Composition and method of preparation

Patent metadata

Field	Value
Publication number	US-10933011-B2
Application number	US-201616084009-A
Country	US
Kind code	B2
Filing date	Nov 8, 2016
Priority date	Mar 14, 2016
Publication date	Mar 2, 2021
Grant date	Mar 2, 2021

Abstract

A composition comprises (A) a silicone elastomer. The (A) silicone elastomer comprises the reaction product of: (a) an organohydrogensiloxane having an average of at least two silicon-bonded hydrogen atoms per molecule; (b) a crosslinking agent having an average of at least two ethylenically unsaturated groups per molecule; and (c) a hydrosilylation catalyst. The reaction product is formed in the in the presence of (d) a silicone polyether polymer; and (e) particles. The composition further comprises (B) a carrier fluid. The (e) particles are dispersed in the (A) silicone elastomer in the composition. A method of preparing the composition is also disclosed.

First claim

The invention claimed is:

1. A composition comprising:
(A) a silicone elastomer comprising the reaction product of a reaction of:
(a) an organohydrogensiloxane having an average of at least two silicon-bonded hydrogen atoms per molecule;
(b) a crosslinking agent having an average of at least two ethylenically unsaturated groups per molecule; and
(c) a hydrosilylation catalyst;
in the presence of:
(d) a silicone polyether polymer; and
(e) particles; and

(B) a carrier fluid;
wherein said (b) crosslinking agent comprises an α,ω-unsaturated hydrocarbon or a polyoxyalkylene; and
wherein said (e) particles are dispersed in said (A) silicone elastomer.

2. The composition of claim 1 , wherein said (a) organohydrogensiloxane comprises siloxy units of average formula:
(R 1 3 SiO 1/2 ) v (R 2 2 SiO 2/2 ) x (R 2 HSiO 2/2 ) y

wherein each R 1 independently is hydrogen or R 2 , each R 2 independently is a substituted or unsubstituted hydrocarbyl group, v≥2, x≥0, and y≥2.

3. The composition of claim 1 , wherein said (b) crosslinking agent comprises said α,ω-unsaturated hydrocarbon.

4. The composition of claim 3 , wherein said α,ω-unsaturated hydrocarbon comprises an α,ω-diene of the formula CH 2 =CH(CH 2 ) b CH═CH 2 , an α,ω-diyne of the formula C≡C(CH 2 ) b C≡CH, an α,ω-ene-yne of the formula CH 2 =CH(CH 2 ) b C≡CH, or mixtures thereof, where b is independently from 0 to 20.

5. The composition of claim 1 , wherein said (b) crosslinking agent comprises said polyoxyalkylene.

6. The composition of claim 5 , wherein said polyoxyalkylene has the general formula:
R 3 O—[(C 2 H 4 O) c (C 3 H 6 O) d (C 4 H 8 O) e ]—R 3

wherein each R 3 independently is a monovalent unsaturated aliphatic hydrocarbon group containing 2 to 12 carbon atoms, c is from 0 to 200, d is from 0 to 200, and e is from 0 to 200, with the proviso that c, d and e are not simultaneously 0.

7. The composition of claim 1 , wherein said (A) silicone elastomer is mixed with said (B) carrier fluid under shear to give said composition.

8. The composition of claim 1 , wherein said (d) silicone polyether polymer and said (e) particles are combined with one another to give a premix such that said (A) silicone elastomer is prepared in the presence of said premix.

9. The composition of claim 1 , wherein said (d) silicone polyether polymer includes at least one pendent polyether group.

10. The composition of claim 1 , wherein said (d) silicone polyether polymer has the general formula:
Y—[SiR 4 R 5 O] f [SiR 4 R 6 O] g [SiR 4 R 5 O] h [SiR 4 R 7 O] i —Y 1

wherein Y and Y 1 are independently selected terminal groups; each R 4 independently is R 5 , R 6 , or R 7 ; each R 5 independently is a substituted or unsubstituted hydrocarbyl group; each R 6 independently is a polyether-containing group; each R 7 independently is R 5 , a hydroxy-containing group, or X′—Si(OSiR 8 3 ) 3 , where X′ is a divalent linking group and each R 8 independently is a substituted or unsubstituted hydrocarbyl group; f≥0; g≥0; h≥0, and i≥0 with the proviso that f, g, h and i are not simultaneously 0, and with the proviso that said (d) silicone polyether polymer includes at least one polyether-containing group represented by R 6 .

11. The composition of claim 1 , wherein said (d) silicone polyether polymer comprises the following units in any location:
(C 2 H 4 O) c ′(C 3 H 6 O) d ′(C 4 H 8 O) e ′[SiR 5 2 O] f′ [SiR 5 R 6 O] g ′

wherein each R 5 independently is selected from a substituted or unsubstituted hydrocarbyl group and R 6 , each R 6 independently is a polyether-containing group, c′≥0, d′≥0, e′≥0, f′≥0, and g′≥0, with the proviso that c′, d′ and e′ are not simultaneously 0, and with the proviso that f′ and g′ are not simultaneously 0.

12. The composition of claim 1 , wherein said (e) particles are a solid.

13. The composition of claim 1 , wherein said (e) particles are further defined as a personal care ingredient.

14. The composition of claim 13 , wherein said personal care ingredient is further defined as a skin care ingredient, and wherein said skin care ingredient is selected from water phase stabilizing agents, cosmetic biocides, conditioning agents, emollients, moisturizers, colorants, dyes, ultraviolet (UV) absorbers, sunscreen agents, antiperspirants, antioxidants, fragrances, antimicrobial agents, antibacterial agents, antifungal agents, antiaging actives, anti-acne agents, skin-lightening agents, pigments, preservatives, pH controlling agents, electrolytes, chelating agents, plant extracts, botanical extracts, sebum absorbents, sebum control agents, vitamins, waxes, surfactants, detergents, emulsifiers, thickeners, propellant gases, skin protectors, film-forming polymers, light-scattering agents, and combinations thereof.

15. The composition of claim 13 , wherein said personal care ingredient is further defined as a hair care ingredient, and wherein said hair care ingredient is selected from conditioning agents, colorants, dyes, ultraviolet (UV) absorbers, preservatives, plant extracts, fatty alcohols, vitamins, fragrance, anti-dandruff agents, color care additives, pearlising agents, pH controlling agents, electrolytes, chelating agents, styling agents, ceramides, amino-acid derivatives, suspending agents, surfactants, detergents, emulsifiers, thickeners, oxidizing agents, reducing agents, film-forming polymers, and combinations thereof.

16. The composition of claim 1 as an emulsion.

17. A method of preparing a composition, said method comprising:
combining (a) an organohydrogensiloxane having an average of at least two silicon-bonded hydrogen atoms per molecule; (b) a crosslinking agent having an average of at least two ethylenically unsaturated groups per molecule; (c) a hydrosilylation catalyst; (d) a silicone polyether polymer; and (e) particles to give a mixture;
hydrosilylating the (a) organohydrogensiloxane, the (b) crosslinking agent, and the (c) hydrosilylation catalyst in the presence of the (d) silicone polyether polymer and the (e) particles to give (A) a silicone elastomer having the (e) particles dispersed therein; and
combining the (A) silicone elastomer with (B) a carrier fluid to give the composition;
wherein the (b) crosslinking agent comprises an α,ω-unsaturated hydrocarbon or a polyoxyalkylene.

18. The method of claim 17 , further comprising shearing the composition to give a sheared paste composition, and optionally combining the sheared paste composition with an additional amount of the (B) carrier fluid.

19. A composition prepared in accordance with the method of claim 17 .

20. A gel paste prepared in accordance with the method of claim 18 .

Assignees

• Dow Silicones Corp

Inventors

• Li Zhi
• Maxon Bartley D
• Nguyen Kimmai T
• Pretzer Paul W
• Steinbrecher Kristen E
• Vanommeren Lisa M
• Waddell Evan
• Zhang Fang
• Zimmerman Kenneth E

Classifications

• A61K8/06

  Emulsions · CPC title

• A61K8/04

  Dispersions; Emulsions · CPC title

• A61Q5/00

  Preparations for care of the hair · CPC title

• A61K8/585

  Organosilicon compounds · CPC title

• A61K8/894 Primary

  modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol · CPC title