Preparation method of a WC cemented carbide with adjustable alignment of plate-shape grains

Patent metadata

Field	Value
Publication number	US-10961606-B2
Application number	US-201716343766-A
Country	US
Kind code	B2
Filing date	Dec 21, 2017
Priority date	Nov 29, 2016
Publication date	Mar 30, 2021
Grant date	Mar 30, 2021

Abstract

The invention discloses a preparation method of a WC cemented carbide with adjustable alignment of plate-shape grains. According to the theoretical composition of the cemented carbide, the weighed W powder is composed of two raw W materials with significantly different particle sizes in a certain mass ratio. Also graphite powder and Co powder are weighed. W—C—Co powder is subjected to planetary ball milling with controlled process parameters; then, after plasma-assisted ball milling, W—C—Co composite powder composed of small-sized lamellar W sheets and large-sized lamellar W sheet is obtained; Finally dense cemented carbide containing plate-shape WC grains is obtained by press molding of the ball milled power and in-situ carbonization through sintering at a high temperature. The invention not only provides simple preparation process with low energy consumption, but also can regulate the degree of orientated alignment of the plate-shape WC in the sintered block. Besides, the mechanical properties of the WC—Co cemented carbide containing plate-shape WC grains are optimized, so that the cemented carbide has excellent overall mechanical properties.

First claim

The invention claimed is:

1. A preparation method of a WC cemented carbide with adjustable alignment of plate-shaped grains, comprising the steps of:
(1) weighting graphite powder, Co powder and W powder according to the composition of WC-XCo; characterized in that, the W powder comprises fine W particles and coarse W particles, and 6≤X≤20;
the fine W particles have a particle size of 0.3 μm-1 μm;
the coarse W particles have a particle size of 5 μm-25 μm;
the mass ratio of the fine W particles to the coarse W particles is 1:4-4:1;
(2) adding the graphite powder, the Co powder and the W powder in step (1), and required extra amount of carbon in a planetary ball mill for planetary ball milling to obtain W—C—Co powder;
(3) placing the W—C—Co powder obtained in step (2) in a plasma-assisted high-energy ball mill for plasma-assisted ball milling to obtain W—C—Co composite powder;
(4) subjecting the W—C—Co composite powder obtained in step (3) to uniaxial compression molding to obtain W—C—Co powder greed body;
(5) carbonizing the W—C—Co powder green body by sintering at 1350-1550° C.

2. The preparation method of a WC cemented carbide with adjustable alignment of plate-shape grains, according to claim 1 , characterized in that, the graphite powder in step (1) has a particle size of 20 μm-80 μm.

3. The preparation method of a WC cemented carbide with adjustable alignment of plate-shape grains, according to claim 1 , characterized in that, the particle size of the Co powder in step (1) is 0.5 μm-5 μm.

4. The preparation method of a WC cemented carbide with adjustable alignment of plate-shape grains, according to claim 1 , characterized in that the specific parameters of the planetary ball milling in step (2) are: a ball-to-batch ratio of 1:3-1:5, and a ball milling time of 5-10 h.

5. The preparation method of a WC cemented carbide with adjustable alignment of plate-shape grains according to claim 1 , characterized in that, the specific parameters of the plasma-assisted ball milling in step (3) are: a ball-to-batch ratio of 30:1-60:1, a ball milling time of 3-6 h, and a discharge current of 1-3 A.

6. The preparation method of a WC cemented carbide with adjustable alignment of plate-shape grains according to claim 1 , characterized in that, the WC—Co composite powder in step (3) is composed of a small-sized lamellar W sheet and a large-sized W sheet, wherein the small-sized lamellar W sheet has a length of 200 nm-1.5 μm and a thickness of 40 nm-200 nm, and the large-sized lamellar W sheet has a length of 3 μm-15 μm and a thickness of 60 nm-300 nm.

7. The preparation method of a WC cemented carbide with adjustable alignment of plate-shape grains according to claim 1 , characterized in that, said carbonizing by sintering refers to vacuum sintering or low pressure sintering.

Assignees

• Univ South China Tech

Inventors

• Zhu Min
• Wang Wei
• Lu Zhongchen
• Zeng Meiqin
• Bao Xianyong

Classifications

• C22C29/08

  based on tungsten carbide · CPC title

• C22C1/055 Primary

  using carbon · CPC title

• B22F3/16

  in successive or repeated steps · CPC title

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title

• C22C29/067

  comprising a particular metallic binder · CPC title