Process for the preparation of a mineral filler product

Patent metadata

Field	Value
Publication number	US-10961397-B2
Application number	US-201615751773-A
Country	US
Kind code	B2
Filing date	Aug 19, 2016
Priority date	Aug 21, 2015
Publication date	Mar 30, 2021
Grant date	Mar 30, 2021

Abstract

A process for the preparation of a mineral filler product is disclosed, the process comprising a step of dry grinding a calcium carbonate-comprising material in a mixture obtained by contacting the calcium carbonate-comprising material with at least one polydimethylsiloxane as grinding agent.

First claim

The invention claimed is:

1. A process for the preparation of a mineral filler product, the process comprising the steps of:
a) providing at least one calcium carbonate-comprising material;
b) providing at least one grinding agent;
c) dry grinding the at least one calcium carbonate-comprising material in a mixture obtained by contacting:
i) the at least one calcium carbonate-comprising material provided in step a), with
ii) the at least one grinding agent provided in step b) in at least one grinding unit to obtain a dry ground mineral filler; and

d) classifying the dry ground mineral filler of step c) to obtain a coarse fraction and a fine fraction, wherein the coarse fraction is removed or subjected to dry grinding step c) and the fine fraction represents a fine mineral filler;
wherein the total moisture content in the mixture of step c) is less than or equal to 10.0 wt.-based on the total weight of said mixture;
the amount of the at least one grinding agent provided in step b) ranges from 0.05 to 150 mg/m 2 , based on the specific surface area of the calcium carbonate-comprising material as calculated based on the particle size distribution;
the temperature in step c) ranges from 45° C. to 200° C.; and
the at least one grinding agent is a polydimethylsiloxane having a kinematic viscosity of 10 to 10 000 mm 2 /s.

2. The process according to claim 1 , comprising a further step e) of drying the fine mineral filler of step d) to obtain a dried mineral filler having a total moisture content of less than 1.0 wt. % based on the total weight of said dried mineral filler.

3. The process according to claim 1 , wherein the calcium carbonate-comprising material provided in step a) is selected from natural calcium carbonate sources and preferably is selected from the group consisting of marble, limestone, chalk, dolomite, and mixtures thereof.

4. The process according to claim 1 , wherein the amount of said at least one grinding agent provided in step b) ranges from 0.1 to 100.0 mg/m 2 based on the specific surface area of the calcium carbonate-comprising material as calculated based on the particle size distribution.

5. The process according to claim 1 , wherein the at least one grinding agent provided in step b) has a kinematic viscosity of 15 to 800 mm 2 /s.

6. The process according to claim 1 , wherein the at least one grinding agent provided in step b) is a linear polydimethylsiloxane.

7. The process according to claim 1 , wherein the total moisture content in the mixture of step c) is less than or equal to 5.0 wt. % based on the total weight of said mixture.

8. The process according to claim 1 , wherein the temperature in step c) ranges from 65° C. to 200° C.

9. The process according to claim 1 , wherein the fine mineral filler of step d) has a weight median particle size d 50 ranging from 0.4 to 40.0 μm.

10. The process according to claim 2 , wherein the process comprises a further step of treating the fine mineral filler of step d) and/or the dried mineral filler of step e) with a hydrophobizing agent.

11. A mineral filler product obtainable by a process according to claim 1 .

12. The mineral filler product according to claim 11 , wherein said product has a volatile onset temperature of at least or equal to 200° C.

13. A product comprising the mineral filler product according to claim 11 , wherein the product is selected from the group consisting of a polymer composition, paper, paper coatings, agricultural products, paints, adhesives, sealants, construction products, food packaging products and cosmetic products.

14. A polymer composition comprising
a) at least one polymeric resin; and
b) from 0.1 to 90.0-wt. %, based on the total weight of said polymer composition of the mineral filler product according to claim 11 .

15. The process according to claim 4 , wherein the amount of said at least one grinding agent provided in step b) ranges from 0.2 to 50.0 mg/m 2 based on the specific surface area of the calcium carbonate-comprising material as calculated based on the particle size distribution.

16. The process according to claim 5 , wherein the at least one grinding agent provided in step b) has a kinematic viscosity of 20 to 550 mm 2 /s.

17. The process according to claim 7 , wherein the total moisture content in the mixture of step c) is less than or equal to 1.0 wt.-% based on the total weight of said mixture.

18. The process according to claim 8 , wherein the temperature in step c) ranges from 80° C. to 150° C.

19. The process according to claim 9 , wherein the fine mineral filler of step d) has a weight median particle size d 50 ranging from 0.7 to 10.0 μm.

20. The mineral filler product according to claim 12 , wherein said product has a volatile onset temperature of at least to 250° C.

Assignees

• Omya Int Ag

Inventors

• Rentsch Samuel
• Blum René Vinzenz
• Gane Patrick A C

Classifications

• C01P2006/88

  Isotope composition differing from the natural occurrence · CPC title

• C01P2006/22

  Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability · CPC title

• C09C3/04

  Physical treatment, e.g. grinding or treatment with ultrasonic vibrations {(C09C3/006 takes precedence)} · CPC title

• C09C3/12

  Treatment with organosilicon compounds {(C09C3/006 takes precedence)} · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title