Soft magnetic alloy and magnetic device

Patent metadata

Field	Value
Publication number	US-10943718-B2
Application number	US-201815905027-A
Country	US
Kind code	B2
Filing date	Feb 26, 2018
Priority date	Feb 27, 2017
Publication date	Mar 9, 2021
Grant date	Mar 9, 2021

Abstract

Provided is a soft magnetic alloy including Fe, as a main component, and including C. the soft magnetic alloy includes an Fe composite network phase having Fe-rich grids connected in a continuous measurement range including 80000 grids, each of which size is 1 nm×1 nm×1 nm. An average of C content ratio of the Fe-poor grids having cumulative frequency of 90% or more from lower C content is 5.0 times or more to an average of C content ratio of the whole soft magnetic alloy.

First claim

The invention claimed is:

1. A soft magnetic alloy comprising Fe, as a main component, and comprising C,
wherein
a composition of the soft magnetic alloy is Fe a Cu b M1 c Si d B e C f , in which a+b+c+d+e+f=100, 0.1≤b≤3.0, 1.0≤c≤10.0, 0.0≤d≤17.5, 6.0≤e≤13.0, and 0.0<f≤4.0, and M1 is one or more selected from a group consisting of Nb, Ti, Zr, Hf, V, Ta, Mo, P and Cr,
the soft magnetic alloy comprises an Fe composite network phase having Fe-rich grids connected in a continuous measurement range including 80000 grids, each of which size is 1 nm×1 nm×1 nm,
Fe content ratio of each of the Fe-rich grids is higher than an average of Fe content ratio of the whole soft magnetic alloy,
the continuous measurement range includes Fe-poor grids among the 80000 grids,
Fe content ratio of each of the Fe-poor grids is less than the average of Fe content ratio of the whole soft magnetic alloy, and
an average of C content ratio of the Fe-poor grids having cumulative frequency of 90% or more is 5.1 times or more and 12.5 times or less to an average of C content ratio of the whole soft magnetic alloy.

2. The soft magnetic alloy according to claim 1 , wherein
an average of M1 content ratio of the Fe-poor grids having cumulative frequency of 90% or more is 1.2 times or more to an average of M1 content ratio of the whole soft magnetic alloy.

3. The soft magnetic alloy according to claim 1 , wherein
the average of C content ratio of the whole soft magnetic alloy is 3 atom % or less.

4. The soft magnetic alloy according to claim 1 , wherein
an average of B content ratio of the Fe-poor grids having cumulative frequency of 90% or more is 1.2 times or more to an average of B content ratio of the whole soft magnetic alloy.

5. A magnetic device comprising the soft magnetic alloy according to claim 1 .

6. The soft magnetic alloy according to claim 1 , wherein 0.5≤b≤1.5, 3.0≤c≤5.0, 11.5≤d≤17.5 when M1 is not P, 9.0≤e≤11.0, and 0.1≤f≤4.0.

7. A soft magnetic alloy comprising Fe, as a main component, and comprising C,
wherein
a composition of the soft magnetic alloy is Fe α M2 β B γ C Ω , in which α+β+γ+Ω=100, 1.0≤β≤15.0, 2.0≤γ≤20.0 and 0.0<Ω≤4.0, and M2 is one or more selected from a group consisting of Nb, Cu, Zr, Hf, Ti, V, Ta, Mo, P, Si and Cr,
the soft magnetic alloy comprises an Fe composite network phase having Fe-rich grids connected in a continuous measurement range including 80000 grids, each of which size is 1 nm×1 nm×1 nm,
Fe content ratio of each of the Fe-rich grids is higher than an average of Fe content ratio of the whole soft magnetic alloy,
the continuous measurement range includes Fe-poor grids among the 80000 grids,
Fe content ratio of each of the Fe-poor grids is less than the average of Fe content ratio of the whole soft magnetic alloy, and
an average of C content ratio of the Fe-poor grids having cumulative frequency of 90% or more is 5.1 times or more and 12.5 times or less to an average of C content ratio of the whole soft magnetic alloy.

8. The soft magnetic alloy according to claim 7 , wherein
an average of M2 content ratio of the Fe-poor grids having cumulative frequency of 90% or more is 1.2 times or more to an average of M2 content ratio of the whole soft magnetic alloy.

9. The soft magnetic alloy according to claim 7 , wherein
the average of C content ratio of the whole soft magnetic alloy is 3 atom % or less.

10. The soft magnetic alloy according to claim 7 , wherein
an average of B content ratio of the Fe-poor grids having cumulative frequency of 90% or more is 1.2 times or more to an average of B content ratio of the whole soft magnetic alloy.

11. A magnetic device comprising the soft magnetic alloy according to claim 7 .

12. The soft magnetic alloy according to claim 7 , wherein 5.0≤b≤8.1, 2.0≤γ≤20.0 and 0.1≤Ω≤3.0.

13. The soft magnetic alloy according to claim 12 , wherein 0.5<Ω≤1.0.

14. The soft magnetic alloy according to claim 12 , wherein 4.5≤γ≤18.0 and M2 is Nb.

15. The soft magnetic alloy according to claim 12 , wherein 2.0≤γ≤8.0 and M2 is Zr and/or Hf.

Assignees

• Tdk Corp

Inventors

• Yoshidome Kazuhiro
• Matsumoto Hiroyuki
• Horino Kenji
• Hasegawa Akito
• Yonezawa Yu
• Goto Syota
• Amano Hajime

Classifications

• C22C45/02

  with iron as the major constituent · CPC title

• C22C33/003 Primary

  making amorphous alloys · CPC title

• H01F41/0226

  from amorphous ribbons · CPC title

• C22C33/04

  by melting · CPC title

• C22C33/006

  compositions used for making ferrous alloys · CPC title