Fiber-reinforced composite material, laminate, pipe, riser pipe, and flow line

Patent metadata

Field	Value
Publication number	US-10935169-B2
Application number	US-201716097855-A
Country	US
Kind code	B2
Filing date	Apr 11, 2017
Priority date	May 2, 2016
Publication date	Mar 2, 2021
Grant date	Mar 2, 2021

Abstract

Provided is a fiber-reinforced composite material having a greater maximum stress, maximum elongation, and tensile modulus, which are determined by a tensile test, than conventional fiber-reinforced composite materials containing a fluororesin as a matrix. The invention relates to a fiber-reinforced composite material including a fluororesin and a reinforcing fiber, the fluororesin containing a tetrafluoroethylene unit and a vinylidene fluoride unit, the tetrafluoroethylene unit representing 55 to 95 mol % of all the monomer units constituting the fluororesin, the vinylidene fluoride unit representing 45 to 5 mol % of all the monomer units constituting the fluororesin.

First claim

The invention claimed is:

1. A fiber-reinforced composite material comprising a fluororesin and a reinforcing fiber,
the fluororesin containing a tetrafluoroethylene unit and a vinylidene fluoride unit,
the tetrafluoroethylene unit representing 55 to 95 mol % of all the monomer units constituting the fluororesin,
the vinylidene fluoride unit representing 45 to 5 mol % of all the monomer units constituting the fluororesin,
wherein the fiber-reinforced composite material has a maximum elongation of 1% or greater.

2. The fiber-reinforced composite material according to claim 1 ,
wherein the fluororesin further contains at least one unit of an ethylenically unsaturated monomer selected from the group consisting of:
ethylenically unsaturated monomers represented by the following formula (1):
CX 11 X 12 ═CX 13 (CX 14 X 15 ) n11 X 16

wherein X 11 to X 16 are the same as or different from each other, and are each H, F, or Cl; and n 11 is an integer of 0 to 8, excluding tetrafluoroethylene and vinylidene fluoride; and
ethylenically unsaturated monomers represented by the following formula (2):
CX 21 X 22 ═CX 23 —O(CX 25 X 25 ) n21 X 26

wherein X 21 to X 26 are the same as or different from each other, and are each H, F, or Cl; and n 21 is an integer of 0 to 8.

3. The fiber-reinforced composite material according to claim 1 ,
wherein the fluororesin and the reinforcing fiber have a mass ratio of 10:90 to 90:10.

4. The fiber-reinforced composite material according to claim 1 ,
wherein the fiber-reinforced composite material has a maximum stress of 50 MPa or greater.

5. The fiber-reinforced composite material according to claim 1 ,
wherein the fiber-reinforced composite material has a tensile modulus of 1000 MPa or greater.

6. The fiber-reinforced composite material according to claim 1 ,
wherein the reinforcing fiber is in the form of a sheet.

7. The fiber-reinforced composite material according to claim 1 ,
wherein the reinforcing fiber is a reinforcing fiber woven fabric.

8. The fiber-reinforced composite material according to claim 1 ,
wherein the reinforcing fiber is at least one selected from the group consisting of carbon fiber, glass fiber, basalt fiber, metal fiber, aramid fiber, polyethylene fiber, polyamide fiber, silicon carbide fiber, polyester fiber, ceramic fiber, alumina fiber, boron fiber, mineral fiber, rock fiber, slag fiber, plant fiber, polyoxymethylene fiber, aromatic polyamide fiber, polyparaphenylene benzobisoxazole fiber, cellulose fiber, and lignin fiber.

9. The fiber-reinforced composite material according to claim 1 ,
wherein the reinforcing fiber has a tensile modulus of 100 to 1000 GPa.

10. The fiber-reinforced composite material according to claim 1 ,
wherein the reinforcing fiber has a tensile strength of 2000 to 10000 MPa.

11. The fiber-reinforced composite material according to claim 1 ,
wherein the fiber-reinforced composite material is a tape.

12. The fiber-reinforced composite material according to claim 11 ,
wherein the tape has a band shape having flexibility that allows the tape to be coiled.

13. A pipe comprising:
a first layer; and
a second layer disposed on the first layer,
the second layer including the fiber-reinforced composite material according to claim 11 ,
the first layer and the second layer being stacked in the given order from the inside of the pipe,
the second layer being formed from the tape wrapped around the outer surface of the first layer.

14. A laminate comprising:
a first layer; and
a second layer disposed on the first layer,
the second layer including the fiber-reinforced composite material according to claim 1 .

15. A pipe comprising the laminate according to claim 14 .

16. The pipe according to claim 15 ,
wherein the first layer is a flexible tube.

17. A riser pipe comprising the pipe according to claim 15 .

18. A flowline comprising the pipe according to claim 15 .

19. The fiber-reinforced composite material according to claim 1 ,
wherein the reinforcing fiber comprises fibers having an average fiber length of 100 mm or longer.

Assignees

• Daikin Ind Ltd

Inventors

• Kuwajima Yuuki
• Tsuda Hayato
• Inaba Takeshi

Classifications

• B32B2597/00

  Tubular articles, e.g. hoses, pipes · CPC title

• B32B2262/108

  Rockwool fibres · CPC title

• B32B2262/106

  Carbon fibres, e.g. graphite fibres · CPC title

• B32B2262/105

  Ceramic fibres · CPC title

• B32B2262/103

  Metal fibres · CPC title