Method for monitoring cement using polymer-based capsules

Patent metadata

Field	Value
Publication number	US-10947438-B2
Application number	US-202016808487-A
Country	US
Kind code	B2
Filing date	Mar 4, 2020
Priority date	Sep 20, 2016
Publication date	Mar 16, 2021
Grant date	Mar 16, 2021

Abstract

Embodiments provide a method for monitoring structural integrity of a hardened cement. An aramide capsule, a cement, and a water to form a cement slurry. The cement slurry is set to form a hardened cement, where the aramide capsule is embedded in the hardened cement. Imperfections of the hardened cement are detected by measuring electrical resistivity of the hardened cement. The aramide capsule is formed by interfacial polymerization using a surfactant, a dispersed monomer, a crosslinker such that a semi-permeable membrane is formed surrounding a core.

First claim

What is claimed is:

1. A method for monitoring structural integrity of a hardened cement, the method comprising the steps of:
mixing an aramide capsule, a cement, and a water to form a cement slurry, where the aramide capsule is formed by the steps of:
mixing a continuous solvent and a surfactant to produce a continuous phase;
mixing a dispersed solvent and a dispersed monomer to produce a dispersed phase, where the dispersed solvent and the continuous solvent are immiscible;
mixing the continuous phase and the dispersed phase to form a mixture having an emulsion such that the dispersed phase is dispersed as droplets in the continuous phase, where an interface defines the droplets of the dispersed phase dispersed in the continuous phase;
adding a crosslinker to the mixture;
allowing an aramide polymer to form on the interface of the droplets, such that the aramide polymer forms a semi-permeable membrane around a core, where the core contains the dispersed phase, such that the semi-permeable membrane around the core forms the aramide capsule;
allowing the aramide capsule to settle from the mixture;
separating the aramide capsule from the mixture using a separation method; and
drying the aramide capsule such that the core is hollow, where the aramide capsule exists as a free flowing powder;

allowing the cement slurry to set to form the hardened cement, where the aramide capsule is embedded in the hardened cement; and
detecting imperfections of the hardened cement by measuring electrical resistivity of the hardened cement.

2. The method of claim 1 , where the cement slurry has a water-to-cement mass ratio ranging between 0.1 and 0.8.

3. The method of claim 1 , where the aramide polymer of the aramide capsule is present in the cement slurry at a concentration ranging between 0.5% and 5% by weight of the cement.

4. The method of claim 1 , where the aramide capsule has a diameter ranging between 500 and 1,200 microns.

5. The method of claim 1 , where the aramide capsule has a diameter ranging between 10 and 500 microns.

6. The method of claim 1 , where the aramide capsule has a wall thickness ranging between 3 and 5 microns.

7. The method of claim 1 , where the dispersed solvent is selected from the group consisting of water, ethanol, methanol, and combinations of the same.

8. The method of claim 1 , where the dispersed monomer is selected from the group consisting of polyethylenimine, 1,4-diaminobenzene, 1,3-diaminobenzene, 1,6-diaminohexane, and combinations of the same.

9. The method of claim 1 , where the continuous solvent is selected from the group consisting of cyclohexane, chloroform, and combinations of the same.

10. The method of claim 1 , where the crosslinker is 1,3,5-benzenetricarbonyl trichloride.

11. A method for monitoring structural integrity of a cemented wellbore, the method comprising the steps of:
mixing an aramide capsule, a cement, and a water to form a cement slurry, where the aramide capsule is formed by the steps of:
mixing a continuous solvent and a surfactant to produce a continuous phase;
mixing a dispersed solvent and a dispersed monomer to produce a dispersed phase, where the dispersed solvent and the continuous solvent are immiscible;
mixing the continuous phase and the dispersed phase to form a mixture having an emulsion such that the dispersed phase is dispersed as droplets in the continuous phase, where an interface defines the droplets of the dispersed phase dispersed in the continuous phase;
adding a crosslinker to the mixture;
allowing an aramide polymer to form on the interface of the droplets, such that the aramide polymer forms a semi-permeable membrane around a core, where the core contains the dispersed phase, such that the semi-permeable membrane around the core forms the aramide capsule;
allowing the aramide capsule to settle from the mixture;
separating the aramide capsule from the mixture using a separation method; and
drying the aramide capsule such that the core is hollow, where the aramide capsule exists as a free flowing powder;

injecting the cement slurry into a drilled wellbore;
allowing the cement slurry to set to form the cemented wellbore, where the aramide capsule is embedded in the cemented wellbore; and
detecting imperfections of the cemented wellbore by measuring electrical conductivity of the cemented wellbore.

12. The method of claim 11 , where the cement slurry has a water-to-cement mass ratio ranging between 0.1 and 0.8.

13. The method of claim 11 , where the aramide polymer of the aramide capsule is present in the cement slurry at a concentration ranging between 0.5% and 5% by weight of the cement.

14. The method of claim 11 , where the aramide capsule has a diameter ranging between 500 and 1,200 microns.

15. The method of claim 11 , where the aramide capsule has a diameter ranging between 10 and 500 microns.

16. The method of claim 11 , where the aramide capsule has a wall thickness ranging between 3 and 5 microns.

17. The method of claim 11 , where the dispersed solvent is selected from the group consisting of water, ethanol, methanol, and combinations of the same.

18. The method of claim 11 , where the dispersed monomer is selected from the group consisting of polyethylenimine, 1,4-diaminobenzene, 1,3-diaminobenzene, 1,6-diaminohexane, and combinations of the same.

19. The method of claim 11 , where the continuous solvent is selected from the group consisting of cyclohexane, chloroform, and combinations of the same.

20. The method of claim 11 , where the crosslinker is 1,3,5-benzenetricarbonyl trichloride.

Assignees

• Saudi Arabian Oil Co

Inventors

• Contreras Elizabeth Q

Classifications

• C09K8/467 Primary

  containing additives for specific purposes · CPC title

• C04B2103/0062

  Cross-linked polymers · CPC title

• C04B24/121

  Amines, polyamines · CPC title

• C08F283/04

  on to polycarbonamides, polyesteramides or polyimides {(C08F283/004 takes precedence)} · CPC title

• C04B28/02

  containing hydraulic cements other than calcium sulfates · CPC title