Block copolymer for protecting parts made from metal

Patent metadata

Field	Value
Publication number	US-10927265-B2
Application number	US-201515513723-A
Country	US
Kind code	B2
Filing date	Sep 4, 2015
Priority date	Sep 24, 2014
Publication date	Feb 23, 2021
Grant date	Feb 23, 2021

Abstract

The invention relates to the use of a block copolymer comprising
at least one polyamide block and at least one polyolefin block to give to the metal-based material onto which it is applied adhesion and anti-corrosion properties.

Another subject of the invention is a block copolymer including
at least one polyamide block at least one polyolefin block and at least one alkylene block,

Its preparation process, a composition containing it and a process for using said composition.

First claim

The invention claimed is:

1. A block copolymer including:
at least one polyamide block,
at least one polyolefin block,
at least one alkylene block positioned between one of the at least one polyamide block and one of the at least one polyolefin block, and wherein the alkylene block is the result of polycondensation of fatty acid dimers, and

wherein the block copolymer has the following formula:
PA-(R-Pol-PA)n-R-Pol-R-PA,

where n is between 0 and 100,
PA denotes the polyamide block,
R denotes the alkylene block, and
Pol denotes the polyolefin block.

2. A block copolymer according to claim 1 , wherein at least one polyolefin block includes at least one polybutadiene.

3. A block copolymer according to claim 1 , wherein
the at least one polyamide block is present in an amount comprised between 2 and 98% by weight relative to the total weight of the block copolymer,
the at least one polyolefin block is present in an amount comprised between 2 and 98% by weight relative to the total weight of the block copolymer.

4. A block copolymer according to claim 1 , wherein the at least one alkylene block is present in an amount comprised between 0.1 and 25% by weight relative to the total weight of the block copolymer.

5. A block copolymer according to claim 1 further comprising at least one chain lengthener block.

6. A block copolymer according to claim 5 , wherein the at least one chain lengthener block is located at least one polyamide end of the block copolymer.

7. A preparation process for the copolymer as defined in claim 1 , including a step of mixing the different blocks.

8. A preparation process according to claim 7 , including the following successive steps:
a step of mixing polyolefin and alkylene blocks, the molar ratio between the polyolefin blocks and the alkylene blocks being greater than or equal to ½, then
a step of mixing polyamide blocks with the mixture obtained in the preceding step.

9. A preparation process according to claim 7 , comprising an extra step of mixing chain lengthener blocks with the mixture obtained in the preceding step.

10. A composition comprising at least one block copolymer as defined in claim 1 .

11. A composition according to claim 10 , wherein the composition is in the form of powder or granules.

12. A process of using the composition defined in claim 10 , comprising an injection, extrusion or spraying step.

13. A component comprising
at least one portion comprising metal and
a composition as defined in claim 10 ,

said composition being applied to said portion.

14. A component according to claim 13 , comprising a second portion, and wherein the composition is interposed and is in contact with both portions.

15. A component according to claim 13 , wherein the component is present in the form of a cable, a rope, a tube, a container, a film or a plate.

16. A method of transporting or storing fluid in vehicles, underwater (off-shore) or on-shore platforms, and/or cooling systems, using the component as defined in claim 13 .

17. A method according to claim 16 , wherein the fluid is chosen from an oil, a brake liquid, urea solutions, glycol-based cooling liquids, fuels, biofuels, biodiesels, potable water, waste water, gas, air, heat transfer fluids, oil and its derivatives.

Assignees

• Arkema France
• Michelin & Cie

Inventors

• Pineau Quentin

Classifications

• C09D153/00

  Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers · CPC title

• C09D5/08 Primary

  Anti-corrosive paints · CPC title

• C09D5/03

  Powdery paints · CPC title

• C08G81/028 Primary

  containing polyamide sequences · CPC title

• C09D187/005

  Block or graft polymers not provided for in groups C09D101/00 - C09D185/04 · CPC title