Electrolytic solution, secondary battery, electronic device, and method of manufacturing electrode
US-2016190545-A1 · Jun 30, 2016 · US
US10954600B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10954600-B2 |
| Application number | US-201615382176-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 16, 2016 |
| Priority date | Dec 16, 2016 |
| Publication date | Mar 23, 2021 |
| Grant date | Mar 23, 2021 |
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An electroplating system includes an enclosure with an interior, an anode lead extending through the enclosure and into the interior, and a porous body. The porous body is supported within the interior of the enclosure for coupling an electroplating solution within the interior with a workpiece. A conduit extends through the enclosure and into the interior of the enclosure to provide a flow of nitrogen enriched air to the interior of enclosure for drying and removing oxygen from the electroplating solution.
Opening claim text (preview).
What is claimed is: 1. An electroplating apparatus, comprising: an enclosure for water sensitive electrolytes having an interior and a plurality of ports for circulating dry inerting gas and electrolyte through the enclosure interior; an air separation module in fluid communication with the enclosure interior for supplying the dry inerting gas to the enclosure interior; a porous body supported within the enclosure interior; and wherein the enclosure is divided by a wall into an inner chamber and an outer chamber, wherein the inner chamber and the outer chamber are fluidly connected by the porous body seated in a work piece aperture, and wherein an anode is disposed within the inner chamber, and wherein the porous body is seated partially within the outer chamber and seated partially within the inner chamber. 2. The apparatus as recited in claim 1 , wherein the dry inerting gas is dry nitrogen enriched air generated in-situ with the air separation module. 3. The apparatus as recited in claim 1 , wherein the air separation module includes a membrane configured to remove oxygen and moisture from compressed air provided thereto. 4. The apparatus as recited in claim 1 , wherein the electrolyte comprises a chloroaluminate ionic liquid. 5. The apparatus as recited in claim 1 , wherein the electrolyte comprises a solid lubricant dispersed within the electrolyte. 6. The apparatus as recited in claim 1 , wherein the ports include an inerting gas inlet port arranged below a surface of liquid electrolyte contained within the enclosure interior. 7. The apparatus as recited in claim 6 , wherein the ports include a vent port arranged above the surface of the liquid electrolyte contained within the enclosure interior. 8. The apparatus as recited in claim 1 , further comprising a recirculation module in fluid communication with the enclosure interior. 9. The apparatus as recited in claim 8 , wherein the ports include a recirculation outlet port fluidly coupling the recirculation module with the enclosure interior. 10. The apparatus as recited in claim 8 , wherein the ports include a recirculation return port fluidly coupling the recirculation module with the enclosure interior. 11. The apparatus as recited in claim 1 , further comprising an anode supported within the enclosure interior. 12. The apparatus as recited in claim 11 , wherein the anode is a sacrificial anode including aluminum. 13. The apparatus as recited in claim 1 , wherein one of the ports is a workpiece aperture, the porous body being seated within the workpiece aperture. 14. The apparatus as recited in claim 13 , further comprising a compression seal extending about the workpiece aperture. 15. An electroplating apparatus, comprising: an enclosure for water sensitive electrolytes having an interior and a plurality of ports for circulating dry inerting gas and electrolyte through the enclosure interior; an anode supported within the enclosure interior; a recirculation module in fluid communication with the enclosure interior through a plurality of the ports; an air separation module in fluid communication with the enclosure interior through one of the port for supplying the dry inerting gas to the enclosure interior to sustaining plating using a non-aqueous electrolyte; and wherein the enclosure is divided by a wall into an inner chamber and an outer chamber, wherein the inner chamber and the outer chamber are fluidly connected by a porous body seated in a work piece aperture, and wherein an anode is disposed within the inner chamber, and wherein the porous body is seated partially within the outer chamber and seated partially within the inner chamber; wherein a recirculation outlet port is in fluid communication with the outer chamber and a recirculation inlet port is arranged within the inner chamber.
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