Drying/transportation and releasing MFC

Patent metadata

Field	Value
Publication number	US-10947670-B2
Application number	US-201716091156-A
Country	US
Kind code	B2
Filing date	Apr 7, 2017
Priority date	Apr 11, 2016
Publication date	Mar 16, 2021
Grant date	Mar 16, 2021

Abstract

A method of forming an aqueous solution comprising mircrofibrillated cellulose, the method comprising the steps of providing a substantially dry composite material, comprising microfibrillated cellulose and a filler material, wherein said filler material is precipitated onto fibers or fibrils of said microfibrillated cellulose; providing an aqueous media, wherein the method further comprises the step of lowering the pH value of said aqueous media and then mixing said aqueous media with said substantially dry composite material, such that the filler material is released from said microfibrillated cellulose, thus dissolving said microfibrillated cellulose; or the step of mixing said aqueous media with said substantially dry composite material, and then lowering the pH of said mixture, such that the filler material is released from said microfibrillated cellulose, thus releasing said microfibrillated cellulose.

First claim

The invention claimed is:

1. A method of forming an aqueous solution comprising microfibrillated cellulose, the method comprising the steps of:
providing a substantially dry composite material, comprising microfibrillated cellulose and a filler material, wherein said filler material is precipitated onto fibers or fibrils of said microfibrillated cellulose;
providing an aqueous media,
wherein the method further comprises the steps of:
lowering the pH value of said aqueous media to a level at which the filler material decomposes by a method consisting essentially of adding an acidic agent, wherein the acidic agent is any one of hydrochloric acid, sulfuric acid, citric acid, phosphoric acid, and nitric acid,
mixing said aqueous media with said substantially dry composite material, before, at the same time as, or after the step of lowering of the pH,
such that the filler material precipitated onto the fibers or fibrils of said microfibrillated cellulose decomposes and generates carbon dioxide releasing said microfibrillated cellulose.

2. The method as claimed in claim 1 , wherein said filler material is a precipitated filler material being any one of a precipitated calcium carbonate and a precipitated magnesium carbonate, or a mixture thereof, and wherein said precipitated filler material is formed or precipitated onto the fibers of the microfibrillated cellulose by allowing precursors of said precipitated filler to react with each other in the presence of said microfibrillated cellulose.

3. The method as claimed in claim 1 , wherein the aqueous media is a process media in a paper making process.

4. The method as claimed in claim 3 , wherein said process media is any one of a pulp and a stock solution.

5. The method as claimed in claim 1 , wherein the step of mixing is performed under stirring.

6. The method as claimed in claim 1 , wherein the dry composite material is added to the aqueous media at the same time as the pH is lowered.

7. The method as claimed in claim 1 , wherein the concentration of microfibrillated cellulose in the aqueous solution is in the range of 0.1 to 20% based on the total dry content of the aqueous solution.

8. The method as claimed in claim 1 , wherein said substantially dry composite material is added in the form of any one of a powder and a particulate material or a mixture thereof.

9. The method of claim 1 wherein the acidic agent is added in an amount sufficient to break down a buffering effect caused by decomposition of the filler material.

10. The method of claim 1 further comprising:
measuring the pH and adjusting an amount of the acidic agent added.

11. The method of claim 1 further comprising:
providing a suspension of said microfibrillated cellulose;
reacting precursors of the filler material in the presence of said microfibrillated cellulose and precipitating the filler material onto the fibers or fibrils of said microfibrillated cellulose;
drying the suspension to form the substantially dry composite material.

12. The method of claim 1 further comprising:
adding carbon dioxide to a suspension of microbrillated cellulose in an aqueous solution of precursors of the filler material and precipitating the filler material onto the fibers or fibrils of said microfibrillated cellulose;
drying the suspension to form the substantially dry composite material.

Assignees

• Stora Enso Oyj

Inventors

• Räsänen Jari

Classifications

• D21H11/18 Primary

  Highly hydrated, swollen or fibrillatable fibres · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• D21C9/007

  by mechanical or physical means · CPC title

• D21C9/086

  with organic compounds or compositions comprising organic compounds · CPC title

• D21H17/67 Primary

  Water-insoluble compounds, e.g. fillers, pigments · CPC title