a polymerization catalyst in a gas-phase polymerization reactor to yield growing polymer particles, the gas-phase polymerization reactor comprising
a riser unit wherein growing polymer particles flow upwards under fluidization, fast fluidization or transport conditions, and
a downcomer wherein growing polymer particles flow downward in a densified form,

wherein the hold-up of polymer particles in the downcomer is from 55 wt. % to 80 wt. % of the total hold-up of polymer particles in the gas-phase polymerization reactor.

2. The process of claim 1 , wherein the gas-phase polymerization reactor is a multizone circulating reactor wherein the riser unit is a riser wherein growing polymer particles flow upwards under fast fluidization or transport conditions, the riser and the downcomer are interconnected, the polymer particles leaving the riser enter the downcomer, and the polymer particles leaving the downcomer enter the riser, thereby establishing a circulation of polymer particles through the riser and the downcomer.

3. The process of claim 1 , wherein the riser unit wherein the growing polymer particles flow upwards comprises
a fluidized bed of growing polymer particles.

4. The process of claim 1 , wherein the gas-phase polymerization reactor comprises
two or more polymerization zones, having a content of inert components in the reaction gas mixture from 30 to 99 vol. %.

5. The process of claim 1 , wherein the ethylene polymer is an ethylene copolymer having a comonomer content from 0.01 wt. % to 15 wt. %, prepared by copolymerizing ethylene and a C 3 -C 8 -1-alkene.

6. The process of claim 1 , wherein the riser unit has a specific pressure reduction Δp/h in the range from 500 Pa/m to 3000 Pa/m, with h being the height of the riser unit and Δp being the pressure difference between the bottom and the top of the riser unit.

7. The process of claim 1 , wherein a barrier fluid in liquid form is fed into the polymerization unit wherein the growing polymer particles flow downward in a densified form.

8. The process of claim 1 , wherein the reaction gas mixtures within the riser unit and the downcomer differ in composition and the reaction gas mixtures within the downcomer has a lower ethylene content than the reaction gas mixtures within the riser unit.

9. The process of claim 1 , wherein gaseous or liquid streams comprising ethylene and optionally a comonomer, inert components, or hydrogen are fed into the downcomer at a monomer feeding point.

10. The process of claim 9 , wherein gaseous or liquid streams comprising ethylene and optionally a comonomer, inert components or hydrogen are fed to at least 3 monomer feeding points into the downcomer and the hold-up of polymer particles between two adjacent monomer feeding points is no greater than 35 wt. % of the total hold-up of polymer particles in the downcomer.

11. The process of claim 1 , wherein the downcomer has sub-zones which differ in the composition of the reaction gas mixtures within the sub-zones of the downcomer.

12. The process of claim 1 , wherein the gas-phase polymerization reactor is part of a reactor cascade.

13. The process of claim 12 , wherein the reactor cascade comprises a fluidized bed reactor upstream of the gas-phase polymerization reactor.

14. The process of claim 1 , wherein the polymerization catalyst is a Ziegler-catalyst or a Ziegler-Natta-catalyst comprising
the reaction product of an aluminum alkyl with a titanium compound supported on a magnesium halide.

15. The process of claim 1 , wherein the ethylene polymer has a density of from 0.916 to 0.964 g/cm 3 , determined according to DIN EN ISO 1183-1:2004, Method A (Immersion), and a MFR 21.6 at a temperature of 190° C. under a load of 21.6 kg, determined according to DIN EN ISO 1133-1:2012-03, of from 0.5 to 300 g/10 min.

16. A process for preparing an ethylene polymer comprising homopolymerizing ethylene or copolymerizing ethylene with one or more comonomers in the presence of a polymerization catalyst in multizone circulating reactor comprising a riser, in which growing polymer particles flow upwards under fast fluidization or transport conditions, and a downcomer, in which growing polymer particles flow downward in a densified form, and the riser and the downcomer are interconnected, and polymer particles leaving the riser enter the downcomer, and polymer particles leaving the downcomer enter the riser, for establishing a circulation of polymer particles through the riser and the downcomer, wherein the hold-up of polymer particles in the downcomer is from 55 wt. % to 80 wt. % of the total hold-up of polymer particles in the multizone circulating reactor, and a barrier fluid in liquid form is fed into the downcomer.

17. The process of claim 16 , wherein the specific pressure reduction Δp/h in the riser is in the range from 500 Pa/m to 3000 Pa/m, with h being the height of the riser and Δp being the pressure difference between the bottom and the top of the riser.

18. The process of claim 16 , wherein the reaction gas mixtures within the riser and the downcomer differ in their composition and the reaction gas mixtures within the downcomer has a lower ethylene content than the reaction gas mixtures within the riser.

19. The process of claim 16 , wherein gaseous or liquid streams comprising ethylene and optionally one or more comonomers, inert components or hydrogen are fed to at least 3 monomer feeding points into the downcomer and the hold-up of polymer particles between two adjacent monomer feeding points is no greater than 35 wt. % of the total hold-up of polymer particles in the downcomer.

20. A process for preparing an ethylene polymer comprising homopolymerizing ethylene or copolymerizing ethylene with one or more comonomers in the presence of a polymerization catalyst in a reactor cascade comprising a fluidized bed reactor upstream of a multizone circulating reactor comprising a riser, in which growing polymer particles flow upwards under fast fluidization or transport conditions, and a downcomer, in which growing polymer particles flow downward in a densified form, and the riser and the downcomer are inter-connected, and polymer particles leaving the riser enter the downcomer, and polymer particles leaving the downcomer enter the riser, for establishing a circulation of polymer particles through the riser and the downcomer, wherein the hold-up of polymer particles in the downcomer of the multizone circulating reactor is from 55 wt. % to 80 wt. % of the total hold-up of polymer particles in the multizone circulating reactor.

Assignees

• Basell Polyolefine Gmbh

Inventors

• Meier Gerhardus
• Schueller Ulf
• Mei Gabriele
• Covezzi Massimo
• Baita Pietro
• Marturano Lorella

Classifications

• C08F2500/18

  Bulk density · CPC title

• C08F10/02 Primary

  Ethene · CPC title

• C08F4/65916

  supported on a carrier, e.g. silica, MgCl2, polymer · CPC title

• C08F4/6545

  and metals of C08F4/64 or compounds thereof · CPC title

• C08F2/34

  Polymerisation in gaseous state · CPC title