Method for the manufacture of calcium silicate hydrate used as hardening accelerator in concrete and cement-based materials, calcium silicate hydrate manufactured with said method

Patent metadata

Field	Value
Publication number	US-10968108-B2
Application number	US-201515577268-A
Country	US
Kind code	B2
Filing date	May 29, 2015
Priority date	May 29, 2015
Publication date	Apr 6, 2021
Grant date	Apr 6, 2021

Abstract

A process for the manufacturing of a slurry containing nucleating agents which comprises reacting at least one source of a Ca containing compound with at least one source of a Si containing compound, in an aqueous media and in the presence of a doping agent selected from the group consisting of P, B, S, and mixtures thereof; wherein: (i) the reaction is carried out at a temperature comprised from 100 to 350° C.; (ii) the total molar ratio Ca/Si is 1.5-2.5, and (iii) the total molar ratio doping agent/Si is 0.01-2; provided that: (a) when the sole doping agent is P, the total molar ratio P/Si is 0.1-2; (b) when the sole doping agent is B, the total molar ratio B/Si is 0.01-2, and (c) when the sole doping agent is S, the total molar ratio S/Si is 0.1-2.

First claim

The invention claimed is:

1. A process for the manufacturing of a slurry containing nucleating agents which comprises reacting at least one source of a Ca containing compound with at least one source of a Si containing compound, in an aqueous media and in the presence of a doping agent selected from the group consisting of a compound containing P, a compound containing B, and mixtures thereof; wherein:
(i) the reaction is a hydrothermal reaction carried out at a temperature from 140 to 250° C. and endogenous pressure;
(ii) the total molar ratio of Ca to Si is from 1.8 to 2.4, and
(iii) the total molar ratio of doping agent to Si is from 0.01 to 2; provided that:
(a) when the sole doping agent is a compound containing P, the total molar ratio of P to Si is from 0.1 to 2; and
(b) when the sole doping agent is a compound containing B, the total molar ratio of B to Si is from 0.01 to 2,
wherein the nucleating agents comprise Calcium Silicate Hydrate (C-S-H) in the form of defective tobermorite.

2. The process according to claim 1 that additionally comprises reacting at least one source of an Al containing compound and the nucleating agents comprise Calcium (Aluminium) Silicate Hydrate (C-(A)-S-H) in the form of defective tobermorite.

3. The process according to claim 1 , wherein the compound containing P is P 2 O 5 .

4. The process according to claim 3 , wherein the nucleating agents additionally comprise hydroxyapatite.

5. The process according to claim 1 , wherein the compound containing B is borax.

6. The process according to claim 1 , wherein the calcium containing compound is selected from calcium oxide, calcium hydroxide, and mixtures thereof.

7. The process according to claim 1 , wherein the silicon containing compound is a water-soluble silicate compound.

8. The process according to claim 2 , wherein the aluminium containing compound is a water soluble aluminate.

9. The process according to claim 1 , wherein the source of the calcium containing compound and the source of the silicon containing compound are industrial wastes or by-products.

10. The process according to claim 9 , wherein the source of the calcium containing compound is acetylene lime slurry.

11. The process according to claim 9 , wherein the source of the silicon containing compound is selected from fly ash, silica fume, ground granulated blast furnace slag, salt slag, glass and mixtures thereof.

12. The process according to claim 1 , wherein the solid to water ratio by weight is comprised from 0.2 to 100.

13. The process according to claim 1 , wherein the duration of the reaction is comprised from 2 to 8 hours.

14. A process for the manufacturing of a powder containing nucleating agents which comprises:
a) carrying out the process as defined in claim 1 ,
b) filtering the resulting slurry,
c) drying the resulting filtered product at a temperature comprised from 80 to 150° C., and
d) disagglomering the resulting dried product to obtain a powder.

15. A slurry containing nucleating agents obtainable by the process of claim 1 .

16. A powder containing nucleating agents obtainable by the process of claim 14 .

17. The powder according to claim 16 , that comprises from 5 to 70% by weight of C-S-H in the form of defective tobermorite or from 1 to 30% by weight of C-S-H in the form of defective tobermorite.

18. Additive composition for concrete or other cement based materials comprising the powder according to claim 16 , together with appropriate additives.

19. Use of the slurry according to claim 15 as hardening accelerator for concrete or other cement based materials.

20. Concrete or other cement based material made with the slurry according to claim 15 .

21. The process according to claim 2 , wherein the source of the calcium containing compound, the source of the silicon containing compound, and the source of the aluminium containing compound are industrial wastes or by-products.

22. The process according to claim 2 , wherein the source of the calcium containing compound, the source of the silicon containing compound, and the source of the aluminium containing compound are selected from fly ash, silica fume, ground granulated blast furnace slag, salt slag, glass and mixtures thereof.

Assignees

• Fundacion Tecnalia Res & Innovation

Inventors

• Sánchez Dolado Jorge
• Gaitero Redondo Juan José

Classifications

• C04B22/00863

  Calcium silicate hydrate · CPC title

• C01B33/24 Primary

  Alkaline-earth metal silicates · CPC title

• C04B40/024

  Steam hardening, e.g. in an autoclave · CPC title

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title

• C04B14/043

  Alkaline-earth metal silicates, e.g. wollastonite · CPC title