MnZn ferrite core and its production method

Patent metadata

Field	Value
Publication number	US-10950375-B2
Application number	US-201716086381-A
Country	US
Kind code	B2
Filing date	Mar 24, 2017
Priority date	Mar 25, 2016
Publication date	Mar 16, 2021
Grant date	Mar 16, 2021

Abstract

A method for producing a MnZn ferrite core used at a frequency of 1 MHz or more and an exciting magnetic flux density of 75 mT or less, the MnZn ferrite comprising 53-56% by mol of Fe (calculated as Fe 2 O 3 ), and 3-9% by mol of Zn (calculated as ZnO), the balance being Mn (calculated as MnO), as main components, and 0.05-0.4 parts by mass of Co (calculated as Co 3 O 4 ) as a sub-component, per 100 parts by mass in total of the main components (calculated as the oxides); comprising a step of molding a raw material powder for the MnZn ferrite to obtain a green body; a step of sintering the green body and cooling it to a temperature of lower than 150° C. to obtain a sintered body of MnZn ferrite; and a step of conducting a heat treatment comprising heating the sintered body of MnZn ferrite to a temperature meeting Condition 1 of 200° C. or higher, and Condition 2 of (Tc−90)° C. to (Tc+100)° C., wherein Tc is a Curie temperature (° C.) calculated from the percentages by mol of Fe 2 O 3 and ZnO contained in the main components of the MnZn ferrite, keeping the sintered body at the above temperature for a predetermined period of time, and then cooling the sintered body from the keeping temperature at a speed of 50° C./hour or less.

First claim

What is claimed is:

1. A method for producing a MnZn ferrite core comprising 53-56% by mol of Fe (calculated as Fe 2 O 3 ), and 3-9% by mol of Zn (calculated as ZnO), the balance being Mn (calculated as MnO), as main components, and 0.05-0.4 parts by mass of Co (calculated as Co 3 O 4 ) as a sub-component per 100 parts by mass in total of said main components (calculated as said oxides), which is used at a frequency of 1 MHz or more and an exciting magnetic flux density of 75 mT or less; comprising
a step of molding a raw material powder for the MnZn ferrite to obtain a green body;
a step of sintering said green body and cooling it to a temperature of lower than 150° C. to obtain a sintered body of MnZn ferrite; and
a step of conducting a heat treatment comprising heating the sintered body of MnZn ferrite to a temperature meeting the following conditions:
Condition 1: 200° C. or higher, and
Condition 2: (Tc−90)° C. to (Tc+100)° C.,

wherein Tc is a Curie temperature (° C.) calculated from the percentages by mol of Fe 2 O 3 and ZnO contained in the main components of said MnZn ferrite, keeping the sintered body at said temperature for a predetermined period of time, and then cooling the sintered body from said keeping temperature at a speed of 50° C./hour or less.

2. The method for producing a MnZn ferrite core according to claim 1 , wherein said sintering step provides the sintered body of MnZn ferrite with core loss Pcv of less than 4000 kW/m 3 between 0° C. and 120° C., at a frequency of 2 MHz and an exciting magnetic flux density of 50 mT.

3. The method for producing a MnZn ferrite core according to claim 2 , wherein said heat treatment step provides the sintered body of MnZn ferrite with core loss Pcv of less than 1500 kW/m 3 between 0° C. and 120° C., at a frequency of 2 MHz and an exciting magnetic flux density of 50 mT.

4. The method for producing a MnZn ferrite core according to claim 1 , wherein said MnZn ferrite further comprises 0.003-0.015 parts by mass of Si (calculated as SiO 2 ), 0.06-0.3 parts by mass of Ca (calculated as CaCO 3 ), 0-0.1 parts by mass of V (calculated as V 2 O 5 ), and 0-0.3 parts by mass in total of Nb (calculated as Nb 2 O 5 ) and/or Ta (calculated as Ta 2 O 5 ) as sub-components, per 100 parts by mass in total of said main components (calculated as said oxides).

5. The method for producing a MnZn ferrite core according to claim 1 , wherein
said sintering step comprises a temperature-elevating step, a high-temperature-keeping step, and a cooling step;
said high-temperature-keeping step is conducted at a keeping temperature of higher than 1050° C. and lower than 1150° C. in an atmosphere having an oxygen concentration of 0.4-2% by volume; and
said cooling step is conducted in an oxygen concentration in a range of 0.001-0.2% by volume from 900° C. to 400° C., and at a cooling speed of 50° C./hour or more from (Tc+70)° C. to 100° C.

6. The method for producing a MnZn ferrite core according to claim 5 , wherein the cooling speed from said keeping temperature to 100° C. in said cooling step is 50° C./hour or more.

7. A MnZn ferrite core used at a frequency of 1 MHz or more and an exciting magnetic flux density of 75 mT or less, said MnZn ferrite core comprising 53-56% by mol of Fe (calculated as Fe 2 O 3 ), and 3-9% by mol of Zn (calculated as ZnO), the balance being Mn (calculated as MnO), as main components, and 0.05-0.4 parts by mass of Co (calculated as Co 3 O 4 ), 0.003-0.015 parts by mass of Si (calculated as SiO 2 ), 0.06-0.3 parts by mass of Ca (calculated as CaCO 3 ), 0-0.1 parts by mass of V (calculated as V 2 O 5 ), 0.05 parts or less (not including 0) by mass of Nb (calculated as Nb 2 O 5 ), and 0-0.1 parts by mass of Ta (calculated as Ta 2 O 5 ) as sub-components, per 100 parts by mass in total of said main components (calculated as said oxides), and having core loss Pcv of less than 1100 kW/m 3 between 0° C. and 120° C., at a frequency of 2 MHz and an exciting magnetic flux density of 50 mT.

8. The MnZn ferrite core according to claim 7 , wherein
said MnZn-ferrite magnetic core contains Nb, Ta and V as only Nb, a combination of Nb and V, or a combination of Nb and Ta;
the V content is 0-0.05 parts by mass (calculated as V 2 O 5 ), the Nb content is 0.01-0.04 parts by mass (calculated as Nb 2 O 5 ), and the Ta content is 0-0.05 parts by mass (calculated as Ta 2 O 5 ); and
said MnZn-ferrite magnetic core has core loss Pcv of 750 kW/m 3 or less between 0° C. and 120° C., at a frequency of 2 MHz and an exciting magnetic flux density of 50 mT.

Assignees

• Hitachi Metals Ltd

Inventors

• Koyuhara Norikazu
• Miyoshi Yasuharu
• Tada Tomoyuki
• Tanaka Satoru

Classifications

• C04B35/2658 Primary

  Other ferrites containing manganese or zinc, e.g. Mn-Zn ferrites · CPC title

• H01F1/34

  non-metallic substances, e.g. ferrites · CPC title

• H01F41/02

  for manufacturing cores, coils, or magnets (H01F41/14 takes precedence; for dynamo-electric machines H02K15/00) · CPC title

• H01F27/255

  made from particles (H01F27/26 takes precedence) · CPC title

• C04B2235/6583

  Oxygen containing atmosphere, e.g. with changing oxygen pressures · CPC title