Process for conversion of fuel grade coke to anode grade coke

Patent metadata

Field	Value
Publication number	US-10941346-B2
Application number	US-202016844820-A
Country	US
Kind code	B2
Filing date	Apr 9, 2020
Priority date	May 27, 2019
Publication date	Mar 9, 2021
Grant date	Mar 9, 2021

Abstract

A process of conversion of fuel grade coke produced through thermal cracking of heavy petroleum residue to anode grade coke. The process employs high sulfur fuel grade coke as the feedstock to produce low sulfur coke, which can be used to manufacture electrodes for use in the aluminum industry. A related system is adapted to remove metal content from coke and convert fuel grade coke to anode grade coke.

First claim

The invention claimed is:

1. A process for conversion of a fuel grade coke to an anode grade coke, wherein the fuel grade coke comprises 3 to 9 wt % of sulfur, 7 to 13 wt % of a volatile matter, 85 to 91 wt % of a fixed carbon, 200 to 1500 ppm of vanadium, the process comprising:
(a) subjecting the fuel grade coke to thermal treatment in a rotary calciner kiln to produce a thermally treated coke, wherein the volatile matter ranges from 0 to 0.3 wt % and the sulfur ranges from 0.5 to 3 wt % in the thermally treated coke;
(b) mixing the thermally treated coke and a pre-processing adsorbent supplied from an adsorbent vessel in a mixing unit to effect transfer of metals from the thermally treated coke to the pre-processing adsorbent, thereby obtaining an adsorbent-coke mixture including demetallized coke and a metal laden adsorbent, wherein the demetallized coke is obtained by demetallizing the thermally treated coke and the metal laden adsorbent is obtained by increasing metal level in the pre-processing adsorbent;
(c) separating the demetallized coke and the metal laden adsorbent by fluidization;
(d) collecting the separated demetallized coke to obtain the anode grade coke;
(e) collecting the separated metal laden adsorbent and routing the separated metal laden adsorbent as post-processing adsorbent to the adsorbent vessel; and
(f) withdrawing a part of the post-processing adsorbent from the adsorbent vessel and adding a fresh metal free adsorbent to the adsorbent vessel to produce the pre-processing adsorbent supplied to the mixing unit in step (b), with a reduced metal level.

2. The process as claimed in claim 1 , wherein the thermal treatment of the fuel grade coke in step (a) is performed at a temperature ranging from 1250 to 1500° C.

3. The process as claimed in claim 1 , wherein the mixing of step (b) is carried out at a temperature in the range of 680 to 800° C. for a period ranging from 1 to 30 minutes.

4. The process as claimed in claim 1 , wherein the mixing unit of step (b) is a rotary cooler.

5. The process as claimed in claim 4 , wherein the ratio of an adsorbent flow rate to a fuel grade coke flow rate into the rotary cooler ranges from 1:1 to 15:1.

6. The process as claimed in claim 1 , wherein:
the mixing unit includes a fluidized mixer vessel to mix the thermally treated coke and the pre-processing adsorbent; and
the thermally treated coke is crushed to fine powder of 10 to 500 micron size prior to mixing with the pre-processing adsorbent.

7. The process as claimed in claim 6 , wherein the pre-processing adsorbent is heated to a temperature in the range of 680 to 800° C. prior to mixing with the thermally treated coke.

8. The process as claimed in claim 6 , wherein the ratio of adsorbent flow rate to fuel grade coke flow rate into the fluidized mixer vessel ranges from 0.5:1 to 15:1.

9. The process as claimed in claim 1 , wherein the adsorbent is a spherical particle of the size ranging from 10 to 160 microns and comprises:
1 to 40 wt % of a rare earth oxide;
5 to 25 wt % of an alumina;
1 to 9 wt % of a zeolite; and
10 to 45 wt % of a clay,
wherein the weight % being based on the total weight of the adsorbent and the rare earth oxide is selected from the group consisting of lanthanum oxide, cerium oxide and neodymium oxide.

10. A system for conversion of a fuel grade coke to an anode grade coke, the system comprising:
(a) a rotary kiln including:
a feed inlet for introducing into the rotary kiln a feed of the fuel grade coke, wherein the fuel grade coke is thermally treated within the rotary kiln;

(b) an adsorbent vessel that includes:
an inlet for introducing into the adsorbent vessel fresh metal free adsorbent; and
an inlet for introducing into the adsorbent vessel a post-processing adsorbent that is laden with metal,
wherein the adsorbent vessel combines the fresh metal free adsorbent and the post-processing adsorbent to produce a pre-processing adsorbent,

(c) a mixing unit that is fluidly connected to the rotary kiln and to the adsorbent vessel and includes:
an inlet for introducing into the mixing unit the thermally treated coke received from the rotary kiln; and
an inlet for introducing into the mixing unit the pre-processing adsorbent from the adsorbent vessel,
wherein the mixing unit mixes the thermally treated coke and the pre-processing adsorbent to obtain an adsorbent-coke mixture including demetallized coke and metal laden adsorbent, and

(d) a separator vessel in fluid communication with the mixing unit and having an inlet for receiving the adsorbent-coke mixture from the mixing,
wherein the separator vessel separates the adsorbent-coke mixture into:
the demetallized coke for use as anode grade coke; and
the post-processing adsorbent to be introduced into the adsorbent vessel.

11. The system as claimed in claim 10 , wherein the separator vessel includes a fluid inlet for a fluidizing medium that fluidizes and separates the demetallized coke and the post-processing adsorbent.

12. The system as claimed in claim 10 , wherein the mixing unit includes a rotary cooler in fluid communication with the rotary kiln and the adsorbent vessel to cool and mix the thermally treated coke and the pre-processing adsorbent to obtain the adsorbent-coke mixture.

13. The system as claimed in claim 10 , further comprising a cyclone separator is in fluid communication with the separator vessel to recover the fine particles in gases emerging out of the separator vessel for disposal or reuse.

14. The system as claimed in claim 10 , wherein the mixing unit includes:
(i) a rotary cooler in fluid communication with the rotary kiln to receive and cool the thermally treated coke and to obtain a cooled thermally treated coke;
(ii) a crusher section in fluid communication with the rotary cooler to receive and crush the cooled thermally treated coke to obtain a crushed thermally treated coke; and
(iii) a mixer vessel in fluid communication with the crusher section and the adsorbent vessel to mix the crushed thermally treated coke and the pre-processing adsorbent to obtain the adsorbent-coke mixture.

15. The system as claimed in claim 14 , wherein the fresh metal free adsorbent received is a heated adsorbent.

Assignees

• Indian Oil Corp Ltd

Inventors

• Pradeep Ponoly Ramachandran
• Mondal Prantik
• Prasad Terapalli Hari Venkata Devi
• Das Satyen Kumar
• Sau Madhusudan
• Mazumdar Sanjiv Kumar
• RAMAKUMAR Sankara Sri Venkata

Classifications

• B01J20/12

  Naturally occurring clays or bleaching earth · CPC title

• C25C3/125

  based on carbon · CPC title

• B01D45/16

  generated by the winding course of the gas stream {, the centrifugal forces being generated solely or partly by mechanical means, e.g. fixed swirl vanes} · CPC title

• B01J20/28004

  Sorbent size or size distribution, e.g. particle size · CPC title

• B01J20/18

  Synthetic zeolitic molecular sieves · CPC title