Coated steel strips, coated stamped products and methods

Patent metadata

Field	Value
Publication number	US-10961602-B2
Application number	US-201916413799-A
Country	US
Kind code	B2
Filing date	May 16, 2019
Priority date	Oct 30, 2006
Publication date	Mar 30, 2021
Grant date	Mar 30, 2021

Abstract

A pre-coated steel strip is provided. The steel strip includes a strip of base steel having a length, a width, a first side, and a second side. The length of the strip is at least 100 m and the width is at least 600 mm. An aluminum or an aluminum alloy pre-coating is on at least part of at least one of the first or second sides of the strip of base steel. A thickness t p of the pre-coating is from 20 to 33 micrometers at every location on at least one of the first or second sides. Processes, coated stamped products and land motor vehicles are also provided.

First claim

What is claimed is:

1. A precoated steel product comprising:
a strip of base steel having a first side and a second side; and
a coating on at least one of the first side of the strip of base steel and the second side of the strip of base steel, wherein the coating results from interdiffusion between the base steel, and an aluminum or aluminum alloy pre-coating, and wherein the coating includes, proceeding from the base steel outwards:
(a) an interdiffusion layer having a first mean iron composition,
(b) an intermediate layer having a second mean iron composition different from the first mean iron composition,
(c) an intermetallic layer having a third mean iron composition different from the first and second mean iron compositions, the third mean iron composition being higher than the second mean iron composition; and
(d) a superficial layer having a fourth mean iron composition different from the third mean iron composition,

wherein the coating has a thickness greater than 30 micrometers.

2. The precoated steel product as recited in claim 1 wherein the layers (c) and (d) are quasi continuous by occupying at least 90% of a level corresponding to each of the layers (c) and (d) and wherein less than 10% of layer (c) is present at an extreme surface of the product.

3. The precoated steel product as recited in claim 1 wherein the base steel includes the following components by weight based on total weight:
0.15%<carbon<0.5%;
0.5%<manganese<3%;
0.1%<silicon<0.5%;
0.01%<chromium<1%;
titanium<0.2%;
aluminum<0.1%;
phosphorus<0.1%;
sulfur<0.05%;
0.0005%<boron<0.08%;
and further comprises iron and impurities inherent in processing.

4. The precoated steel product as recited in claim 1 wherein the base steel comprises the following components by weight based on total weight:
0.20%<carbon<0.5%;
0.8%<manganese<1.5%;
0.1%<silicon<0.35%;
0.01%<chromium<1%;
titanium<0.1%;
aluminum<0.1%;
phosphorus<0.05%;
sulfur<0.03%;
0.0005%<boron<0.01%;
and further comprises iron and impurities inherent in processing.

5. The precoated steel product as recited in claim 1 wherein the base steel comprises 20 ppm or less of sulfur.

6. The precoated steel product as recited in claim 2 wherein the base steel comprises 20 ppm or less of sulfur.

7. The precoated steel product as recited in claim 1 wherein a ratio of titanium to nitrogen in the base steel in weight % is in excess of 3.42.

8. The precoated steel product as recited in claim 2 wherein a ratio of titanium to nitrogen in the base steel in weight % is in excess of 3.42.

9. The precoated steel product as recited in claim 1 wherein the layer (a) has a thickness less than 15 micrometers.

10. The precoated steel product as recited in claim 1 wherein the layer (a) has a thickness less than 10 micrometers.

11. The precoated steel product as recited in claim 1 wherein the interdiffusion layer comprises the following components by weight based on total weight: 86 to 95% Fe, 4 to10% Al, and 0 to 5% Si.

12. The precoated steel product as recited in claim 1 wherein the intermediate layer comprises the following components by weight based on total weight: 39 to 47% Fe, 53 to 61% Al, and 0 to 2% Si.

13. The precoated steel product as recited in claim 1 wherein the intermetallic layer comprises the following components by weight based on total weight: 62 to 67% Fe, 30 to 34% Al, and 2 to 6% Si.

14. The precoated steel product as recited in claim 1 wherein the superficial layer comprises the following components by weight based on total weight: 39 to 47% Fe, 53 to 61% Al, and 0 to 2% Si.

15. The precoated steel product as recited in claim 11 wherein the intermediate layer comprises the following components by weight based on total weight: 39 to 47% Fe, 53 to 61% Al, and 0 to 2% Si.

16. The precoated steel product as recited in claim 15 wherein the intermetallic layer comprises the following components by weight based on total weight: 62 to 67% Fe, 30 to 34% Al, and 2 to 6% Si.

17. The precoated steel product as recited in claim 16 wherein the superficial layer comprises the following components by weight based on total weight: 39 to 47% Fe, 53 to 61% Al, and 0 to 2% Si.

18. The precoated steel product as recited in claim 1 wherein the interdiffusion layer has a thickness of from 1 micron to 15 microns.

19. The precoated steel product as recited in claim 1 wherein the first mean iron composition is 90 percent, the second mean iron composition is 43 percent, the third mean iron composition is 63 percent and the fourth mean iron composition is 45 percent.

20. The precoated steel product as recited in claim 1 wherein the fourth mean iron composition is lower than the third mean iron composition.

21. A precoated steel product comprising:
a strip of base steel having a first side and a second side; and
a coating on at least one of the first side of the strip of base steel and the second side of the strip of base steel, wherein the coating results from interdiffusion between the base steel, and an aluminum or aluminum alloy pre-coating, and wherein the coating includes, proceeding from the base steel outwards:
(a) an interdiffusion layer having a first mean iron composition,
(b) an intermediate layer having a second mean iron composition different from the first mean iron composition,
(c) an intermetallic layer having a third mean iron composition different from the first and second mean iron compositions, the third mean iron concentration being higher than the second mean iron composition, and
(d) a superficial layer having a fourth mean iron composition different from the first, second and third mean iron compositions,

wherein the coating has a thickness greater than 30 micrometers.

22. The precoated steel product as recited in claim 21 wherein the fourth mean iron composition is lower than the third mean iron composition.

23. The precoated steel product as recited in claim 22 wherein the fourth mean iron composition is higher than the second mean iron composition.

24. A precoated steel product comprising:
a strip of base steel having a first side and a second side; and
a coating on at least one of the first side of the strip of base steel and the second side of the strip of base steel, wherein the coating results from interdiffusion between the base steel, and an aluminum or aluminum alloy pre-coating, and wherein the coating includes, proceeding from the base steel outwards:
(a) an interdiffusion layer having a first mean aluminum composition,
(b) an intermediate layer having a second mean aluminum composition different from the first mean aluminum composition,
(c) an intermetallic layer having a third mean aluminum composition different from the first and second mean aluminum compositions, and
(d) a superficial layer having a fourth mean aluminum composition different from the first, second and third mean aluminum compositions, the second mean aluminum composition being greater than the third mean aluminum composition;

wherein the coating has a thickness greater than 30 micrometers.

25. The precoated steel product as recited in claim 24 wherein the fourth mean aluminum composition is less than the second mean aluminum composition.

26. The precoated steel product as recited in claim 24 wherein the layer (a) has a thickness less than 15 micrometers.

27. The precoated steel product as recite

Assignees

• Arcelormittal

Inventors

• Drillet Pascal
• Spehner Dominique
• Kefferstein Ronald

Classifications

• C23C2/26

  After-treatment (C23C2/14 takes precedence) · CPC title

• B32B15/00 Primary

  Layered products comprising {a layer of} metal · CPC title

• C21D8/02

  during manufacturing of plates or strips (C21D8/12 takes precedence) · CPC title

• C21D9/46 Primary

  for sheet metals · CPC title

• Y10T428/12389

  having variation in thickness · CPC title