Multielectrode sensor for concentration and depth measurements in molten salt

Patent metadata

Field	Value
Publication number	US-10955375-B2
Application number	US-201815923155-A
Country	US
Kind code	B2
Filing date	Mar 16, 2018
Priority date	Mar 16, 2018
Publication date	Mar 23, 2021
Grant date	Mar 23, 2021

Abstract

A multi electrode sensor that provides in-situ, real time measurements for molten salts and other process fluids such as real-time concentration and salt level measurements for nuclear systems such as molten salt reactors, nuclear reprocessing facilities utilizing molten salts and concentrated solar power systems. The sensor has multiple electrodes with unique lengths which are connected to a potentiostat. Measurements are taken when the electrodes are immersed in the process fluid.

First claim

The invention claimed is:

1. A multielectrode sensor providing a current per unit depth measurement in a vessel of process fluids, the multielectrode sensor comprising:
an array, the array having a first plug and a plurality of electrodes, the first plug having a top surface and a bottom surface, a plurality of openings extending from the top surface to the bottom surface wherein each of the plurality of openings is spaced equidistant from adjacent openings, each of the plurality of electrodes formed of an inert material;
each of the plurality of electrodes having a bottom end, and a respective predetermined length wherein each respective predetermined length is different, each of the plurality of electrodes removably inserted into one of the plurality of openings such that each of the plurality of bottom ends contact the process fluids at a respective immersion depth wherein each respective immersion depth is different, at least one of the plurality of electrodes being a counter electrode and the remainder of the plurality of electrodes operable as both working electrodes and quasi-reference electrodes;
a plurality of bimodal electrode pairs formed from two adjacent ones of the plurality of electrodes wherein one electrode functions as a working electrode and one electrode functions as a quasi-reference electrode;
a potentiostat in electrical communication with each of the plurality of electrodes, the potentiostat adapted to apply an electroanalytical waveform to each of the plurality of bimodal electrode pairs in a measurement sequence to obtain a current per unit depth of the process fluids at each of the immersion depths.

2. The multielectrode sensor of claim 1 , and further including a controller and a display, the controller and display in electrical communication with the potentiostat.

3. The multielectrode sensor of claim 1 , wherein the first plug is made of non-conductive material.

4. The multielectrode sensor of claim 1 , wherein the first plug is made of ceramic.

5. The multielectrode sensor of claim 1 , further comprising a second plug in the array, wherein the second plug is spaced from the first plug, the second plug having a top surface and a bottom surface, a plurality of openings extending from the top surface to the bottom surface of the second plug wherein each of the plurality of openings of the second plug is spaced equidistant from adjacent openings and aligned with corresponding openings in the first plug, such that each of the plurality of electrodes may be inserted into one of the plurality of openings in each of the first and second plug.

6. The multielectrode sensor of claim 1 , wherein one of the plurality of electrodes may be substituted with a dynamic reference electrode.

7. The multielectrode sensor of claim 1 , wherein one of the plurality of electrodes may be substituted with a thermodynamic reference electrode.

8. The multielectrode sensor of claim 1 , wherein the potentiostat is a multichannel potentiostat.

9. The multielectrode sensor of claim 1 , wherein the potentiostat is a single-channel potentiostat connected to a signal multiplexer.

Assignees

• Us Energy
• Us Dept Energy

Inventors

• Hoyt Nathaniel C
• Williamson Mark A
• Willit James L

Classifications

• G01N27/283 Primary

  Means for supporting or introducing electrochemical probes · CPC title

• G01N27/48

  using polarography, i.e. measuring changes in current under a slowly-varying voltage · CPC title

• G01N27/4166

  measuring a particular property of an electrolyte · CPC title