Optically clear high refractive index adhesives

Patent metadata

Field	Value
Publication number	US-10954418-B2
Application number	US-201415100371-A
Country	US
Kind code	B2
Filing date	Nov 25, 2014
Priority date	Dec 4, 2013
Publication date	Mar 23, 2021
Grant date	Mar 23, 2021

Abstract

Optically clear adhesive compositions contain an elastomeric polymer and a low molecular weight polymeric additive. The elastomeric polymer and the low molecular weight polymeric additive form an acid-base interaction. The refractive index of the adhesive composition is higher than the refractive index of the elastomeric polymer. The adhesive composition may also contain additional domains of liquids, polymers, additives or particles that have a higher refractive index than the elastomeric polymer.

First claim

What is claimed is:

1. An adhesive composition comprising:
a thermoplastic polymeric shell;
a first elastomeric polymer prepared in the thermoplastic polymeric shell; and
a low molecular weight polymeric additive, wherein the first elastomeric polymer and the low molecular weight polymeric additive form an acid-base interaction, and wherein the refractive index of the adhesive composition is higher than the refractive index of the first elastomeric polymer, wherein the adhesive composition is hot melt processable, and wherein the first elastomeric polymer and the low molecular weight polymeric additive upon forming the acid-base interaction is a composition having a refractive index that approximates the refractive index of the thermoplastic polymeric shell, and wherein the refractive index of the adhesive composition is in the range of 1.45-1.50.

2. The adhesive composition of claim 1 , wherein the adhesive composition comprises a pressure sensitive adhesive.

3. The adhesive composition of claim 1 , wherein the adhesive composition is optically transparent.

4. The adhesive composition of claim 1 , where the adhesive composition is optically clear, having a visible light transmission of greater than 90%, and a haze of less than 5%.

5. The adhesive composition of claim 1 , wherein the adhesive composition further comprises domains having a higher refractive index than the first elastomeric polymer, wherein the domains comprise liquids, polymers, additives or particles.

6. The adhesive composition of claim 5 , wherein the domains comprise particles of a thermoplastic polymer, at least some of the particles having an average particle size that is larger than the wavelengths of visible light, where the wavelengths of visible light are 400-700 nanometers, that is, the average particle size is larger than 400 nanometers, and where the adhesive composition is optically clear, having a visible light transmission of greater than 90%, and a haze of less than 5%.

7. The adhesive composition of claim 6 , wherein the particles of thermoplastic polymer comprise particles of polyethylene, ethylene vinyl acetate, ethylene methyl acrylate, ethylene acrylic acid, ethylene acrylic acid ionomers, polypropylene, acrylic polymers, polyphenylene ether, polyphenylene sulfide, acrylonitrile-butadiene-styrene copolymers, polyurethanes, and mixtures and blends thereof.

8. The adhesive composition of claim 1 , wherein the low molecular weight polymeric additive comprises a copolymer prepared from ethylenically unsaturated monomers, the ethylenically unsaturated monomers comprising aromatic monomers, and monomers with acidic functionality or basic functionality, wherein at least one of the aromatic monomers has the formula:

wherein:
Ar is an aromatic group which is unsubstituted or substituted with a substituent selected from the group consisting of Br y and (R 3 ) z wherein y represents the number of bromine substituents attached to the aromatic group and is an integer from 0 to 3; R 3 is a straight or branched alkyl of 2 to 12 carbons; and z represents the number of R 3 substituents attached to the aromatic ring and is an integer from 0 to 1, provided that both y and z are not zero;
X is oxygen, sulfur or —NR 4 —, wherein R 4 is H or C 1 -C 4 alkyl;
n is 0 to 3;
R 1 is an unsubstituted straight or branched alkyl linking group of 2 to 12 carbons;
and
R 2 is either H or CH 3 .

9. The adhesive composition of claim 8 , wherein the low molecular weight polymeric additive comprises a (meth)acrylate copolymer comprising a copolymer of an aromatic monomer in an amount of at least 5 parts by weight per 100 parts by weight of total monomer, the aromatic monomer having the formula:

wherein:
Ar is an aromatic group which is unsubstituted or substituted with a substituent selected from the group consisting of Br y and (R 3 ) z wherein y represents the number of bromine substituents attached to the aromatic group and is an integer from 0 to 3; R 3 is a straight or branched alkyl of 2 to 12 carbons; and z represents the number of R 3 substituents attached to the aromatic ring and is an integer from 0 to 1, provided that both y and z are not zero;
X is oxygen, sulfur or —NR 4 —, wherein R 4 is H or C 1 -C 4 alkyl;
n is 0 to 3;
R 1 is an unsubstituted straight or branched alkyl linking group of 2 to 12 carbons;
and
R 2 is either H or CH 3 .

10. The adhesive composition of claim 9 , wherein the aromatic monomer(s) are selected from the group consisting of 6-(4,6-dibromo-2-isopropyl phenoxy)-1-hexyl acrylate, 6-(4,6-dibromo-2-sec-butyl phenoxy)-1-hexyl acrylate, 2,6-dibromo-4-nonylphenyl acrylate, 2,6-dibromo-4-dodecyl phenyl acrylate, 2-(1-naphthyloxy)-1-ethyl acrylate, 2-(2-naphthyloxy)-1-ethyl acrylate, 6-(1-naphthyloxy)-1-hexyl acrylate, 6-(2-naphthyloxy)-1-hexyl acrylate, 8-(1-naphthyloxy)-1-octyl acrylate, 8-(2-naphthyloxy)-1-octyl acrylate, and phenoxy ethyl acrylate.

11. The adhesive composition of claim 1 , wherein the adhesive composition is crosslinked.

Assignees

• 3M Innovative Properties Co
• 3M Innovation Properties Company

Inventors

• Sherman Audrey A
• Branigan Margot A
• Hamer Craig E
• Behling Ross E
• Augustine Thomas E
• Benson Karl E

Classifications

• C09J133/06 Primary

  of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical · CPC title

• C08F220/1808

  C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate · CPC title

• C09J4/06 Primary

  {Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond} in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00 · CPC title

• C08L33/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• C09J11/08

  Macromolecular additives · CPC title