Production of upgraded extract and raffinate

Patent metadata

Field	Value
Publication number	US-10947460-B2
Application number	US-201916567218-A
Country	US
Kind code	B2
Filing date	Sep 11, 2019
Priority date	May 25, 2016
Publication date	Mar 16, 2021
Grant date	Mar 16, 2021

Abstract

Systems and methods are provided for producing upgraded raffinate and extract products from lubricant boiling range feeds and/or other feeds having a boiling range of 400° F. (204° C.) to 1500° F. (816° C.) or more. The upgraded raffinate and/or extract products can have a reduced or minimized concentration of sulfur, nitrogen, metals, or a combination thereof. The reduced or minimized concentration of sulfur, nitrogen, and/or metals can be achieved by hydrotreating a suitable feed under hydrotreatment conditions corresponding to relatively low levels of feed conversion. Optionally, the feed can also dewaxed, such as by catalytic dewaxing or by solvent dewaxing. Because excessive aromatic saturation is not desired, the pressure for hydrotreatment (and optional dewaxing) can be 500 psig (˜3.4 MPa) to 1200 psig (˜8.2 MPa).

First claim

The invention claimed is:

1. A method for forming a raffinate and an extract, comprising:
hydrotreating a feedstock having a T5 boiling point of at least 400° F. and a T95 boiling point of 1500° F. or less under hydrotreating conditions comprising less than 15% feed conversion relative to a conversion temperature of 700° F. to form a hydrotreated effluent, the feedstock having a 650° F.+aromatics content of 25 wt % to 90 wt % and a sulfur content of greater than 1000 wppm, the hydrotreated effluent comprising a hydrotreated effluent fraction having a T5 boiling point of at least 400° F., an aromatics content of at least 10 wt %, a sulfur content of less than 1000 wppm, and a combined amount of Ni, V, and Fe of less than 10 wppm; and
performing a solvent extraction on the hydrotreated effluent fraction to form at least a raffinate product having a nitrogen content of less than 50 wppm and an extract product comprising at least 70 wt % aromatics.

2. The method of claim 1 , wherein the raffinate product has a nitrogen content of 10 wppm or less.

3. The method of claim 1 , further comprising dewaxing at least a portion of the hydrotreated effluent fraction prior to performing the solvent extraction.

4. The method of claim 1 , further comprising dewaxing at least a portion of the raffinate product.

5. The method of claim 4 , wherein the dewaxing comprises solvent dewaxing, catalytic dewaxing, or a combination thereof.

6. The method of claim 1 , wherein the hydrotreating conditions comprise exposing the separated fraction to a hydrotreating catalyst at a pressure of 500 psig to 1200 psig, a temperature of 300° C. to 450° C., and a LIISV of 0.1 to 5.0 hr −1 .

7. The method of claim 1 , wherein the feedstock has a sulfur content of at least 2.0 wt %.

8. The method of claim 1 , wherein the feedstock has a 650° F.+aromatics content of less than 50 wt %, and the raffinate product having an aromatics content of 2 wt % to 20 wt %.

9. The method of claim 1 , wherein the feedstock has a 650° F.+aromatics content of 50 wt % to 90 wt %.

10. The method of claim 1 , wherein the hydrotreated effluent fraction has a naphthene content of 30 wt % to 80 wt %, and the extract product having a naphthene content of at least 10 wt %.

11. The method of claim 1 , wherein the feedstock has a nitrogen content of less than 1000 wppm, and wherein the extract product has a nitrogen content of less than 1000 wppm.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Umansky Benjamin S
• Aldous Keith K
• Gleeson James W
• Blok Edward J
• Demmin Richard A

Classifications

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title

• C10G67/0418

  The hydrotreatment being a hydrorefining · CPC title

• C10G2400/30

  Aromatics · CPC title

• C10G21/00

  Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents (C10G17/00, C10G19/00 take precedence) · CPC title

• C10G45/10 Primary

  containing platinum group metals or compounds thereof · CPC title