Olefin polymerization catalyst systems and methods of use thereof

Patent metadata

Field	Value
Publication number	US-10968289-B2
Application number	US-201716089008-A
Country	US
Kind code	B2
Filing date	Mar 30, 2017
Priority date	Mar 31, 2016
Publication date	Apr 6, 2021
Grant date	Apr 6, 2021

Abstract

Olefin polymerization catalyst systems are provided that include a procatalyst component having a metal-ligand complex of Formula (I): [formula] (I) where each X is a neutral, monoanionic, or dianionic, monodentate or polydentate ligand such that the complex of Formula (I) is neutral; each R 1 and R 10 is a (C 6 -C 40 )aryl, substituted (C 6 -C 40 )aryl, (C 3 -C 40 )heteroaryl, or substituted (C 3 -C 40 )heteroaryl; each R 2 , R 3 , R 4 , R 7 , R 8 , and R 9 is a hydrogen; (C 1 -C 40 )hydrocarbyl; substituted (C 1 -C 40 )hydrocarbyl; (C 1 -C 40 )heterohydrocarbyl; substituted (C 1 -C 40 )heterohydrocarbyl; halogen; or nitro (NO 2 ) group; and each R 5 and R 6 is a (C 1 -C)alkyl; substituted (C 1 -C 40 )alkyl; or [(Si) 1 —(C+Si) 40 ] substituted organosilyl. Additionally, olefin-based polymers and processes for polymerizing one or more olefin-based polymers in the presence of the olefin polymerization catalyst systems are also provided.

First claim

The invention claimed is:

1. An olefin polymerization catalyst system comprising a procatalyst component selected from metal-ligand complexes of Formula (I):

wherein M is titanium, zirconium, or hafnium;
wherein each X is independently a monodentate or polydentate ligand that is neutral, monoanionic, or dianionic, wherein n is an integer, and wherein X and n are chosen in such a way that the metal-ligand complex of Formula (I) is overall neutral;
wherein each R 1 and R 10 independently is selected from the group consisting of (C 6 -C 40 )aryl, substituted (C 6 -C 40 )aryl, (C 3 -C 40 )heteroaryl, and substituted (C 3 -C 40 )heteroaryl;
wherein each R 2 , R 3 , R 4 , R 7 , R 8 , and R 9 independently is selected from a group consisting of hydrogen; (C 1 -C 40 )hydrocarbyl; substituted (C 1 -C 40 )hydrocarbyl; (C 1 -C 40 )heterohydrocarbyl; substituted (C 1 -C 40 )heterohydrocarbyl; halogen; and nitro (NO 2 );
wherein each R 5 and R 6 independently is selected from the group consisting of a (C 1 -C 40 )alkyl; substituted (C 1 -C 40 )alkyl; [(Si) 1 —(C+Si) 40 ] substituted organosilyl;
optionally, two or more of the R 1-5 groups are combined together to form a ring structure, with such ring structure having from 5 to 16 atoms in the ring excluding any hydrogen atoms; and
optionally, two or more of the R 6-10 groups are combined together to form a ring structure, with such ring structure having from 5 to 16 atoms in the ring excluding any hydrogen atoms.

2. The olefin polymerization catalyst system according to claim 1 , wherein each X independently is Me, Bn, or Cl.

3. The olefin polymerization catalyst system according to claim 1 , wherein R 1 and R 10 are substituted phenyl groups and the metal-ligand complex has Formula (II):

wherein R a -R j are each independently selected from the group consisting of R S substituents and hydrogen; and wherein each R S independently is a halogen atom, polyfluoro substitution, perfluoro substitution, unsubstituted (C 1 -C 18 )alkyl, (C 6 -C 18 )aryl, F 3 C, FCH 2 O, F 2 HCO, F 3 CO, (R Z ) 3 Si, (R Z )3Ge, (R Z )O, (R Z )S, (R Z )S(O), (R Z )S(O) 2 , (R Z ) 2 P, (R Z ) 2 N, (R Z ) 2 C═N, NC, NO 2 , (R Z )C(O)O, (R Z )OC(O), (R Z )C(O)N(R Z ), or (R Z ) 2 NC(O), or two of the R S are taken together to form an unsubstituted (C 1 -C 18 )alkylene, wherein each R Z independently is an unsubstituted (C 1 -C 18 )alkyl.

4. The olefin polymerization catalyst system according to claim 3 , wherein R a , R e , R f and R j are each independently selected from the group consisting of halogen atoms, (C 1 -C 8 )alkyl groups, and (C 1 -C 18 )alkoxyl groups.

5. The olefin polymerization catalyst system according to claim 3 , wherein R a , R e , R f and R j are each independently methyl, ethyl, or isopropyl.

6. The olefin polymerization catalyst system of claim 1 , wherein said metal-ligand complex of Formula (I) is selected from the group consisting of Procatalysts 1-16:

7. The olefin polymerization catalyst system of claim 6 , wherein said metal-ligand complex of Formula (I) is selected from the group consisting of Procatalyst 1, Procatalyst 7, Procatalyst 8, Procatalyst 10, Procatalyst 11, and Procatalyst 14.

8. The olefin polymerization catalyst system of claim 6 , wherein said metal-ligand complex of Formula (I) is selected from the group consisting of Procatalyst 1, Procatalyst 7, and Procatalyst 8.

9. The olefin polymerization catalyst system of claim 1 , wherein said metal-ligand complex of Formula (I) is selected from the group consisting of Procatalyst 17, Procatalyst 18, and Procatalyst 19:

10. An olefin-based polymer comprising the product of a polymerization reaction of one or more olefin monomers in the presence of an olefin polymerization catalyst system according to claim 1 .

11. The olefin-based polymer according to claim 10 , wherein one or more of the olefin monomers is selected from the group consisting of linear alpha-olefins having from 3 to 12 carbons, branched alpha-olefins having from 5 to 16 carbons, and combinations thereof.

12. The olefin-based polymer according to claim 10 , wherein the polymer is an olefin block copolymer generated through a chain shuttling process.

13. A process for polymerizing one or more olefin-based polymers comprising:
polymerizing one or more olefin monomers in the presence of an olefin polymerization catalyst system according to claim 1 .

14. The process according to claim 13 , wherein the olefin polymerization catalyst system further comprises an activator.

15. The process according to claim 13 , wherein the olefin polymerization catalyst system further comprises a chain transfer agent.

Assignees

• Dow Global Technologies Llc

Inventors

• Bailey Brad C
• Christianson Matthew D
• Davis Anna V
• Patton Jasson T
• Paine Tomas D

Classifications

• C08F210/16 Primary

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F210/06

  Propene · CPC title

• C08F2/38

  Polymerisation using regulators, e.g. chain terminating agents {, e.g. telomerisation} · CPC title

• C08F2410/01

  Additive used together with the catalyst, excluding compounds containing Al or B · CPC title

• C08F4/64044 Primary

  NN · CPC title