System and method for carbon dioxide upgrade and energy storage using an ejector

Patent metadata

Field	Value
Publication number	US-10954825-B2
Application number	US-201816642012-A
Country	US
Kind code	B2
Filing date	Aug 29, 2018
Priority date	Aug 29, 2017
Publication date	Mar 23, 2021
Grant date	Mar 23, 2021

Abstract

A method for producing work is disclosed. The method includes increasing the pressure of a working fluid including carbon dioxide from a first pressure at least equal to a triple point pressure to a second pressure above the triple point pressure. The method also includes heating the working fluid, extracting mechanical work by expanding a first portion of the heated working fluid to a third pressure, supplying a second portion of the heated working fluid as a motive fluid to an ejector, increasing the pressure of the expanded working fluid by supplying the expanded working fluid to the ejector to combine with the motive fluid and form an output fluid at the fourth pressure, the fourth pressure at least equal to the triple point pressure of the working fluid. The method also includes refrigerating the output fluid to condense a vapor phase into a liquid phase.

First claim

What is claimed is:

1. A method for producing work, comprising:
increasing the pressure of a working fluid with a pressurization device, from a first pressure at least equal to a triple point pressure of the working fluid to a second pressure above the triple point pressure of the working fluid and higher than the first pressure, the working fluid comprising carbon dioxide;
heating the working fluid with a first heat exchanger until it is substantially one of a vapor and a supercritical fluid;
extracting mechanical work by expanding a first portion of the heated working fluid to a third pressure below the triple point pressure of the working fluid;
supplying a second portion of the heated working fluid as a motive fluid to a high-pressure motive inlet of an ejector;
increasing the pressure of the expanded working fluid from the third pressure to a fourth pressure while decreasing the pressure of the motive fluid to the fourth pressure by supplying the expanded working fluid to a low-pressure inlet of the ejector to combine with the motive fluid to form an output fluid at the fourth pressure, the fourth pressure at least equal to the triple point pressure of the working fluid; and
refrigerating the output fluid received from an outlet of the ejector to condense a vapor phase portion of the output fluid into a liquid phase by exchanging heat between the output fluid from the ejector and a carbon dioxide solid, converting at least a portion of the carbon dioxide solid to at least one of a liquid phase and a vapor phase having a storage pressure at least equal to a triple point pressure of carbon dioxide.

2. The method of claim 1 , wherein the output fluid from the ejector is in direct fluid communication with the carbon dioxide solid.

3. The method of claim 1 , further comprising producing the carbon dioxide solid by extracting heat from at least one of a carbon dioxide liquid and a carbon dioxide vapor at a pressure at least equal to a triple point pressure of carbon dioxide, wherein the production of the carbon dioxide solid is asynchronous from the extraction of mechanical work.

4. The method of claim 1 , wherein refrigerating the output fluid from the ejector is accomplished using a Stirling cooling cycle.

5. The method of claim 4 , wherein a working fluid of the Stirling cooling cycle comprises carbon dioxide.

6. The method of claim 5 , wherein the working fluid of the Stirling cooling cycle is in direct fluid communication with the carbon dioxide solid.

7. A system for producing work, comprising:
a pressurization device communicatively coupled to a second heat exchanger and configured to pressurize a working fluid drawn from the second heat exchanger from a first pressure at least equal to a triple point pressure of the working fluid to a second pressure above the triple point pressure of the working fluid, the working fluid comprising carbon dioxide;
a first heat exchanger in thermal contact with the working fluid pressurized by the pressurization device and configured to heat the working fluid until it is substantially one of a vapor and a supercritical fluid;
an expansion device communicatively coupled to the pressurization device through the first heat exchanger to produce mechanical work by expanding a first portion of the heated working fluid from the second pressure to a third pressure below the triple point pressure of the working fluid;
an ejector communicatively coupled to the expansion device through a low-pressure inlet of the ejector to receive the expanded working fluid at the third pressure, and also communicatively coupled to the pressurization device through a high-pressure motive inlet of the ejector to receive a second portion of the heated working fluid at the second pressure as a motive fluid, and further communicatively coupled to the second heat exchanger through an outlet of the ejector to provide an output fluid at a fourth pressure to the second heat exchanger, the fourth pressure at least equal to the triple point pressure of the working fluid and the output fluid comprising the first and second portions of the working fluid;
wherein the second heat exchanger refrigerates the output fluid to condense a vapor phase portion of the output fluid into at least a liquid phase before being supplied to the pressurization device.

8. The system of claim 7 , further comprising an insulated vessel comprising a carbon dioxide supply in at least a solid phase and a liquid phase, wherein the second heat exchanger refrigerates the output fluid by exchanging heat between the output fluid from the ejector and the carbon dioxide supply of the insulated vessel, converting at least a portion of the carbon dioxide solid to at least one of a liquid phase and a vapor phase having a storage pressure at least equal to the triple point pressure of carbon dioxide.

9. The system of claim 8 , wherein output fluid of the ejector is in direct fluid communication with the carbon dioxide supply of the insulated vessel.

10. The system of claim 8 , further comprising a heat engine thermally coupled to the insulated vessel and configured to extract work from the carbon dioxide supply.

11. The system of claim 10 , wherein the heat engine comprises the second heat exchanger.

12. A method for producing work, comprising:
increasing the pressure of a working fluid with a pressurization device, from a first pressure at least equal to a triple point pressure of the working fluid to a second pressure above the triple point pressure of the working fluid and higher than the first pressure, the working fluid comprising carbon dioxide;
heating the working fluid with a first heat exchanger until it is substantially one of a vapor and a supercritical fluid;
extracting mechanical work by expanding a first portion of the heated working fluid to a third pressure below the triple point pressure of the working fluid;
supplying a second portion of the heated working fluid as a motive fluid to a high-pressure motive inlet of an ejector;
increasing the pressure of the expanded working fluid from the third pressure to a fourth pressure while decreasing the pressure of the motive fluid to the fourth pressure by supplying the expanded working fluid to a low-pressure inlet of the ejector to combine with the motive fluid to form an output fluid at the fourth pressure, the fourth pressure at least equal to the triple point pressure of the working fluid; and
refrigerating the output fluid received from an outlet of the ejector to condense a vapor phase portion of the output fluid into a liquid phase.

13. The method of claim 12 , wherein the pressurization device is a liquid pump.

14. The method of claim 12 , wherein the second pressure is a pressure corresponding to a vapor-liquid equilibrium proximate an atmospheric ambient temperature, and wherein heating the working fluid is accomplished by an ambient source.

15. The method of claim 12 , wherein the second pressure is a pressure corresponding to a vapor-liquid equilibrium below an atmospheric ambient temperature, and wherein heating the working fluid comprises providing refrigeration to an external source.

16. The method of claim 12 , wherein the second pressure is one of a pressure corresponding to a vapor-liquid equilibrium above the atmospheric ambient temperature and a supercritical pressure, and wherein heating the working fluid comprises extracting heat from an external super-ambient temperature source.

17. The method of claim 12 , wherein heating the working fluid comprises transferring heat from a water supply in a liquid phase to the working fl

Assignees

• Univ Arizona State

Inventors

• Cirucci John Frederick
• Lackner Klaus Stephan

Classifications

• Y02C20/40

  of CO2 · CPC title

• F22B1/02

  by exploitation of the heat content of hot heat carriers · CPC title

• F01K3/12

  having two or more accumulators · CPC title

• F28D20/02

  using latent heat · CPC title

• F01K7/22

  the turbines having inter-stage steam heating · CPC title