Polyorganosiloxane, polycarbonate-polyorganosiloxane copolymer, and production method therefor

Patent metadata

Field	Value
Publication number	US-10934392-B2
Application number	US-201816182049-A
Country	US
Kind code	B2
Filing date	Nov 6, 2018
Priority date	Mar 31, 2014
Publication date	Mar 2, 2021
Grant date	Mar 2, 2021

Abstract

Provided is a polyorganosiloxane, wherein a value obtained by integrating dw/d log(M) from 2.5≤log(M)≤3.1 is 0 to 10% of a value obtained by integrating dw/d log(M) over the entire range of log (M) in a differential molecular weight distribution curve, wherein the differential molecular weight distribution curve is determined by gel permeation chromatography using the polystyrene calibration curve, has an x-axis showing a logarithmic value log(M) of a molecular weight M and has a y-axis showing dw/d log(M) obtained by differentiating a concentration fraction w with respect to the logarithmic value log(M) of the molecular weight.

First claim

The invention claimed is:

1. A method for producing a polycarbonate-polyorganosiloxane copolymer, comprising
reacting a dihydric phenol with a carbonate precursor in an organic solvent to produce a polycarbonate oligomer,
mixing the polycarbonate oligomer, a polyorganosiloxane and a dihydric phenol in a water-insoluble organic solvent, and
reacting the mixture,
wherein
the polyorganosiloxane has a value obtained by integrating dw/d log(M) from 2.5≤log(M)≤3.1 is 0 to 10% of a value obtained by integrating dw/d log(M) over the entire range of log (M) in a differential molecular weight distribution curve, wherein the differential molecular weight distribution curve is determined by gel permeation chromatography using the polystyrene calibration curve, has an x-axis showing a logarithmic value log(M) of a molecular weight M and has a y-axis showing dw/d log(M) obtained by differentiating a concentration fraction w with respect to the logarithmic value log(M) of the molecular weight.

2. The method for producing a polycarbonate-polyorganosiloxane copolymer according to claim 1 , wherein the dw/d log(M) value becomes maximum in the range of 3.3≤log(M)≤3.9, in the differential molecular weight distribution curve.

3. The method for producing a polycarbonate-polyorganosiloxane copolymer according to claim 1 , wherein an average chain length of the polyorganosiloxane is in the range of 20 to 50.

4. The method for producing a polycarbonate-polyorganosiloxane copolymer according to claim 1 , wherein the polyorganosiloxane is represented by the following general formula (1) or (2);

wherein, R 1 to R 4 each independently represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms: Y represents —R 5 O—, —R 5 COO—, —R 5 NH—, —R 5 NR 6 —, —COO—, —S—, —R 5 COO—R 7 —O—, or —R 5 O—R 8 —O—; R 5 represents a single bond, a linear, branched, or cyclic alkylene group, an aryl-substituted alkylene group, an arylene group, or a diarylene group; R 6 represents an alkyl group, an alkenyl group, an aryl group, or an aralkyl group; R 7 represents a diarylene group; R 8 represents a linear, branched, or cyclic alkylene group, or a diarylene group; Z represents a hydrogen atom or a halogen atom; β represents a divalent group derived from a diisocyanate compound, or a divalent group derived from a dicarboxylic acid or a halogenated dicarboxylic acid; p and q each independently represents 0 or an integer of 1 or more, a sum of p and q is n and n represents an average repeat number in the range of 20 to 50.

Assignees

• Idemitsu Kosan Co

Inventors

• Ishikawa Yasuhiro
• Abe Tomoko

Classifications

• C08G77/20

  containing silicon bound to unsaturated aliphatic groups · CPC title

• C08L83/10

  Block- or graft-copolymers containing polysiloxane sequences (obtained by polymerising a compound having a carbon-to-carbon double bond on to a polysiloxane C08L51/08, C08L53/00) · CPC title

• C08G77/38

  Polysiloxanes modified by chemical after-treatment · CPC title

• C08G64/186 Primary

  containing polysiloxane sequences · CPC title

• C08G77/26

  nitrogen-containing groups · CPC title