Method of producing metal powder

Patent metadata

Field	Value
Publication number	US-10953469-B2
Application number	US-201716093803-A
Country	US
Kind code	B2
Filing date	Apr 7, 2017
Priority date	Apr 21, 2016
Publication date	Mar 23, 2021
Grant date	Mar 23, 2021

Abstract

A metal powder having a BET specific surface area of 5 to 250 m2/g is obtained by contacting and mixing together a gas of a metal chloride (metal source gas) and a reducing gas (e.g., hydrogen gas) that have been separately heated so as to instantaneously form fine metal particles based on the gas phase reduction reaction thereof, and collecting the fine metal particles from the gas stream after the reaction.

First claim

The invention claimed is:

1. A method of producing a metal powder including:
a preparatory step of providing a metal chloride gas and a reducing gas;
a gas phase reduction step in which said metal chloride gas and said reducing gas are contacted and mixed together so as to undergo a gas phase reduction reaction to form metal particles in a mixed gas stream formed by said metal gas and said reducing gas; and
a collection step of obtaining a metal powder by collecting the metal particles from the gas stream after said gas phase reduction reaction; wherein,
in said preparatory step, said metal chloride gas and said reducing gas are heated separately from each other, said metal chloride gas being maintained at a temperature lower than a thermal decomposition temperature of said metal chloride;
in said preparatory step, a multiple tube is used, the metal chloride gas is fed into at least one tube of said multiple tube, and the reducing gas is fed into at least the other tube of said multiple tube such that said metal chloride gas and said reducing gas are separately heated in said multiple tube;
in said gas phase reduction step, said metal chloride gas and said reducing gas are contacted together so that the temperature of the mixed gas of said metal chloride gas and said reducing gas becomes higher than a temperature at which said gas phase reduction reaction takes place;
the metal powder obtained through said collection step has a BET specific surface area of 5 to 250 m 2 /g, and
wherein said reducing gas is a hydrogen gas.

2. The production method according to claim 1 , wherein in said gas phase reduction step, after said metal chloride gas and said reducing gas are contacted together, the mixed gas stream is cooled within 0.1 seconds.

3. The production method according to claim 1 , wherein in said gas phase reduction step, said metal chloride gas and said reducing gas meet together and contact together at the gas outlet port of said multiple tube to undergo the gas phase reduction reaction.

4. The production method according to claim 1 , wherein a silicon chloride is used as said metal chloride, and a silicon powder is obtained as said metal powder.

5. The production method according to claim 4 , wherein said silicon chloride is a trichlorosilane or a silicon tetrachloride.

6. The production method according to claim 1 , wherein after having collected the metal particles contained in the gas stream after said reaction, the hydrogen gas is separated from said gas stream and is fed to said preparatory step.

7. The production method according to claim 1 , wherein after having collected the formed metal particles from the gas stream after said reaction, the hydrogen gas and the metal chloride containing the metal particles are separated from said gas stream followed by the recovery of the metal particles contained in the metal chloride that is separated and, thereafter, said metal chloride is fed to said preparatory step.

Assignees

• Tokuyama Corp

Inventors

• Oda Hiroyuki
• Mochizuki Naoto

Classifications

• B22F1/05

  Metallic powder characterised by the size or surface area of the particles · CPC title

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title

• B22F2201/40

  Metal compounds · CPC title

• B22F2201/013

  Hydrogen · CPC title

• C01B33/03

  by decomposition of silicon halides or halosilanes or reduction thereof with hydrogen as the only reducing agent · CPC title