Methods and systems for performing chemical separations

Patent metadata

Field	Value
Publication number	US-10960343-B2
Application number	US-201916444923-A
Country	US
Kind code	B2
Filing date	Jun 18, 2019
Priority date	Dec 19, 2016
Publication date	Mar 30, 2021
Grant date	Mar 30, 2021

Abstract

The present disclosure provides a method for generating higher hydrocarbon(s) from a stream comprising compounds with two or more carbon atoms (C 2+ ), comprising introducing methane and an oxidant (e.g., O 2 ) into an oxidative coupling of methane (OCM) reactor. The OCM reactor reacts the methane with the oxidant to generate a first product stream comprising the C 2+ compounds. The first product stream can then be directed to a separations unit that recovers at least a portion of the C 2+ compounds from the first product stream to yield a second product stream comprising the at least the portion of the C 2+ compounds.

First claim

What is claimed is:

1. A method for generating compounds with two or more carbon atoms (C 2+ compounds), comprising:
(a) directing oxygen (O 2 ) and methane (CH 4 ) into an oxidative coupling of methane (OCM) reactor that reacts the O 2 and the CH 4 in an OCM process to yield a product stream comprising (i) C 2+ compounds including olefins and paraffins and (ii) carbon dioxide (CO 2 ); and
(b) directing the product stream from the OCM reactor into a separations unit that selectively adsorbs the olefins from the paraffins, wherein the separations unit comprises (i) a pressure swing adsorption (PSA) unit, (ii) a temperature swing adsorption (TSA) unit, or (iii) a membrane unit, and wherein the PSA unit, the TSA unit or the membrane unit comprises a sorbent that selectively adsorbs the olefins;
(c) desorbing the olefins from the sorbent to generate an olefins stream comprising olefins and CO 2 ; and
(d) directing the olefins stream to a CO2 removal unit to remove CO2 from the olefins stream.

2. The method of claim 1 , wherein the separations unit selectively separates ethylene from the paraffins.

3. The method of claim 1 , wherein the sorbent has dispersed metal ions that are capable of complexing with the olefins.

4. The method of claim 1 , wherein the sorbent is selected from a zeolite, a molecular sieve sorbent, a carbon molecular sieve, an activated carbon, a carbon nanotube, a metal-organic framework (MOF), and a polymeric resin.

5. The method of claim 1 , further comprising recycling at least a portion of the CO 2 removed from the olefins stream to a methanation unit.

6. The method of claim 1 , wherein the sorbent is a MOF, the olefin is ethylene, and the ethylene is desorbed from the MOF using ethane, propane or any combination thereof.

7. A method for generating compounds with two or more carbon atoms (C 2+ compounds), comprising:
(a) directing oxygen (O 2 ) and methane (CH 4 ) into an oxidative coupling of methane (OCM) reactor that reacts the O 2 and CH 4 in an OCM process to yield a product stream comprising C 2+ compounds comprising olefins including ethylene (C 2 H 2 ) and propylene (C 3 H 6 ) and paraffins including ethane (C 2 H 6 ), unreacted CH 4 , carbon dioxide (CO 2 ), and hydrogen (H 2 );
(b) directing the product stream into a first separations unit containing an adsorbent that produces (i) a bottoms stream comprising the C 2+ compounds and the CO 2 and (ii) an overhead stream enriched with the unreacted CH 4 and H 2 ,
(c) directing the bottoms stream to a second separations unit containing a metal organic framework (MOF) that selectively adsorbs olefins over paraffins;
(d) desorbing olefins from the MOF in the second separations unit to generate a desorbed olefins stream comprising the olefins and the CO 2 ; and
(e) directing the desorbed olefins stream to a CO 2 removal unit to remove CO 2 from the desorbed olefins stream to generate a substantially CO 2 -free olefins stream.

8. The method of claim 7 , further comprising:
directing the overhead stream enriched with the un-reacted CH 4 and H 2 and at least a portion of the CO 2 removed from the desorbed olefins stream to a methanation unit to generate a methane (CH 4 ) stream; and
directing the CH 4 stream into the OCM reactor.

9. The method of claim 7 , further comprising: directing the substantially CO 2 -free olefins stream to a third separations unit to separate ethylene from propylene.

10. The method of claim 7 , wherein the second separations unit comprises a pressure swing absorber (PSA) that contains the MOF.

11. The method of claim 7 , wherein the second separations unit comprises a temperature swing absorber (TSA) that contains the MOF.

12. The method of claim 7 , wherein the olefins are desorbed from the MOF using ethane, propane or any combination thereof.

13. A method for generating compounds with two or more carbon atoms (C 2+ compounds), comprising:
(a) directing oxygen (O 2 ) and methane (CH 4 ) into an oxidative coupling of methane (OCM) reactor having a catalytic section and a cracking section to produce an OCM product stream, which catalytic section reacts the O 2 and CH 4 to yield ethylene (C 2 H 4 ), ethane (C 2 H 6 ) and heat, which cracking section uses the heat to convert C 2 H 6 into C 2 H 4 , and wherein the OCM product stream comprises C 2+ compounds including C 2 H 6 , un-reacted CH 4 , carbon dioxide (CO 2 ), and hydrogen (H 2 );
(b) directing the OCM product stream into a first separations unit comprising an adsorbent that produces (i) a first light stream comprising un-reacted CH 4 , H 2 , and a first portion of the CO 2 and (ii) a first heavy stream comprising C 2 H 4 , C 2 H 6 , and a second portion of the CO 2 ;
(c) directing the first heavy stream to a CO2 removal unit to separate the second portion of the CO 2 from the first heavy stream to produce a CO 2 -free first heavy stream; and (d) directing the CO 2 -free first heavy stream to a second separations unit comprising a metal organic framework (MOF) to separate the CO 2 -free first heavy stream into a second light stream comprising C 2 H 6 and a second heavy stream comprising C 2 H 4 .

14. The method of claim 13 , further comprising directing the first light stream and a portion of the second portion of the CO 2 to a methanation unit to generate a methane (CH 4 ) stream, and directing the CH 4 stream into the catalytic section of the OCM reactor.

15. The method of claim 13 , wherein the second separations unit comprises a pressure swing absorber (PSA) or a temperature swing absorber (TSA) that contains the MOF.

16. The method of claim 13 , wherein the first separations unit comprises a CaX zeolite and the second separations unit comprises M 2 (dobdc) MOF.

17. The method of claim 13 , further comprising directing a portion of the second light stream to the cracking section of the OCM reactor.

18. The method of claim 13 , further comprising directing a purge gas comprising ethane, propane, or combinations thereof to the first separations unit to desorb components of the first heavy stream from the adsorbent, and directing a purge gas comprising ethane, propane, or combinations thereof to the second separations unit to desorb components of the second heavy stream from the MOF.

Assignees

• Lummus Technology Inc

Inventors

• Jonnavittula Divya
• Chachra Gaurav
• Radaelli Guido

Classifications

• B01D53/047 Primary

  Pressure swing adsorption · CPC title

• Y02C20/20

  of methane · CPC title

• B01D2253/204

  Metal organic frameworks (MOF's) · CPC title

• C07C2/84

  catalytic · CPC title

• B01D53/228

  characterised by specific membranes · CPC title