Method of producing thermoplastic resin

Patent metadata

Field	Value
Publication number	US-10955680-B2
Application number	US-201615769182-A
Country	US
Kind code	B2
Filing date	Nov 2, 2016
Priority date	Nov 4, 2015
Publication date	Mar 23, 2021
Grant date	Mar 23, 2021

Abstract

The present invention provides a method for producing a thermoplastic resin by reacting reactants comprising a dihydroxy compound. In this production method, the dihydroxy compound comprises a dihydroxy compound represented by the following formula (1), and at least one of a compound represented by the following formula (A), a compound represented by the following formula (B), and a compound represented by the following formula (C), wherein the total weight of the compound represented by the formula (A), the compound represented by the formula (B), and the compound represented by the formula (C) is 1,500 ppm or more, based on the weight (100 parts by weight) of the dihydroxy compound represented by the formula (1).

First claim

The invention claimed is:

1. A method for producing a thermoplastic resin by reacting reactants comprising a dihydroxy compound, wherein
the dihydroxy compound comprises
a dihydroxy compound represented by the following formula (1), and
at least one of a compound represented by the following formula (A), a compound represented by the following formula (B), and a compound represented by the following formula (C), wherein
the total weight of the compound represented by the formula (A), the compound represented by the formula (B), and the compound represented by the formula (C) is 1,500 ppm or more, based on the weight (100 parts by weight) of the dihydroxy compound represented by the formula (1),

wherein R 1 and R 2 are each independently selected from the group consisting of a hydrogen atom, an alkyl group containing 1 to 20 carbon atoms, an alkoxy group containing 1 to 20 carbon atoms, a cycloalkyl group containing 5 to 20 carbon atoms, a cycloalkoxy group containing 5 to 20 carbon atoms, an aryl group containing 6 to 20 carbon atoms, and an aryloxy group containing 6 to 20 carbon atoms.

2. The production method according to claim 1 , wherein the weight of the compound represented by the formula (A) in the dihydroxy compound is 1,000 ppm or more, based on the weight (100 parts by weight) of the dihydroxy compound represented by the formula (1).

3. The production method according to claim 1 , wherein the weight of the compound represented by the formula (B) in the dihydroxy compound is 200 ppm or more, based on the weight (100 parts by weight) of the dihydroxy compound represented by the formula (1).

4. The production method according to claim 1 , wherein the weight of the compound represented by the formula (C) in the dihydroxy compound is 200 ppm or more, based on the weight (100 parts by weight) of the dihydroxy compound represented by the formula (1).

5. The production method according to claim 1 , wherein the dihydroxy compound further comprises at least one of a dihydroxy compound represented by the following formula (2) and a dihydroxy compound represented by the following formula (3):

wherein X each independently represents an alkylene group containing 1 to 4 carbon atoms,

wherein R 6 and R 7 are each independently selected from the group consisting of a hydrogen atom, an alkyl group containing 1 to 20 carbon atoms, an alkoxy group containing 1 to 20 carbon atoms, a cycloalkyl group containing 5 to 20 carbon atoms, a cycloalkoxy group containing 5 to 20 carbon atoms, an aryl group containing 6 to 20 carbon atoms, an aryloxy group containing 6 to 20 carbon atoms, and a halogen atom;
Z 1 and Z 2 are each independently selected from the group consisting of an alkylene group containing 1 to 8 carbon atoms, a cycloalkylene group containing 6 to 10 carbon atoms, and an arylene group containing 6 to 10 carbon atoms;
l 1 and l 2 each independently represent an integer of 0 to 5;
Q represents a single bond or is selected from the group consisting of:

wherein R 8 , R 9 , and R 14 to R 17 are each independently selected from the group consisting of a hydrogen atom, an alkyl group containing 1 to 10 carbon atoms, and a phenyl group;
R 10 to R 13 each independently represent a hydrogen atom or an alkyl group containing 1 to 5 carbon atoms;
Z′ represents an integer of 3 to 11; and
R 6 and R 7 may be identical to or different from each other.

6. The production method according to claim 1 , wherein X represents an ethylene group.

7. The production method according to claim 1 , wherein the thermoplastic resin is selected from the group consisting of a polycarbonate resin, a polyester resin, and a polyester carbonate resin.

8. The production method according to claim 7 , wherein the thermoplastic resin is a polycarbonate resin.

9. The production method according to claim 1 , wherein the reactants further comprise carbonic acid diester.

10. The production method according to claim 7 , wherein
the thermoplastic resin is a polyester carbonate resin,
the reactants comprise the dihydroxy compound; carbonic acid diester; and dicarboxylic acid comprising at least one selected from terephthalic acid, 2,6-naphthalenedicarboxylic acid, and fluorene-9,9-dipropionic acid, or derivative of the dicarboxylic acid; and
the molar ratio between the dihydroxy compound and the dicarboxylic acid or a derivative of the dicarboxylic acid (dihydroxy compound/dicarboxylic acid or derivative of the dicarboxylic acid) is 20/80 to 95/5.

11. The production method according to claim 1 , wherein tensile strength is 70% or more.

12. A method for producing a molded body, comprising a step of molding a thermoplastic resin obtained by the production method according to claim 1 .

13. A method for producing an optical material, which is characterized in that it uses a thermoplastic resin obtained by the production method according to claim 1 .

14. A method for producing an optical lens, which is characterized in that it uses a thermoplastic resin obtained by the production method according to claim 1 .

15. A method for producing an optical film, which is characterized in that it uses a thermoplastic resin obtained by the production method according to claim 1 .

16. The production method according to claim 1 , wherein R 1 and R 2 is each independently selected from the group consisting of an alkyl group containing 1 to 20 carbon atoms, an alkoxy group containing 1 to 20 carbon atoms, a cycloalkyl group containing 5 to 20 carbon atoms, a cycloalkoxy group containing 5 to 20 carbon atoms, an aryl group containing 6 to 20 carbon atoms, and an aryloxy group containing 6 to 20 carbon atoms.

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Kato Noriyuki
• Kondo Mitsuteru
• SHIRATAKE Munenori
• Ishihara Kentaro
• Hirose Koji
• Ikeda Shinya

Classifications

• G02B1/04

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title

• C08G64/307 Primary

  and phenols · CPC title

• G02B1/041

  Lenses · CPC title

• C08G63/64 Primary

  Polyesters containing both carboxylic ester groups and carbonate groups · CPC title

• C08G64/06 Primary

  not containing aliphatic unsaturation · CPC title