Dispersion and inkjet ink composition, light conversion layer, and liquid crystal display element using the dispersion

Patent metadata

Field	Value
Publication number	US-10947403-B2
Application number	US-201716474357-A
Country	US
Kind code	B2
Filing date	Dec 21, 2017
Priority date	Dec 28, 2016
Publication date	Mar 16, 2021
Grant date	Mar 16, 2021

Abstract

A dispersion contains, as essential ingredients, light-emitting nanocrystals, a polymeric dispersant having an amine value of 5 mg/KOH g or more, and a stimulation-responsive curable material that cures in response to an external stimulus.

First claim

The invention claimed is:

1. A dispersion comprising, as essential ingredients, light-emitting nanocrystals, a polymeric dispersant having an amine value of 5 mg KOH/g or more, and at least one stimulation-responsive curable material that cures in response to an external stimulus, wherein
a solubility of a coating film made from the dispersion in a 1% by mass aqueous solution of potassium hydroxide at 25° C. is 3% by mass or less.

2. The dispersion according to claim 1 , wherein the polymeric dispersant has an acid value of 50 mg KOH/g or less.

3. The dispersion according to claim 1 , wherein the polymeric dispersant has a weight-average molecular weight of 1000 or more.

4. The dispersion according to claim 1 , further comprising at least one type of light-diffusing particles.

5. The dispersion according to claim 4 , wherein the light-diffusing particles include at least one selected from the group consisting of titanium oxide, alumina, zirconium oxide, zinc oxide, calcium carbonate, barium sulfate, and silica.

6. The dispersion according to claim 1 , wherein the stimulation-responsive curable material is at least one active radiation-curable monomer or thermosetting resin.

7. The dispersion according to claim 6 , wherein the dispersion is an active radiation-curable dispersion that contains, as essential ingredients, the light-emitting nanocrystals, the polymeric dispersant having an amine value of 8 to 50 mg KOH/g, and the active radiation-curable monomer.

8. The dispersion according to claim 7 , wherein the active radiation-curable monomer is a radically photopolymerizable compound.

9. The dispersion according to claim 7 , further comprising, besides the light-emitting nanocrystals, the basic polymeric dispersant having an amine value of 8 to 50 mg KOH/g, and the active radiation-curable monomer, an active radiation-curable resin selected from the group consisting of urethane (meth)acrylate resins, polyester (meth)acrylate resins, and epoxy (meth)acrylate resins.

10. The dispersion according to claim 7 , wherein the active radiation-curable monomer is a monofunctional (meth)acrylate and/or a multifunctional (meth)acrylate.

11. The dispersion according to claim 7 , further comprising a polymerization initiator.

12. The dispersion according to claim 6 , wherein the stimulation-responsive curable material is a thermosetting resin, the dispersion contains the light-emitting nanocrystals, the light-diffusing particles, the polymeric dispersant, and the thermosetting resin, and the amine value of the polymeric dispersant is 5 mg KOH/g or more.

13. The dispersion according to claim 1 , wherein the stimulation-responsive curable material is insoluble in alkalis.

14. The dispersion according to claim 1 , wherein the dispersion is not a dispersion containing a polymer soluble in alkalis.

15. The dispersion according to claim 1 , wherein a percentage of the light-emitting nanocrystals in the dispersant is between 10% and 70% by mass.

16. The dispersion according to claim 1 , wherein the light-emitting nanocrystals have a core that contains at least one or two or more first semiconductor materials; and
a shell that covers the core and contains a second semiconductor material that is the same as or different than in the core.

17. The dispersion according to claim 1 , wherein the polymeric dispersant has a backbone polyether, polyester, polyalkylene imine, or polyolefin chain and a basic functional group in a resin structure thereof.

18. The dispersion according to claim 1 , further comprising a solvent having a boiling point higher than or equal to 180° C.

19. A light conversion layer comprising a plurality of pixel units, wherein
the pixel units include at least one pixel unit that includes a cured form of a dispersion,
the dispersion comprises, as essential ingredients, light-emitting nanocrystals, a polymeric dispersant having an amine value of 5 mg KOH/g or more, and at least one stimulation-responsive curable material that cures in response to an external stimulus, and
a solubility of a coating film made from the dispersion in a 1% by mass aqueous solution of potassium hydroxide at 25° C. is 3% by mass or less.

20. The light conversion layer according to claim 19 , further comprising a light shield between the pixel units, wherein
the pixel units include:
a first pixel unit that includes the cured form and contains, as the luminescent nanocrystal particles, light-emitting nanocrystals that absorb light with a wavelength between 420 and 480 nm and emit light that has a peak emission wavelength in a range of 605 to 665 nm; and
a second pixel unit that includes the cured form and contains, as the luminescent nanocrystal particles, light-emitting nanocrystals that absorb light with a wavelength between 420 and 480 nm and emit light that has a peak emission wavelength in a range of 500 to 560 nm.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Isonaka Takeshi
• Umezu Yasuo
• Yamaguchi Hidehiko
• Aoki Yoshio
• Sasaki Hirotomo
• Yoshihara Sunao
• Miki Takayuki
• ISHIZUKA Aya
• KIZAKI Takeo

Classifications

• C09D11/50

  Sympathetic, colour changing or similar inks · CPC title

• C09D11/40

  Ink-sets specially adapted for multi-colour inkjet printing · CPC title

• C09D11/38 Primary

  characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title

• G02F1/13

  based on liquid crystals, e.g. single liquid crystal display cells · CPC title

• G02B5/20

  Filters (polarising elements G02B5/30) · CPC title