Preparation method and application of the multicomponent composite sulfides lubricant film

Patent metadata

Field	Value
Publication number	US-10934612-B2
Application number	US-202016943841-A
Country	US
Kind code	B2
Filing date	Jul 30, 2020
Priority date	Nov 9, 2018
Publication date	Mar 2, 2021
Grant date	Mar 2, 2021

Abstract

The invention relates to a multi-component composite sulfide solid lubricating film prepared by sulfurizing the surface of a high-entropy alloy. The high-entropy alloy is composed of five metal elements of Co, Cr, Fe, Ni and Mo or six metal elements of Co, Cr, Fe, Ni, Mo and W. The multi-component composite sulfide solid lubricating film of the invention is mainly applied to the friction pair surface of mechanical equipment, the lubricating film and the sulfurized base have high bonding strength, and multi-component composite sulfide solid lubricating films containing different sulfide lubricating phases can be chose and prepared according to the service environment of equipment.

First claim

What is claimed is:

1. A multi-component composite sulfide solid lubricating film prepared by sulfurizing the surface of an alloy, wherein
the alloy consists of five metal elements of Co, Cr, Fe, Ni and Mo or six metal elements of Co, Cr, Fe, Ni, Mo and W, and the atomic mole percentage of each element ranges from 5% to 35%;
the sulfurizing method is a low-temperature ion sulfurization, and the low-temperature ion sulfurization is carried out at a vacuum degree of 10 tor, a pulse voltage of 550V-700V, a sulfurization temperature of 180° C.-280° C., in the presence of hydrogen sulfide gas as sulfurization gas and hydrogen and argon as protective gas; and
the thickness of the multi-component composite sulfide solid lubricating film is 3-5 μm.

2. The multi-component composite sulfide solid lubricating film according to claim 1 , wherein the low-temperature ion sulfurization treatment specifically comprises: placing the alloy on a cathode tower in an ion sulfurization furnace body, allowing the alloy to be connected to a cathode of the ion sulfurization furnace and a furnace wall to be connected to an anode, starting a vacuum pump, applying a pulse voltage of 550V-700V between the anode and cathode when the vacuum degree reaches 10 tor, introducing hydrogen and a small amount of argon into the furnace to produce a glow discharge phenomenon, bombarding the surface of the alloy near the cathode at a high speed by the obtained hydrogen ions and argon ions; and when the sulfurization temperature is between 180° C. and 280° C., and the temperature in the furnace reaches 180° C.-280° C., introducing hydrogen sulfide to sulfurize the alloy of the cathode, wherein the temperature holding time in sulfurization is for 2-2.5 hours.

3. A metal workpiece with high wear resistance, wherein the multi-component composite sulfide solid lubricating film according to claim 1 is attached to the surface of the metal workpiece.

4. The metal workpiece with high wear resistance according to claim 3 , wherein the metal workpiece is a sliding bearing, a low-speed gearbox gear, a stamping die, a rock drill piston, or a cylinder sleeve.

5. A preparation method of the metal workpiece with high wear resistance according to claim 3 , comprising the following steps: (1) mixing the alloy metal powder uniformly and then ball milling to a particle size of 300 meshes; (2) carrying out surface treatment on a base material, and cladding the alloy metal powder prepared in step (1) on the surface of the base material by laser cladding technology; (3) fine grinding and polishing to a surface roughness of 0.4 um; and (4) carrying out the low-temperature ion sulfurization technology for sulfurization treatment.

6. The method according to claim 5 , wherein the low-temperature ion sulfurization treatment specifically comprises: placing the alloy on a cathode tower in an ion sulfurization furnace body, allowing the alloy to be connected to a cathode of the ion sulfurization furnace and a furnace wall to be connected to an anode, starting a vacuum pump, applying a pulse voltage of 550V-700V between the anode and cathode when the vacuum degree reaches 10 tor, introducing hydrogen and a small amount of argon into the furnace to produce a glow discharge phenomenon, bombarding the surface of the alloy near the cathode at a high speed by the obtained hydrogen ions and argon ions; and
when the temperature in the furnace reaches 180° C. -280° C., introducing hydrogen sulfide to sulfurize the alloy of the cathode, wherein the sulfurization temperature is between 180° C. and 280° C., and the temperature holding time in sulfurization is 2-2.5 hours.

Assignees

• Univ China Petroleum East China

Inventors

• Han Bin
• Cui Gang
• Li Meiyan
• Wang Yong

Classifications

• B22F1/17

  Metallic particles coated with metal · CPC title

• Y02P10/25

  Process efficiency · CPC title

• B22F2003/242

  Coating · CPC title

• B22F10/25

  Direct deposition of metal particles, e.g. direct metal deposition [DMD] or laser engineered net shaping [LENS] · CPC title

• B22F7/08

  with one or more parts not made from powder {(B22F7/062 takes precedence)} · CPC title