High temperature hydrate inhibitors and methods of use

Patent metadata

Field	Value
Publication number	US-10934470-B2
Application number	US-201515769038-A
Country	US
Kind code	B2
Filing date	Dec 18, 2015
Priority date	Dec 18, 2015
Publication date	Mar 2, 2021
Grant date	Mar 2, 2021

Abstract

Compositions and methods of using of such compositions to, for example, inhibit of the formation of gas hydrate agglomerates are provided. In one embodiment, the methods comprise: introducing a low-dosage hydrate inhibitor additive into a fluid, wherein the low-dosage hydrate inhibitor additive comprises a quaternary or tertiary ammonium cation moiety, a lipophilic tail, and a sulfonate anion moiety; and exposing the low-dosage hydrate inhibitor additive to a temperature above about 200° F.

First claim

What is claimed is:

1. A method comprising:
introducing a low-dosage hydrate inhibitor additive into a fluid, wherein the low-dosage hydrate inhibitor additive comprises at least one compound having the structural formula:

wherein each of R 1 and R 2 is independently a C 1 to C 6 hydrocarbon chain,
wherein R 3 is selected from the group consisting of hydrogen and a C 1 to C 6 hydrocarbon chain,
wherein R 4 is a C 1 to C 50 hydrocarbon chain, and
wherein R 5 is an organic moiety; and

exposing the low-dosage hydrate inhibitor additive to at least one temperature above about 200° F., wherein the low-dosage hydrate inhibitor additive does not substantially degrade for up to about 7 days after being substantially continually exposed to at least one temperature of above about 200° F.

2. The method of claim 1 wherein the organic moiety is selected from the group consisting of: an alkyl group, an alkenyl group, an aryl group, an arylalkyl group, an arylalkenyl group, an alkylaryl group, an alkenylaryl group, a heterocyclic group, a hydroxyl group, a carbonyl group, an amine group, and any combination thereof.

3. The method of claim 1 wherein the fluid comprises at least one component selected from the group consisting of: water, a gas, a liquid hydrocarbon, and any combination thereof.

4. The method of claim 1 wherein the low-dosage hydrate inhibitor additive is introduced into a quaternary ammonium cation moiety or a tertiary ammonium cation moiety the fluid through a conduit or an injection point having at least one temperature above about 200° F. and the low-dosage hydrate inhibitor additive is exposed to at least one temperature above about 200° F. in the conduit or the injection point.

5. The method of claim 1 wherein the fluid has at least one temperature above about 200° F. and the low-dosage hydrate inhibitor additive is exposed to at least one temperature above about 200° F. in the fluid.

6. The method of claim 1 wherein the fluid resides within a location selected from the group consisting of: a conduit, a wellbore, a subterranean formation, and a vessel.

7. The method of claim 1 wherein the fluid comprises water and has a water cut of from about 1% to about 65%.

8. The method of claim 1 wherein the fluid comprises water and has a water cut of about 50% or greater.

9. The method of claim 1 wherein the low-dosage hydrate inhibitor additive is introduced in an amount such that the low-dosage hydrate inhibitor additive is present in the fluid in an amount from about 0.1% to about 10% volume based on the water cut of the fluid.

10. The method of claim 1 wherein the water is selected from the group consisting of: brine, deionized water, and any combination thereof.

11. A method comprising:
introducing a low-dosage hydrate inhibitor additive into a wellhead of a wellbore penetrating at least a portion of a subterranean formation having at least one temperature above about 200° F., wherein the low-dosage hydrate inhibitor additive does not substantially degrade for up to about 7 days after being substantially continually exposed to at least one temperature of above about 200° F., wherein the low-dosage hydrate inhibitor additive comprises at least one compound having the structural formula:

wherein each of R 1 and R 2 is independently a C 1 to C 6 hydrocarbon chain,
wherein R 3 is selected from the group consisting of hydrogen and a C 1 to C 6 hydrocarbon chain,
wherein R 4 is a C 1 to C 50 hydrocarbon chain, and
wherein R 5 is an organic moiety; and

allowing the low-dosage hydrate inhibitor additive to contact a fluid in the wellbore.

12. The method of claim 11 wherein the fluid comprises at least one component selected from the group consisting of: water, a gas, a liquid hydrocarbon, and any combination thereof.

13. The method of claim 11 wherein the fluid comprises water and has a water cut of about 50% or greater.

14. The method of claim 11 wherein wellbore has at least one temperature from about 250° F. to about 350° F.

15. A method comprising:
introducing a low-dosage hydrate inhibitor additive into a conduit having at least one temperature above about 200° F. and containing a fluid, wherein the low-dosage hydrate inhibitor additive does not substantially degrade for up to about 7 days after being substantially continually exposed to at least one temperature of above about 200° F., wherein the low-dosage hydrate inhibitor additive comprises at least one compound having the structural formula:

wherein each of R 1 and R 2 is independently a C 1 to C 6 hydrocarbon chain,
wherein R 3 is selected from the group consisting of hydrogen and a C 1 to C 6 hydrocarbon chain,
wherein R 4 is a C 1 to C 50 hydrocarbon chain, and
wherein R 5 is an organic moiety.

16. The method of claim 15 wherein the fluid comprises at least one component selected from the group consisting of: water, a gas, a liquid hydrocarbon, and any combination thereof.

17. The method of claim 15 wherein the conduit has at least one temperature from about 250° F. to about 350° F.

Assignees

• Halliburton Energy Services Inc
• Multi Chem Group Llc

Inventors

• Lan Qiang
• Monteiro Deepak
• Ceglio Ii Mark Paul
• Acosta Erick J
• Krishnamurthy Pushkala

Classifications

• C09K2208/22

  Hydrates inhibition by using well treatment fluids containing inhibitors of hydrate formers · CPC title

• C09K8/584

  characterised by the use of specific surfactants · CPC title

• C09K8/52 Primary

  Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning · CPC title

• E21B37/06

  using chemical means for preventing or limiting {, e.g. eliminating,} the deposition of paraffins or like substances · CPC title

• C09K8/602

  containing surfactants · CPC title