Liquid crystal composition, liquid crystal mixture, reverse-mode polymer dispersed liquid crystal element, and associated selectively dimmable device

Patent metadata

Field	Value
Publication number	US-10934486-B2
Application number	US-201916373431-A
Country	US
Kind code	B2
Filing date	Apr 2, 2019
Priority date	Oct 7, 2016
Publication date	Mar 2, 2021
Grant date	Mar 2, 2021

Abstract

Described herein are liquid crystal compositions and derivative mixtures thereof that can allow for the adjustment of their refractive indices by the application of an electric field. In addition, selectively dimmable reverse-mode polymer dispersed liquid crystal (PDLC) elements and devices using the aforementioned compositions are also described, which are transparent when no voltage is applied and opaque when a voltage is applied.

First claim

What is claimed is:

1. A liquid-crystalline composition comprising:
(1) a polymer created by polymerization of a monomer of a formula:

wherein m and n are independently 1, 2, 3, 4, 5, or 6, and o and p are independently 0 or 1; and
(2) a liquid crystalline mixture comprising a first liquid crystalline (LC) compound of a formula:

wherein R 1 is H or CH 3 ; R 2 , R 3 , R 4 , R 5 , R 6 , R 2 , R 8 , R 9 , and R 10 are independently H, CH 3 , or F, wherein at least one of R 1 and R 3 is CH 3 ; X is C 2-8 alkyl or C 3-7 —O-alkyl; Y is F or CN; and
q and r are independently 0 or 1;
wherein the liquid crystalline mixture is dispersed within the polymer.

2. The liquid-crystalline composition of claim 1 , wherein the first liquid crystalline compound is further represented by the formula:

3. The liquid-crystalline composition of claim 2 , wherein X is:

4. The liquid-crystalline composition of claim 1 , wherein the first liquid crystalline compound is:

5. The liquid-crystalline composition of claim 1 , wherein the liquid crystal mixture further comprises at least one second liquid crystalline compound of the formula:

wherein R 11 is C 3-9 alkyl or C 3-9 —O-alkyl, Cy 1 is cyclohexyl or phenyl, Cy 2 is a single covalent bond or phenyl; and Y 3 is CN or —NCS.

6. The liquid-crystalline composition of claim 5 , wherein the second liquid crystalline compound comprises:

or a combination thereof;
wherein the combination of the first liquid crystalline compound and the second crystalline compound(s) forms a liquid crystal mixture.

7. The liquid-crystalline composition of claim 1 , further comprising a chiral dopant.

8. The liquid-crystalline composition of claim 7 wherein the chiral dopant is R-octan-2-yl 4-((4-(hexyloxy)benzoyl)oxy)benzoate.

9. The liquid-crystalline composition of claim 1 , further comprising an initiator.

10. A liquid crystal element comprising:
a transparency changing layer comprising the liquid-crystalline composition of claim 1 , having a first surface and a second surface; and
a first alignment layer bounding the first surface and a second alignment layer bounding the second surface.

11. A dimmable device comprising:
the liquid crystal element of claim 10 disposed between a first conductive substrate and a second conductive substrate; and
a voltage source; wherein:
the liquid crystal element, the first conductive substrate, the second conductive substrate, and the voltage source are all in electrical communication such that when a voltage is applied by the voltage source an electric field is applied across the liquid crystal element.

12. The device of claim 11 , wherein the device has a haze of at most 7% when there is no voltage applied across the device.

13. The device of claim 11 , wherein the device has a haze of at least 28% when a voltage of at least 60 volts is applied across the device.

14. The device of claim 11 , wherein the substrates are flexible so that the device forms a flexible sheet.

15. The device of claim 11 , further comprising a sealant to protect the liquid crystal element from the environment.

16. The device of claim 11 , further comprising a removable backing.

Assignees

• Nitto Denko Corp

Inventors

• Khan Sazzadur Rahman
• Luu Hiep
• Sambandan Ekambaram

Classifications

• C09K19/3059

  in which at least two rings are linked by a carbon chain containing carbon to carbon triple bonds · CPC title

• C09K2019/183

  Ph-Ph-C≡C-Ph · CPC title

• C09K19/586

  Optically active dopants; chiral dopants · CPC title

• C09K19/544

  as dispersing or encapsulating medium around the liquid crystal · CPC title

• C09K19/12

  at least two benzene rings directly linked, e.g. biphenyls · CPC title