Methods of making an elastomer composite reinforced with silica and products containing same

Patent metadata

Field	Value
Publication number	US-10961359-B2
Application number	US-201916421522-A
Country	US
Kind code	B2
Filing date	May 24, 2019
Priority date	Jul 15, 2015
Publication date	Mar 30, 2021
Grant date	Mar 30, 2021

Abstract

Methods to make a silica elastomer composite with a destabilized dispersion of silica are described, along with silica elastomer composites made from the methods. The advantages achieved with the methods are further described.

First claim

What is claimed is:

1. A method of producing a silica elastomer composite, comprising:
providing a first fluid comprising a destabilized dispersion of silica with silica present in an amount of from 6 to 35 weight percent, and said first fluid having a first fluid volumetric flow rate, and providing a second fluid comprising an elastomer latex and said second fluid having a second fluid volumetric flow rate, and combining under continuous flow conditions at least the first fluid and the second fluid to form a semi-solid silica-containing continuous rubber phase mixture, and forming said semi-solid silica-containing continuous rubber phase mixture into said silica elastomer composite in a mixing chamber of a device, and recovering said silica elastomer composite having a silica content of about 15 phr to about 180 phr.

2. The method of claim 1 , wherein said silica content of said silica elastomer composite is from about 35 phr to about 115 phr.

3. The method of claim 1 , wherein said silica content of said silica elastomer composite is from about 40 phr to about 115 phr.

4. The method of claim 1 , wherein said elastomer latex comprises about 10 wt % to about 70 wt % dry rubber content.

5. The method of claim 1 , wherein said destabilized dispersion of silica comprises about 10 wt % to about 28 wt % silica.

6. The method of claim 1 , wherein said first fluid comprising said destabilized dispersion of silica has a zeta potential magnitude of less than 30 mV.

7. The method of claim 1 , wherein said first fluid comprising said destabilized dispersion of silica has a zeta potential magnitude of less than 20 mV.

8. The method of claim 1 , wherein carbon black is present in said silica elastomer composite in an amount of from about 10 wt % to about 0.1 wt % based on total particulates present in said silica elastomer composite.

9. The method of claim 1 , wherein said elastomer latex is natural rubber latex.

10. The method of claim 9 , wherein said natural rubber latex is in the form of a field latex, latex concentrate, desludged latex, chemically modified latex, enzymatically modified latex, or any combinations thereof.

11. The method of claim 9 , wherein said natural rubber latex is in the form of an epoxidized natural rubber latex.

12. The method of claim 9 , wherein said natural rubber latex is in the form of a latex concentrate.

13. The method of claim 1 , wherein the method further comprises mixing the silica elastomer composite with additional elastomer to form an elastomer composite blend.

14. A method for making a rubber compound comprising
blending the silica elastomer composite prepared from the method of claim 1 with other components to form the rubber compound, wherein said other components comprise at least one antioxidant, sulfur, polymer other than an elastomer latex, catalyst, extender oil, resin, coupling agent, one or more additional elastomer composite(s), or reinforcing filler, or any combinations thereof.

15. A method for making a rubber article selected from tires, moldings, mounts, liners, conveyors, seals, or jackets, comprising
(a) compounding the silica elastomer composite prepared from the method of claim 1 with other components to form a compound, and
(b) vulcanizing the compound to form said rubber article.

16. The method of claim 1 , wherein the method further comprises conducting one or more post processing steps after recovering the silica elastomer composite.

17. The method of claim 16 , wherein the post processing steps comprise at least one of:
a) dewatering the silica elastomer composite to obtain a dewatered mixture;
b) mixing or compounding the dewatered mixture to obtain a compounded silica elastomer composite;
c) milling the compounded silica elastomer composite to obtain a milled silica elastomer composite;
d) granulating or mixing the milled silica elastomer composite;
e) baling the silica elastomer composite after the granulating or mixing to obtain a baled silica elastomer composite;
f) extruding the silica elastomer composite;
g) calendaring the silica elastomer composite; and/or
h) optionally breaking apart the baled silica elastomer composite and mixing with further components.

18. The method of claim 16 , wherein the post processing steps comprise at least roll milling of the silica elastomer composite.

19. The method of claim 1 , wherein said second fluid comprises a blend of two or more different elastomer lattices.

20. The method of claim 1 , wherein said process further comprises providing one or more additional fluids and combining the one or more additional fluids with said first fluid flow and second fluid flow, wherein said one or more additional fluids comprise one or more elastomer latex fluids, and said additional fluids are the same as or different from said elastomer latex present in said second fluid.

21. The method of claim 1 , wherein said process further comprises converting the semi-solid silica-containing continuous rubber phase to a solid silica-containing continuous rubber phase, by at least one step comprising (a) mechanical removal of water; (b) having the semi-solid silica-containing continuous rubber phase sit for at least 10 minutes; (c) heating the semi-solid silica-containing continuous rubber phase to remove water content; or (d) subjecting the semi-solid silica-containing continuous rubber phase to acid, to additional acid, to salt, to additional salt or to a combination of acid and salt; and combinations thereof.

Assignees

• Cabot Corp

Inventors

• Xiong Jincheng
• Green Martin C
• Williams William R
• Fomitchev Dmitry
• Adler Gerald D
• Mcdonald Duane G
• Grosz Ron

Classifications

• C08L21/02

  Latex · CPC title

• C08L9/10

  Latex (C08L9/04, C08L9/08 take precedence) · CPC title

• C08L7/02

  Latex · CPC title

• C08J3/22

  using masterbatch techniques · CPC title

• C08J3/215 Primary

  at least one additive being also premixed with a liquid phase · CPC title