Lubricating oil composition, lubricating method, and transmission

Patent metadata

Field	Value
Publication number	US-10954463-B2
Application number	US-201716080937-A
Country	US
Kind code	B2
Filing date	Mar 1, 2017
Priority date	Mar 15, 2016
Publication date	Mar 23, 2021
Grant date	Mar 23, 2021

Abstract

Provided are a lubricating oil composition having a high intermetallic friction coefficient and having excellent clutch anti-shudder performance of excellent initial clutch anti-shudder performance and a long clutch anti-shudder lifetime, and a lubrication method and a transmission using the lubricating oil composition. The lubricating oil composition contains an amide compound (A) having a specific structure, a metal-based detergent (B), and at least one phosphorus acid ester (C) selected from an acid phosphate ester and an acid phosphite ester; and the lubrication method and the transmission use the lubricating oil composition.

First claim

The invention claimed is:

1. A lubricating oil composition, comprising:
(A) an amide compound (A) represented by formula (I):

(B) from 0.2% by mass to 2% by mass of a metal-based detergent (B) which is at least one selected from the group consisting of an alkaline earth metal sulfonate, an alkaline earth metal phenate and an alkaline earth metal salicylate; and
(C) from 0.15% by mass to 2% by mass of at least one phosphorus acid ester (C) selected from an acid phosphate ester of formula (II) and an acid phosphite ester of formula (IV);

wherein R 4 and R7 each independently represent an alkyl group or an alkenyl group having 6 or more and 14 or less carbon atoms;
wherein:
a content of hydrocarbon group having 12 carbon atoms as R 1 and R 2 in all R 1 's and R 2 's contained in the amide compound is 30% by mass or more and 75% by mass or less, and a content of hydrocarbon group having 14 carbon atoms as R 1 and R 2 in all R 1 's and R 2 's contained in the amide compound is 5% by mass or more and 40% by mass or less;
R 1 and R 2 each independently represent a hydrocarbon group having 6 or more carbon atoms;
R 3 represents a hydroxyalkyl group having 1 or more and 6 or less carbon atoms, or a group formed through condensation of the hydroxyalkyl group and an acylating agent;
X represents an oxygen atom or a sulfur atom; and
the amide compound (A) is present in an amount from 0.1% by mass to 2% by mass, based on the total amount of the composition.

2. The lubricating oil composition according to claim 1 , wherein, in all R 1 's and R 2 's contained in the amide compound, a content of a dodecyl group is 30% by mass or more and 75% by mass or less, and a content of a tetradecyl group is 5% by mass or more and 40% by mass or less.

3. The lubricating oil composition according to claim 1 , wherein:
R 1 and R 2 contained in the amide compound (A) comprise a dodecyl group, a tetradecyl group and at least one selected from the group consisting of an octyl group, a decyl group, a hexadecyl group, an octadecyl group and an octadecenyl group; and,
in all R 1 's and R 2 's contained in the amide compound, a content of the dodecyl group is 30% by mass or more and 75% by mass or less, a content of the tetradecyl group is 5% by mass or more and 40% by mass or less, and a content of the at least one selected from the group consisting of the octyl group, the decyl group, the hexadecyl group, the octadecyl group and the octadecenyl group is 1% by mass or more and 20% by mass or less.

4. The lubricating oil composition according to claim 1 , wherein:
R 1 and R 2 each are an alkyl group having 6 or more and 24 or less carbon atoms;
R 3 is a hydroxyalkyl group having 1 or more and 2 or less carbon atoms; and
X is an oxygen atom.

5. The lubricating oil composition according to claim 1 , wherein the amide compound (A) is a reaction product formed from a vegetable-derived secondary amine comprising a dodecyl group in an amount of 30% by mass or more and 75% by mass or less, a tetradecyl group in an amount of 5% by mass or more and 40% by mass or less, and at least one selected from an octyl group, a decyl group, a hexadecyl group, an octadecyl group and an octadecenyl group in an amount of 1% by mass or more and 20% by mass or less.

6. The lubricating oil composition according to claim 1 , wherein a nitrogen content derived from the amide compound (A) is 100 ppm by mass or more based on a total amount of the composition.

7. The lubricating oil composition according to claim 1 , wherein a base number of the metal-based detergent (B) is 10 mgKOH/g or more and 700 mgKOH/g or less.

8. The lubricating oil composition according to claim 1 , wherein a metal content derived from the metal-based detergent (B) is 10 ppm by mass or more and 1,000 ppm by mass or less based on a total amount of the composition.

9. The lubricating oil composition according to claim 1 , wherein a phosphorus content derived from the phosphorus acid ester (C) is 100 ppm by mass or more based on the total amount of the composition.

10. The lubricating oil composition according to claim 1 , which is adapted to function as a lubricating oil composition for transmissions.

11. The lubricating oil composition according to claim 1 , which is adapted to function as a lubricating oil composition for continuously variable transmissions.

12. A lubrication method, comprising lubricating a device with the lubricating oil composition of claim 1 .

13. A transmission, comprising the lubricating oil composition of claim 1 .

14. The lubricating oil composition according to claim 1 , wherein:
the amide compound (A) is present in an amount from 0.5% by mass to 2% by mass, based on the total amount of the composition; and
a phosphorus content derived from the phosphorus acid ester (C) is from 200-1,000 ppm by mass based on the total amount of the composition.

Assignees

• Idemitsu Kosan Co

Inventors

• Yanagihara Takashi

Classifications

• C10M141/10 Primary

  at least one of them being an organic phosphorus-containing compound · CPC title

• C10M163/00

  Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10M2215/08

  Amides [having hydrocarbon substituents containing less than thirty carbon atoms] · CPC title

• C10M2215/04

  having amino groups bound to acyclic or cycloaliphatic carbon atoms · CPC title