Polycarbonate compositions having improved adhesion to polyurethane layers

Patent metadata

Field	Value
Publication number	US-10934429-B2
Application number	US-201916259638-A
Country	US
Kind code	B2
Filing date	Jan 28, 2019
Priority date	Oct 18, 2013
Publication date	Mar 2, 2021
Grant date	Mar 2, 2021

Abstract

Compositions are provided comprising A) at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyester carbonate, B) at least one mixture comprising at least one butadiene-based graft polymer prepared by emulsion, suspension or solution polymerization and at least one polybutadiene-free vinyl (co)polymer, and C) at least one polymer additive, where the polybutadiene content based on the sum total of the parts by weight of components A and B is 10% to 20% by weight, and where the total content of butadiene-free vinyl (co)polymer from component B based on the sum total of the parts by weight of components A and B is 12% to 23% by weight. Composite components formed from these compositions and a polyurethane layer, which are notable for improved adhesion between the two layers, and a process for producing the composite components are also provided.

First claim

What is claimed is:

1. A composite component comprising:
a) a carrier consisting of a thermoplastic composition consisting of:
A) 55 to 75 parts by weight of at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyester carbonate;
B) 25 to 45 parts by weight of at least one mixture comprising at least one polybutadiene-based graft polymer prepared by emulsion, suspension or solution polymerization and at least one polybutadiene-free vinyl (co)polymer; and
C) 0.1 to 20.0 parts by weight (based in each case on the sum total of components A and B) of at least one polymer additive, where the polybutadiene content based on the sum total of the parts by weight of components A and B is 12% to 17% by weight;
wherein the total content of butadiene-free vinyl (co)polymer from component B based on the sum total of the parts by weight of components A and B is 12% to 23% by weight, and where the sum total of the parts by weight of components A and B in the polycarbonate composition is normalized to 100; and

b) at least one polyurethane layer selected from the group consisting of coating materials, foams and compact skins, comprising:
at least one polyisocyanate component;
least one polyfunctional H-active compound; and
optionally at least one polyurethane additive and/or processing aid,
having a molar ratio of NCO- to H-active groups of 1:1 to 1.1:1.

2. The composite component according to claim 1 , wherein the butadiene-based graft polymer of component B) is prepared by emulsion polymerization.

3. The composite component according to claim 1 , wherein the polybutadiene-based graft polymer comprises:
B.1 5% to 95% by weight, based on the graft polymer, of at least one vinyl monomer on
B.2 95% to 5% by weight, based on the graft polymer, of one or more polybutadiene graft bases.

4. The composite component according to claim 3 , wherein component B.1 comprises mixtures of:
B.1.1, comprising 50% to 99% by weight, based on B.1, of at least one of styrene, α-methylstyrene, p-methylstyrene, and p-chlorostyrene; and
B.1.2, comprising 1% to 50% by weight, based on B.1, of at least one of acrylonitrile, methacrylonitrile, anhydrides, and imides.

5. The composite component according to claim 4 , wherein component B.1.2 comprises at least one of maleic anhydride and N-phenylmaleimide.

6. The composite component according to claim 1 , wherein the polybutadiene-based graft polymer comprises:
B.1 25% to 50% by weight, based on the graft polymer, of at least one vinyl monomer on
B.2 50% to 75% by weight, based on the graft polymer, of one or more polybutadiene graft bases, wherein the gel content of component B.2 is at least 60% by weight, based on B.2 and measured in the insoluble component in toluene.

7. The composite component according to claim 6 , wherein the aromatic polycarbonate is based on bisphenol A and has a weight-average molecular weight in the range of 23,000 to 30,000 grams per mole.

8. The composite component according to claim 1 comprising:
57 to 74 parts by weight of component A);
26 to 43 parts by weight of component B); and
0.2 to 15.0 parts by weight of component C);
wherein the polybutadiene content based on the sum total of the parts by weight of components A) and B) is 12% to 17% by weight;
wherein the total content of butadiene-free vinyl (co)polymer from component B), based on the sum total of the parts by weight of components A) and B), is 12% to 20% by weight, and where the sum total of the parts by weight of components A) and B) in the polycarbonate composition has been normalized to 100.

9. The composite component according to claim 1 comprising:
64 to 73 parts by weight of component A);
27 to 36 parts by weight of component B); and
0.3 to 10.0 parts by weight of component C);
wherein the polybutadiene content based on the sum total of the parts by weight of components A) and B) is 12% to 17% by weight and where the total content of butadiene-free vinyl (co)polymer from component B), based on the sum total of the parts by weight of components A) and B), is 13% to 19% by weight, and where the sum total of the parts by weight of components A) and B) in the polycarbonate composition has been normalized to 100.

10. The composite component according to claim 1 wherein component C) comprises at least one polymer additive selected from the group consisting of thermal stabilizers, demoulding agents, colourants and UV absorbers.

11. The composite component according to claim 1 , wherein the polyurethane layer is a coating material having a layer thickness of 50 μm to 300 μm.

12. The composite component according to claim 1 , wherein the polyurethane layer is a foam having a layer thickness of 1 mm to 1 cm.

13. The composite component according to claim 1 , wherein the polyurethane layer is a compact skin having a layer thickness of 1 mm to 4 mm.

14. The composite component according to claim 13 , wherein a graft base of the polybutadiene-based graft polymer has a median particle size in a range of 0.2 μm to 0.5 μm, the polybutadiene-based graft polymer does not contain methyl methacrylate, and no graft polymers which have been prepared by bulk polymerization are present.

15. The composite component according to claim 1 configured as an interior or exterior component of a rail vehicle, aircraft or motor vehicle and for electrical/electronic components and IT components.

16. A process for producing a composite component according to claim 1 , wherein the polyurethane layer has been produced by full polymerization of a reactive polyurethane raw material mixture comprising:
at least one polyisocyanate component;
at least one polyfunctional H-active compound; and
optionally at least one polyurethane additive and/or processing aid;
in direct contact with the carrier which has been shaped beforehand from the thermoplastic composition and solidified.

17. A process for producing a composite component according to claim 1 , wherein
(i) the melt of the thermoplastic composition is injected into a first mould cavity and then cooled;
(ii) the cooled thermoplastic component is transferred into a larger cavity and a defined gap is produced thereby;
(iii) the gap which thus results between the thermoplastic component and the mould surface of the enlarged cavity is injected with a reactive polyurethane raw material mixture comprising:
at least one polyisocyanate component;
at least one polyfunctional H-active compound; and
optionally at least one polyurethane additive and/or processing aid;
the polyurethane raw material mixture polymerizing fully in direct contact with the surface of the thermoplastic carrier to give a compact polyurethane layer or to give a polyurethane foam layer,

(iv) the composite component is demoulded from the mould cavity, and wherein (i) to (iv) following one another in immediate succession.

18. The process according to claim 16 , wherein in (iii) the surface of the injection mould in contact with the thermoplastic composition is heated to a temperature in the range of 60 to 90° C. and the surface of the injection mould in contact with the reactive polyurethane mixture to a temperature in the range of 60 to 90° C.

Assignees

• Covestro Deutschland Ag

Inventors

• Hufen Ralf
• Eckel Thomas
• Hobeika Sven
• Kuhlmann Timo
• Scherer Johannes

Classifications

• C08J5/00

  Manufacture of articles or shaped materials containing macromolecular substances (manufacture of semi-permeable membranes B01D67/00 - B01D71/00) · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C08L33/00

  Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers · CPC title

• B29C45/1676

  using a soft material and a rigid material, e.g. making articles with a sealing part · CPC title

• B32B2605/08

  Cars · CPC title