Rubber composition for hollow ball and hollow ball

Patent metadata

Field	Value
Publication number	US-10940369-B2
Application number	US-201816160543-A
Country	US
Kind code	B2
Filing date	Oct 15, 2018
Priority date	Oct 30, 2017
Publication date	Mar 9, 2021
Grant date	Mar 9, 2021

Abstract

A rubber composition for a hollow ball includes a base rubber, an inorganic filler composed of a large number of flat particles, and a carbon-based filler. As to the carbon-based filler, a degree of flatness DLc obtained by dividing an average particle diameter D50c (μm) by an average thickness Tc (μm) is not less than 50. A weight ratio Mc/Mi is not less than 0.01 and not greater than 1.00. The rubber composition is obtained by a production method including: a first step of mixing the base rubber and the carbon-based filler to obtain a master batch; and a second step of adding the large number of flat particles that form the inorganic filler, to the master batch to orient the large number of flat particles. The hollow ball 2 includes a core 4 formed from the rubber composition.

First claim

What is claimed is:

1. A rubber composition for a hollow ball, the rubber composition including a base rubber, an inorganic filler composed of particles, and a carbon-based filler, wherein
a degree of flatness DLc obtained by dividing an average particle diameter D 50 c (μm) of the carbon-based filler by an average thickness Tc (μm) of the carbon-based filler is not less than 110,
a weight ratio Mc/Mi of an amount Mc of the carbon-based filler to an amount Mi of the inorganic filler is not less than 0.04 and not greater than 1.00,
a degree of flatness DLi obtained by dividing an average particle diameter D 50 i (μm) of the inorganic filler by an average thickness Ti (μm) of the inorganic filler is not less than 20, and an amount of the inorganic filler per 100 parts by weight of the base rubber is not less than 1 parts by weight and not greater than 150 parts by weight.

2. The rubber composition according to claim 1 , wherein a nitrogen gas permeability coefficient N 2A (cm 3 ·cm/cm 2 /sec/cmHg) at 40° C. of the rubber composition satisfies the following formula (1),
N 2A /N 2B ≤0.95  (1)

wherein N 2B is a nitrogen gas permeability coefficient (cm 3 ·cm/cm 2 /sec/cmHg) at 40° C. of a rubber composition obtained by replacing the carbon-based filler having a degree of flatness DLc of not less than 50 with a carbon-based filler having a degree of flatness DLc of 1.

3. The rubber composition according to claim 1 , wherein the carbon-based filler includes carbon atoms by not less than 90% by weight of entire components thereof.

4. The rubber composition according to claim 1 , wherein the carbon-based filler is selected from the group consisting of carbon fibers, graphites, graphenes, and carbon nanotubes.

5. The rubber composition according to claim 1 , wherein the average particle diameter D 50 c of the carbon-based filler is not less than 0.01 μm and not greater than 100 μm.

6. The rubber composition according to claim 1 , wherein the inorganic filler is selected from the group consisting of talc, kaolin clay, and mica.

7. The rubber composition according to claim 1 , wherein the average particle diameter D 50 i of the inorganic filler is not less than 0.01 μm and not greater than 100 μm.

8. The rubber composition according to claim 1 , wherein the base rubber includes a butadiene rubber and a natural rubber, and a weight ratio B/N of an amount B of the butadiene rubber to an amount N of the natural rubber in the base rubber is not greater than 1.4.

9. The rubber composition according to claim 1 , wherein the rubber composition has a sulfur content of not less than 0.01% by weight and not greater than 10% by weight.

10. The rubber composition according to claim 1 , wherein the rubber composition has a nitrogen gas permeability coefficient N 2A at 40° C. of not greater than 3.0×10 −9 (cm 3 ·cm/cm 2 /sec/cmHg).

11. The rubber composition according to claim 1 , wherein the rubber composition has a Shore A hardness Ha of not less than 20 and not greater than 88.

12. The rubber composition according to claim 1 , wherein the rubber composition has a loss tangent tan δ at 20° C. of not greater than 1.0.

13. The rubber composition according to claim 1 , wherein a product of a Shore A hardness Ha of the rubber composition and elongation at break EB (%) of the rubber composition obtained according to JIS K6251 is not less than 1,000 and not greater than 100,000.

14. The rubber composition according to claim 1 , wherein a product of a Shore A hardness Ha of the rubber composition and a toluene swelling ratio SW (%) of the rubber composition obtained according to JIS K6258 is not less than 2,500 and not greater than 50,000.

15. The rubber composition according to claim 1 , wherein the hollow ball is a tennis ball.

16. A method for producing a rubber composition for a hollow ball, the method comprising:
a first step of mixing a base rubber and a carbon-based filler having a degree of flatness particle diameter D 50 c (μm) of the carbon-based filler by an average thickness Tc (μm) of the carbon-based filler; and
a second step of adding an inorganic DLc of not less than 110, to obtain a master batch, the degree of flatness DLc being obtained by dividing an average filler composed of particles to the master batch to orient the particles that form the inorganic filler, in the base rubber, wherein
a weight ratio Mc/Mi of an amount Mc of the carbon-based filler to an amount Mi of the inorganic filler is not less than 0.04 and not greater than 1.00,
a degree of flatness DLi obtained by dividing an average particle diameter D 50 i (μm) of the inorganic filler by an average thickness Ti (μm) of the inorganic filler is not less than 20, and an amount of the inorganic filler per 100 parts by weight of the base rubber is not less than 1 parts by weight and not greater than 150 parts by weight.

17. A hollow ball comprising a hollow core formed from a rubber composition, wherein
the rubber composition includes a base rubber, an inorganic filler composed of particles, and a carbon-based filler,
a degree of flatness DLc obtained by dividing an average particle diameter D 50 c (μm) of the carbon-based filler by an average thickness Tc (μm) of the carbon-based filler is not less than 110,
a weight ratio Mc/Mi of an amount Mc of the carbon-based filler to an amount Mi of the inorganic filler is not less than 0.04 and not greater than 1.00,
a degree of flatness DLi obtained by dividing an average particle diameter D 50 i (μm) of the inorganic filler by an average thickness Ti (μm) of the inorganic filler is not less than 20, and an amount of the inorganic filler per 100 parts by weight of the base rubber is not less than 1 parts by weight and not greater than 150 parts by weight.

Assignees

• Sumitomo Rubber Ind

Inventors

• Hyodo Takehiko
• Taguchi Masanori
• Shiga Kazuyoshi
• Suzuki Fumiya
• Tanaka Hiroaki
• Niwa Kunio

Classifications

• A63B39/00

  Hollow non-inflatable balls {, i.e. having no valves (rigid balls A63B37/00)} · CPC title

• C08K3/041

  Carbon nanotubes · CPC title

• C08K2201/016

  Additives defined by their aspect ratio · CPC title

• C08K3/346

  Clay · CPC title

• C08K2201/008

  Additives improving gas barrier properties · CPC title