Nanocrystal production method, and steel production method

Patent metadata

Field	Value
Publication number	US-10927442-B2
Application number	US-201716329439-A
Country	US
Kind code	B2
Filing date	Aug 25, 2017
Priority date	Sep 1, 2016
Publication date	Feb 23, 2021
Grant date	Feb 23, 2021

Abstract

A nanocrystal production method includes a light irradiation step of applying light to a surface of a metal material immersed in water to form nanocrystals on the surface. In this nanocrystal production method, the metal material contains iron, the nanocrystal contains at least one of iron oxide and iron hydroxide, and in the spectrum of the light, a wavelength at which the intensity is maximum is not less than 360 nm and less than 620 nm.

First claim

The invention claimed is:

1. A nanocrystal production method comprising
a light irradiation step of applying light to a surface of a metal material immersed in water to form nanocrystals on the surface of the metal material,
wherein the metal material contains iron,
the nanocrystals contain at least one of iron oxide and iron hydroxide, and
in a spectrum of the light, a wavelength at which an intensity is maximum is not less than 360 nm and less than 620 nm.

2. The nanocrystal production method according to claim 1 , further comprising a surface roughening step of roughening the surface of the metal material before the light irradiation step.

3. The nanocrystal production method according to claim 2 , wherein the surface roughening step is performed by machining, chemical treatment, or discharge treatment in a liquid.

4. The nanocrystal production method according to claim 1 , wherein the metal material comprises pure iron or an iron alloy.

5. The nanocrystal production method according to claim 1 , wherein a content of the iron in the metal material is 10.0 to 100% by mass based on a total mass of the metal material.

6. The nanocrystal production method according to claim 1 , wherein the light is sunlight or simulated sunlight.

7. The nanocrystal production method according to claim 1 , wherein the water is at least one selected from the group consisting of pure water, ion exchange water, rain water, tap water, river water, well water, filtered water, distilled water, reverse osmosis water, mineral water, spring water, dam water, and sea water.

8. The nanocrystal production method according to claim 1 , wherein pH of the water is 5.00 to 10.0.

9. The nanocrystal production method according to claim 1 , wherein electrical conductivity of the water is 0.05 to 1.0 μS/cm.

10. The nanocrystal production method according to claim 1 , wherein a shape of the nanocrystals is at least one selected from the group consisting of a needle shape, a columnar shape, a rod shape, a tubular shape, a scaly shape, a lump shape, a flower shape, a starfish shape, a branch shape, and a convex shape.

11. The nanocrystal production method according to claim 1 , wherein a gas containing hydrogen is produced in the light irradiation step.

12. The nanocrystal production method according to claim 11 , wherein the number of moles of oxygen in the gas is not less than 0 times and less than 1/2 times the number of moles of the hydrogen.

13. The nanocrystal production method according to claim 1 , wherein the metal material comprises iron scrap.

14. A steel production method comprising:
a step of forming nanocrystals on the surface of the metal material by the nanocrystal production method according to claim 1 ;
a step of removing the nanocrystals from the surface of the metal material to recover the nanocrystals; and
a step of producing steel using the metal material from which the nanocrystals have been removed.

Assignees

• Hitachi Chemical Co Ltd
• Univ Hokkaido Nat Univ Corp
• Showa Denko Materials Co Ltd

Inventors

• Adachi Shuichiro
• Kitagawa Masaki
• Watanabe Seiichi
• Zhang Lihua
• Okinaka Noriyuki
• TAKAI Dai

Classifications

• B01J35/45

  Nanoparticles · CPC title

• C22C37/00

  Cast-iron alloys · CPC title

• C22C38/60

  containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur · CPC title

• C22C38/00

  Ferrous alloys, e.g. steel alloys (cast-iron alloys C22C37/00) · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title