Compositions for three-dimensional (3d) printing
US-2015344682-A1 · Dec 3, 2015 · US
US10946579B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10946579-B2 |
| Application number | US-201615771893-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 14, 2016 |
| Priority date | Dec 14, 2015 |
| Publication date | Mar 16, 2021 |
| Grant date | Mar 16, 2021 |
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A fabrication process includes: 1) forming an object by 3D printing; 2) smoothing the object by applying a gel to the object to coat at least a portion of the object with a film of the gel; 3) subjecting the object coated with the film to vacuum; and 4) curing the film to yield the object coated with the cured film.
Opening claim text (preview).
What is claimed is: 1. A fabrication process comprising: forming an object by 3D printing having a first rms surface roughness; smoothing the object by applying a gel to the object to coat at least a portion of the object with a film of the gel; subjecting the object coated with the film to vacuum; and curing the film to yield the object coated with the cured film, wherein the cured film has a second root mean square (rms) surface roughness that is 100 nm or less and wherein the first rms surface roughness is at least 10 times greater than the rms surface roughness of the cured film. 2. The fabrication process of claim 1 , wherein a root mean square (rms) surface roughness of the cured film is 20 nm or less to attain an optical quality surface. 3. The fabrication process of claim 2 , wherein the rms surface roughness of the cured film is 10 nm or less. 4. The fabrication process of claim 1 , wherein forming the object is performed by 3D printing with a Stereo-Lithography printer or a wax printer. 5. The fabrication process of claim 1 , further comprising, prior to applying the gel, cleaning the object and subjecting the object to vacuum. 6. The fabrication process of claim 1 , wherein the gel is composed of a pre-polymer based on an alkyl ester of acrylic acid. 7. The fabrication process of claim 1 , wherein the gel is a methacrylate-based gel. 8. The fabrication process of claim 1 , wherein applying the gel is performed using an applicator. 9. The fabrication process of claim 1 , wherein applying the gel is performed by spin-coating, deposition, spaying, screen printing, dropping, dipping, or painting. 10. The fabrication process of claim 1 , wherein subjecting the object coated with the film to vacuum is performed at a pressure of 10 −1 Torr or less. 11. The fabrication process of claim 1 , wherein curing the film is performed by exposing the film to light or heat. 12. The fabrication process of claim 1 , further comprising depositing a metal layer over the cured film to form an optically smooth mirrored surface. 13. The fabrication process of claim 1 , wherein the object coated with the cured film is a mold, and further comprising forming a molded object using the mold. 14. An optical device or an optical device mold formed by the fabrication process of claim 1 , wherein the optical device comprises a reflective lens, a refractive lens, an optically smooth mirrored surface, or a combination thereof. 15. An optical device formed by the fabrication process of claim 1 , wherein the optical device comprises a reflective lens, a refractive lens, an optically smooth mirrored surface, or a combination thereof. 16. An optical device comprising: an object; and a polymer film coating the object and having a root mean square (rms) surface roughness of 100 nm or less, wherein the object is an object having a rms surface roughness of at least 10 times greater than the rms surface roughness of the polymer film and wherein the optical device comprises a reflective lens, a refractive lens, an optically smooth mirrored surface, or a combination thereof. 17. The optical device of claim 16 , wherein the object is a 3D printed object. 18. The optical device of claim 16 , wherein the rms surface roughness of the polymer film is 10 nm or less. 19. The optical device of claim 16 , further comprising a metal layer coating the polymer film, wherein the optical device is a reflective lens comprising an optically smooth mirrored surface. 20. The optical device of claim 16 , wherein the polymer film is composed of a polymer based on an alkyl ester of acrylic acid.
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