Process for feeding a polymerisation catalyst

Patent metadata

Field	Value
Publication number	US-10946357-B2
Application number	US-201716098346-A
Country	US
Kind code	B2
Filing date	Apr 28, 2017
Priority date	May 2, 2016
Publication date	Mar 16, 2021
Grant date	Mar 16, 2021

Abstract

The present invention is directed to a process for feeding a polymerisation catalyst into a polymerisation reactor (7), comprising the steps of: (i) maintaining a catalyst slurry comprising a diluent and a solid catalyst component in a catalyst feed vessel (4); (ii) continuously withdrawing a stream of the catalyst slurry from the catalyst feed vessel (4); and (iii) introducing the withdrawn portion of the catalyst slurry into the polymerisation reactor (7), wherein the catalyst slurry is transferred by using a valveless piston pump (5) from the catalyst feed vessel (4) into the polymerisation reactor (7); the diluent has a dynamic viscosity of from 0.01 to 20 mPas at the conditions within the catalyst feed vessel (4), and wherein the catalyst slurry is transferred along a substantially vertical path downwards from the catalyst feed vessel (4) to the reactor (7).

First claim

The invention claimed is:

1. A process for feeding a polymerisation catalyst into a polymerisation reactor, comprising the steps of:
(i) maintaining a catalyst slurry comprising a diluent and a solid catalyst component in a catalyst feed vessel;
(ii) continuously withdrawing a stream of the catalyst slurry from the catalyst feed vessel; and
(iii) introducing a withdrawn portion of the catalyst slurry into the polymerisation reactor,
wherein the catalyst slurry is transferred by using a valveless piston pump from the catalyst feed vessel into the polymerisation reactor; the diluent has a dynamic viscosity of from 0.01 to 20 mPas at conditions within the catalyst feed vessel, wherein the catalyst slurry is transferred along a substantially vertical path downwards from the catalyst feed vessel to the polymerisation reactor, wherein the diluent is selected from the group consisting of C 3 to C 10 hydrocarbons and mixtures thereof.

2. The process according to claim 1 wherein the diluent is selected from the group consisting of propane, n-butane, isobutane, n-pentane, isopentane and the mixtures thereof.

3. The process according to claim 1 wherein the catalyst is selected from the group consisting of Ziegler-Natta catalysts, metallocene catalysts, late transition metal catalysts and mixtures thereof.

4. The process according to claim 1 comprising a step of allowing the catalyst slurry to settle in the catalyst feed vessel thus forming a concentrated catalyst slurry in a lower part of the feed vessel and a dilute phase in an upper part of the catalyst feed vessel.

5. The process according to claim 1 comprising steps of (iv) introducing a volume of the solid catalyst component into a mixing vessel; (v) introducing a volume of the diluent into the mixing vessel, thereby forming the catalyst slurry; (vi) transferring the catalyst slurry from the mixing vessel to the catalyst feed vessel.

6. The process according to claim 5 wherein the catalyst slurry is allowed to settle in the mixing vessel.

7. The process according to claim 6 comprising a first catalyst feed vessel and a second catalyst feed vessel.

8. The process according to claim 7 wherein the catalyst is withdrawn from one of the first catalyst feed vessel or the second catalyst feed vessel while the other one of the first catalyst feed vessel or the second catalyst feed vessel is being prepared for receiving a new batch of catalyst slurry.

9. The process according to claim 8 comprising a step of monitoring a level of the catalyst slurry by means of a level sensor in the first catalyst feed vessel and the second catalyst feed vessel.

10. The process according to claim 9 comprising steps of stopping a withdrawal of the catalyst slurry from one of the first catalyst feed vessel or the second catalyst feed vessel and starting a withdrawal of the catalyst slurry from the other one of the first catalyst feed vessel or the second catalyst feed vessel in response to a signal from the level sensor.

11. The process according to claim 5 comprising a first catalyst feed vessel and a second catalyst feed vessel.

12. The process according to claim 11 wherein the catalyst slurry is withdrawn from one of the first catalyst feed vessel or the second catalyst feed vessel while the other one of the first catalyst feed vessel or the second catalyst feed vessel is being prepared for receiving a new batch of catalyst slurry.

13. The process according to claim 11 comprising a step of monitoring a level of the catalyst slurry by means of a level sensor in the first catalyst feed vessel and the second catalyst feed vessel.

14. The process according to claim 13 comprising steps of stopping a withdrawal of the catalyst slurry from one of the first catalyst feed vessel or the second catalyst feed vessel and starting a withdrawal of the catalyst slurry from the other one of the first catalyst feed vessel or the second catalyst feed vessel in response to a signal from the level sensor.

15. A process for polymerising at least one olefin in the polymerisation reactor comprising a step of feeding the polymerisation catalyst into the polymerisation reactor with the process according to claim 1 .

16. The process according to claim 15 comprising the step of polymerising at least one olefin in the presence of a polymerisation diluent.

17. The process according to claim 16 wherein the polymerisation diluent is the same as the diluent in the catalyst feed vessel.

18. A process for polymerising at least one olefin in the polymerisation reactor comprising a step of feeding the polymerisation catalyst into the polymerisation reactor by the process according to claim 7 .

19. The process according to claim 18 comprising a step of polymerising at least one olefin in the presence of a polymerisation diluent.

20. The process according to claim 19 wherein the polymerisation diluent is the same as the diluent in the catalyst feed vessel.

Assignees

• Borealis Ag

Inventors

• Leskinen Pauli
• Elovainio Erno
• Nikkilä Katri
• Parjanen Jukka-Pekka
• Aho Jani

Classifications

• B01J8/002

  with a moving instrument · CPC title

• B01J8/0005

  Catalytic processes under superatmospheric pressure (non-catalytic processes B01J3/00) · CPC title

• B01J8/003

  in a downward flow · CPC title

• B01J2208/00212

  Plates; Jackets; Cylinders · CPC title

• B01J8/22

  gas being introduced into the liquid · CPC title