Encoding method and decoding method using metal nanostructures

Patent metadata

Field	Value
Publication number	US-10967666-B2
Application number	US-201816608814-A
Country	US
Kind code	B2
Filing date	Apr 27, 2018
Priority date	Apr 28, 2017
Publication date	Apr 6, 2021
Grant date	Apr 6, 2021

Abstract

The present disclosure relates to an encoding method and a decoding method using a chiral metal nanostructure. The encoding method according to an aspect of the present disclosure includes preparing a plurality of metal nanostructures having a chiral structure; obtaining the optical data of the plurality of metal nanostructures, and preparing a security medium including the plurality of metal.

First claim

The invention claimed is:

1. An encoding method using a chiral metal nanostructure, the encoding method comprising:
preparing a plurality of metal nanostructures having a chiral structure;
obtaining optical data of the plurality of metal nanostructures; and
preparing a security medium including the plurality of metal nanostructures.

2. The encoding method according to claim 1 , wherein the preparing of a plurality of metal nanostructures includes:
mixing a metal precursor, a surfactant, and a reducing agent to prepare a first mixed solution;
adding a peptide to the first mixed solution to prepare a second mixed solution; and
adding a plurality of metal seed particles to the second mixed solution to grow the plurality of metal nanostructures.

3. The encoding method according to claim 2 , wherein the peptide includes one or more selected from the group consisting of cysteine (Cys), glutamate (Glu), alanine (Ala), glycine (Gly), penicillamine, histidine, lysine, ornithine, arginine, aspartic acid, glutamic acid, asparagine, glutathione and glutamine.

4. The encoding method according to claim 3 , wherein the peptide is a monopeptide, a dipeptide or a tripeptide.

5. The encoding method according to claim 2 , wherein the plurality of metal seed particles is at least one of gold, silver, and copper, and each of the plurality of metal seed particles has a size of 1 nm to 100 nm.

6. The encoding method according to claim 1 , wherein each of the plurality of metal nanostructures includes a concave portion and a convex portion, and
wherein the concave portion and the convex portion are extended to be bent in one direction.

7. The encoding method according to claim 1 , wherein each of the plurality of metal nanostructures has a helicoid shape in which a corner is twisted in one direction.

8. The encoding method according to claim 1 , wherein the optical data includes at least one of spectroscopic data and color conversion pattern data measured from the plurality of metal nanostructures,
wherein the spectroscopic data includes one of a circular dichroism (CD) spectrum, a g-factor spectrum and an absorbance spectrum of the plurality of metal nanostructures, and
wherein the color conversion pattern data includes a color change according to an angle change of polarized light irradiated to the plurality of metal nanostructures.

9. The encoding method according to claim 8 , wherein the spectroscopic data includes a plurality of parameters obtained from one of the circular dichroism (CD) spectrum, the g-factor spectrum or the absorbance spectrum.

10. The encoding method according to claim 8 , wherein the obtaining of optical data of the plurality of metal nanostructures includes:
irradiating the plurality of metal nanostructures with polarized light to measure the spectroscopic data or the color conversion data; and
storing the measured spectroscopic data or the color conversion data.

11. The encoding method according to claim 1 , wherein the plurality of metal nanostructures comprises a plurality of first metal nanostructures having a first chiral structure and a plurality of second metal nanostructures having a second chiral structure,
wherein the first chiral structure and the second chiral structure have different shapes, and
wherein the spectroscopic data and the color conversion pattern data measured from the first metal nanostructure and the second metal nanostructure are different from each other.

12. A decoding method using a chiral metal nanostructure, the decoding method comprising:
preparing a target medium including a plurality of metal nanostructures having a chiral structure;
irradiating polarized light to the plurality of metal nanostructures of the target medium to measure optical data;
loading reference optical data previously stored from a storage unit; and
comparing the measured optical data with the reference optical data.

13. The decoding method according to claim 12 , wherein each of the plurality of metal nanostructures includes a concave portion and a convex portion, and
wherein the concave portion and the convex portion are extended to be bent in one direction.

14. The decoding method according to claim 12 , wherein the optical data includes at least one of spectroscopic data and color conversion pattern data measured from the plurality of metal nanostructure,
wherein the spectroscopic data includes one of a circular dichroism (CD) spectrum, a g-factor spectrum, or an absorbance spectrum of the metal nanostructure, and
wherein the color conversion pattern data includes a color change according to an angle change of polarized light irradiated to the metal nanostructure.

15. The decoding method according to claim 12 , wherein the reference optical data is measured from a reference chiral metal nanostructure produced under predetermined conditions to determine security breach or forgery.

16. The decoding method according to claim 12 , wherein the plurality of metal nanostructures comprises a plurality of first metal nanostructures having a first chiral structure and a plurality of second metal nanostructures having a second chiral structure,
wherein the first chiral structure and the second chiral structure have different shapes, and
wherein the spectroscopic data and the color conversion pattern data measured from the first metal nanostructure and the second metal nanostructure are different from each other.

17. The decoding method according to claim 12 , wherein in the comparing the measured optical data with the reference optical data, the security is verified when the measured optical data matches the reference optical data, and the security is not recognized when at least one of the measured optical data is different from the reference optical data.

Assignees

• Lg Display Co Ltd
• Seoul Nat Univ R&Db Foundation

Inventors

• Chang Ki Seok
• Ryu Sung Pil
• Nam Ki Tae
• Kim Wook Sung
• Lee Hye Eun
• Ahn Hyo Yong

Classifications

• B42D25/425

  by deformation, e.g. embossing · CPC title

• B42D25/373 Primary

  Metallic materials · CPC title

• B42D25/29

  Securities; Bank notes · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• G01N21/19

  Dichroism · CPC title