Methods of reducing phosphorus content in liquid hydrocarbons
US-10011781-B2 · Jul 3, 2018 · US
US10947463B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10947463-B2 |
| Application number | US-201916563350-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 6, 2019 |
| Priority date | Sep 14, 2018 |
| Publication date | Mar 16, 2021 |
| Grant date | Mar 16, 2021 |
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Methods of reducing a phosphorus content of a liquid hydrocarbon. The liquid hydrocarbon may be co-fed with an olefin to an alkylation unit to produce a low-phosphorus content liquid hydrocarbon product.
Opening claim text (preview).
What is claimed is: 1. A method for reducing phosphorus content, the method comprising: contacting a liquid hydrocarbon with an olefin in an alkylation unit, wherein the liquid hydrocarbon comprises a phosphorus containing compound and wherein the liquid hydrocarbon has an initial octane number; alkylating the liquid hydrocarbon and olefin to produce a product having an octane number greater than the initial octane number of the liquid hydrocarbon, wherein the product has a phosphorus content less than about 35 wtppm. 2. The method according to claim 1 wherein the liquid hydrocarbon comprises C5s and C6s. 3. The method according to claim 1 wherein the phosphorus containing compound is a hydrocarbon soluble phosphine. 4. The method according to claim 1 wherein the phosphorus containing compound is a tributyl phosphine. 5. The method according to claim 1 wherein the phosphorus of the phosphorus containing compound transferred to an acid component contained in the alkylation unit. 6. The method according to claim 1 wherein the product has a phosphorus content less than about 20 wtppm. 7. The method according to claim 1 wherein the product has a phosphorus content less than about 15 wtppm. 8. The method according to claim 1 wherein the product has a phosphorus content less than about 10 wtppm.
Octane number, e.g. motor octane number [MON], research octane number [RON] · CPC title
Heteroatoms content, i.e. S, N, O, P · CPC title
Organic compounds not containing metal atoms · CPC title
Higher olefins · CPC title
Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title
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