Liquid ink containing a hydantoin co-solvent

Patent metadata

Field	Value
Publication number	US-10947401-B2
Application number	US-201616311579-A
Country	US
Kind code	B2
Filing date	Oct 17, 2016
Priority date	Oct 17, 2016
Publication date	Mar 16, 2021
Grant date	Mar 16, 2021

Abstract

An example of a liquid ink includes a colorant, a co-solvent, and a balance of water. The co-solvent includes a hydantoin having a general formula (I) or a general formula (II) wherein n is an integer greater than 2 and m is an integer equal to or greater than 2.

First claim

What is claimed is:

1. A liquid ink, comprising:
a colorant;
a co-solvent including a hydantoin having a general formula I

or a general formula II

wherein n is an integer greater than 2 and m is an integer equal to or greater than 2;
a binder consisting of a latex, wherein the latex is a heteropolymer including a hydrophobic component and a hydrophilic component;
a monomer making up the hydrophobic component is selected from the group consisting of methyl methacrylate, butyl acrylate, butyl methacrylate, hexyl acrylate, hexyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, hydroxyethyl acrylate, lauryl acrylate, lauryl methacrylate, octadecyl acrylate, octadecyl methacrylate, isobornyl acrylate, isobornyl methacrylate, stearyl methacrylate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetrahydrofurfuryl acrylate, alkoxylated tetrahydrofurfuryl acrylate, 2-phenoxyethyl methacrylate, benzyl acrylate, ethoxylated nonyl phenol methacrylate, cyclohexyl methacrylate, trimethyl cyclohexyl methacrylate, t-butyl methacrylate, n-octyl methacrylate, trydecyl methacrylate, isodecyl acrylate, dimethyl maleate, dioctyl maleate, acetoacetoxyethyl methacrylate, diacetone acrylamide, pentaerythritol tri-acrylate, pentaerythritol tetra-acrylate, pentaerythritol tri-methacrylate, pentaerythritol tetra-methacrylate, divinylbenzene, styrene, methylstyrenes, vinyl chloride, vinylidene chloride, vinylbenzyl chloride, acrylonitrile, methacrylonitrile, N-vinyl imidazole, N-vinylcarbazole, N-vinyl-caprolactam, and combinations thereof; anda monomer making up the hydrophilic component is selected from the group consisting of acrylic acid, methacrylic acid, ethacrylic acid, dimethylacrylic acid, maleic anhydride, maleic acid, vinylsulfonate, cyanoacrylic acid, vinylacetic acid, allylacetic acid, ethylidineacetic acid, propylidineacetic acid, crotonoic acid, fumaric acid, itaconic acid, sorbic acid, angelic acid, cinnamic acid, styrylacrylic acid, citraconic acid, glutaconic acid, aconitic acid, phenylacrylic acid, acryloxypropionic acid, aconitic acid, phenylacrylic acid, acryloxypropionic acid, vinylbenzoic acid, N-vinylsuccinamidic acid, mesaconic acid, methacroylalanine, acryloylhydroxyglycine, sulfoethyl methacrylic acid, sulfopropyl acrylic acid, styrene sulfonic acid, sulfoethylacrylic acid, 2-methacryloyloxymethane-1-sulfonic acid, 3-methacryoyloxypropane-1-sulfonic acid, 3-(vinyloxy)propane-1-sulfonic acid, ethylenesulfonic acid, vinyl sulfuric acid, 4-vinylphenyl sulfuric acid, ethylene phosphonic acid, vinyl phosphoric acid, vinyl benzoic acid, 2 acrylamido-2-methyl-1-propanesulfonic acid, and combinations thereof; and

a balance of water.

2. The liquid ink as defined in claim 1 wherein:
the colorant is present in the liquid ink in an amount ranging from about 0.5 wt % to about 15 wt %; and
the co-solvent is present in the liquid ink in an amount ranging from about 0.1 wt % to about 30 wt %.

3. The liquid ink as defined in claim 1 , further comprising a surfactant.

4. The liquid ink as defined in claim 3 wherein:
the binder is present in the liquid ink in an amount ranging from about 0.5 wt % to about 15 wt %; and
the surfactant is present in the liquid ink in an amount ranging from about 0.1 wt % to about 20 wt %.

5. The liquid ink as defined in claim 1 , further comprising an additive selected from the group consisting of an antimicrobial agent, a sequestering agent, a viscosity modifier, an anti-kogation agent, and combinations thereof.

6. The liquid ink as defined in claim 5 wherein the additive is present in the liquid ink in an amount ranging from about 0.01 wt % to about 20 wt %.

7. The liquid ink as defined in claim 1 wherein the liquid ink excludes a saccharide.

8. A liquid ink, consisting of:
a colorant;
a co-solvent including a hydantoin having a general formula I

or a general formula II

wherein n is an integer equal to 1 or greater than 2 and m is an integer equal to or greater than 2;
a binder wherein;
the latex binder is a heteropolymer including a hydrophobic component and a hydrophilic component;
a monomer making up the hydrophobic component is selected from the group consisting of methyl methacrylate, butyl acrylate, butyl methacrylate, hexyl acrylate, hexyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, hydroxyethyl acrylate, lauryl acrylate, lauryl methacrylate, octadecyl acrylate, octadecyl methacrylate, isobornyl acrylate, isobornyl methacrylate, stearyl methacrylate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetrahydrofurfuryl acrylate, alkoxylated tetrahydrofurfuryl acrylate, 2-phenoxyethyl methacrylate, benzyl acrylate, ethoxylated nonyl phenol methacrylate, cyclohexyl methacrylate, trimethyl cyclohexyl methacrylate, t-butyl methacrylate, n-octyl methacrylate, trydecyl methacrylate, isodecyl acrylate, dimethyl maleate, dioctyl maleate, acetoacetoxyethyl methacrylate, diacetone acrylamide, pentaerythritol tri-acrylate, pentaerythritol tetra-acrylate, pentaerythritol tri-methacrylate, pentaerythritol tetra-methacrylate, divinylbenzene, styrene, methylstyrenes, vinyl chloride, vinylidene chloride, vinylbenzyl chloride, acrylonitrile, methacrylonitrile, N-vinyl imidazole, N-vinylcarbazole, N-vinyl-caprolactam, and combinations thereof; and
a monomer making up the hydrophilic component is selected from the group consisting of acrylic acid, methacrylic acid, ethacrylic acid, dimethylacrylic acid, maleic anhydride, maleic acid, vinylsulfonate, cyanoacrylic acid, vinylacetic acid, allylacetic acid, ethylidineacetic acid, propylidineacetic acid, crotonoic acid, fumaric acid, itaconic acid, sorbic acid, angelic acid, cinnamic acid, styrylacrylic acid, citraconic acid, glutaconic acid, aconitic acid, phenylacrylic acid, acryloxypropionic acid, aconitic acid, phenylacrylic acid, acryloxypropionic acid, vinylbenzoic acid, N-vinylsuccinamidic acid, mesaconic acid, methacroylalanine, acryloylhydroxyglycine, sulfoethyl methacrylic acid, sulfopropyl acrylic acid, styrene sulfonic acid, sulfoethylacrylic acid, 2-methacryloyloxymethane-1-sulfonic acid, 3-methacryoyloxypropane-1-sulfonic acid, 3-(vinyloxy)propane-1-sulfonic acid, ethylenesulfonic acid, vinyl sulfuric acid, 4-vinylphenyl sulfuric acid, ethylene phosphonic acid, vinyl phosphoric acid, vinyl benzoic acid, 2 acrylamido-2-methyl-1-propanesulfonic acid, and combinations thereof;

a surfactant;
an additive selected from the group consisting of an antimicrobial agent, a sequestering agent, a viscosity modifier, anti-kogation agent, and combinations thereof; and
a balance of water.

9. The liquid ink as defined in claim 8 wherein:
the colorant is present in the liquid ink in an amount ranging from about 0.5 wt % to about 15 wt %;
the co-solvent is present in the liquid ink in an amount ranging from about 0.1 wt % to about 30 wt %;
the latex binder is present in the liquid ink in an amount ranging from about 0.5 wt % to about 15 wt %;
the surfactant is present in the liquid ink in an amount ra

Assignees

• Hewlett Packard Development Co

Inventors

• Zhou Zhang-Lin
• Abelovski Benjamin

Classifications

• C09D11/38

  characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title

• C09D11/033

  characterised by the solvent · CPC title

• C09D11/102

  containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds · CPC title

• C09D11/322 Primary

  Pigment inks · CPC title

• C09D11/037

  characterised by the pigment · CPC title