Methods of producing a lithium carbon fluoride primary battery

Patent metadata

Field	Value
Publication number	US-10944109-B2
Application number	US-201916408503-A
Country	US
Kind code	B2
Filing date	May 10, 2019
Priority date	Nov 6, 2014
Publication date	Mar 9, 2021
Grant date	Mar 9, 2021

Abstract

A Li/CFx primary battery having a lithium-based anode and a fluorinated carbon cathode. The fluorinated carbon cathode includes fluorinated carbon nanoparticles. The structure and size distribution of the carbon precursor carbon nanotubes are configured to provide improved battery performance. The fluorinated carbon nanoparticles can be formed by fluorinating carbon nanoparticles using a fluorine-based reactive gas at a temperature in the range from 300 to 600° C., and the fluorinated carbon nanoparticles can further be used to form the cathode of the primary battery. Producing the Li/CFx primary batter can also include heating the fluorinated carbon nanoparticles under an inert atmosphere before the fluorinated carbon nanoparticles are used to form the cathode of the primary battery.

First claim

What is claimed is:

1. A method of producing a Li/CFx primary battery, the method including:
forming fluorinated carbon nanoparticles by fluorinating carbon nanoparticles using a fluorine-based reactive gas at a temperature in the range from 300 to 600 ° C.;
using the fluorinated carbon nanoparticles to form a cathode of the primary battery; and
incorporating the cathode that includes fluorinated carbon nanoparticles with a lithium-based anode.

2. A method of producing a Li/CFx primary battery according to claim 1 , wherein forming the fluorinated carbon nanoparticles comprises forming fluorinated carbon nanoparticles having a number-weighted diameter distribution in which a D10 particle diameter is at least 10 nm.

3. A method of producing a Li/CFx primary battery according to claim 2 , further comprising:
measuring the number-weighted diameter distribution by one or more of scanning electron microscopy, transmission electron microscopy, or atomic force microscopy.

4. A method of producing a Li/CFx primary battery according to claim 1 , wherein forming the fluorinated carbon nanoparticles comprises forming fluorinated carbon nanoparticles having a number-weighted diameter distribution, as measured by scanning electron microscopy, transmission electron microscopy, or atomic force microscopy, in which a D90 particle diameter is at most 300 nm.

5. A method of producing a Li/CFx primary battery according to claim 1 , wherein forming the fluorinated carbon nanoparticles comprises forming fluorinated carbon nanoparticles wherein diameters of substantially all of the fluorinated carbon nanoparticles are in a range from 1 to 500 nm.

6. A method of producing a Li/CFx primary battery according to claim 1 , wherein a value of x is at least 0.3.

7. A method of producing a Li/CFx primary battery according to claim 1 , wherein a value of x is at most 1.2.

8. A method of producing a Li/CFx primary battery according to claim 1 , wherein forming the fluorinated carbon nanoparticles comprises forming fluorinated carbon nanoparticles with a specific surface area of at least 10 m 2 /g.

9. A method of producing a Li/CFx primary battery according to claim 1 , wherein forming the fluorinated carbon nanoparticles comprises forming equiaxed fluorinated carbon nanoparticles.

10. A method of producing a Li/CFx primary battery according to claim 1 , wherein forming the fluorinated carbon nanoparticles comprises forming fluorinated carbon nanoparticles having aspect ratios less than 2.

11. A method of producing a Li/CFx primary battery according to claim 1 , wherein the method further includes:
heating the fluorinated carbon nanoparticles under an inert atmosphere before the fluorinated carbon nanoparticles are used to form the cathode of the primary battery.

12. A method of producing a Li/CFx primary battery according to claim 11 , wherein heating the fluorinated carbon nanoparticles includes heating at a temperature between 100 and 400 ° C.

13. A method of producing a Li/CFx primary battery according to claim 1 , further comprising:
separating the cathode and the anode with a separator.

14. A method of producing a Li/CFx primary battery according to claim 13 , the separator including one or more of polyethylene, polypropylene, glass fibre, polytetrafluoroethylene, polyimide, or cellulose.

15. A method of producing a Li/CFx primary battery according to claim 8 , the specific surface area of at least some of the fluorinated carbon nanoparticles being at least 100 m 2 /g.

16. A method of producing a Li/CFx primary battery according to claim 8 , the specific surface area of at least some of the fluorinated carbon nanoparticles being at least 200 m 2 /g.

17. A method of producing a Li/CFx primary battery according to claim 8 , the specific surface area of at least some of the fluorinated carbon nanoparticles being at least 500 m 2 /g.

18. A method of producing a Li/CFx primary battery according to claim 8 , the specific surface area of the fluorinated carbon nanoparticles being at most 2000 m 2 /g.

19. A method of producing a Li/CFx primary battery according to claim 1 , the lithium-based anode including one or more of boron or magnesium.

20. A method of producing a Li/CFx primary battery according to claim 1 , further comprising:
incorporating an electrolyte including one or more of ethylene carbonate, dimethyl carbonate, diethyl carbonate, dissolved lithium salt, or a molten salt containing lithium and a eutectic composition with at least one of KCl or NaCl.

Assignees

• Schlumberger Technology Corp

Inventors

• Liang Hanpu
• Lawrence Nathan
• Jones Timothy
• Gahlings Steven
• Jarvis Christine
• Li wen rong
• Ramos Rogerio Tadeu
• Solis Vladimir Hernandez

Classifications

• H01M4/623

  fluorinated polymers · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M4/382

  Lithium (H01M4/405 takes precedence) · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• C01P2004/12

  with a cylindrical shape · CPC title