Polymer matrix composites comprising intumescent particles and methods of making the same

Patent metadata

Field	Value
Publication number	US-10927228-B2
Application number	US-201816191554-A
Country	US
Kind code	B2
Filing date	Nov 15, 2018
Priority date	Nov 16, 2017
Publication date	Feb 23, 2021
Grant date	Feb 23, 2021

Abstract

Polymer matrix composite comprising a porous polymeric network; and a plurality of intumescent particles distributed within the polymeric network structure; wherein the intumescent particles are present in a range from 15 to 99 weight percent, based on the total weight of the intumescent particles and the polymer (excluding the solvent); and wherein the polymer matrix composite volumetrically expands at least 2 times its initial volume when exposed to at least one temperature greater than 135° C.; and methods for making the same. The polymer matrix composites are useful, for example, as fillers, thermally initiated fuses, and fire stop devices.

First claim

What is claimed is:

1. A method of making a polymer matrix composite, the method comprising:
combining a thermoplastic polymer, a solvent, and a plurality of intumescent particles to provide a slurry;
forming the slurry into an article;
heating the article in an environment to retain at least 90 percent by weight of the solvent in the article, based on the weight of the solvent in the article, and solubilize at least 50 by weight percent of the thermoplastic polymer, based on the total weight of the thermoplastic polymer; and
inducing phase separation of the thermoplastic polymer from the solvent to provide the polymer matrix composite.

2. The method of claim 1 , wherein the intumescent particles are present in a range from 50 to 99 weight percent based on the total weight of the intumescent particles and the thermoplastic polymer.

3. The method of claim 1 , wherein the polymer in the slurry has a melting point, wherein the solvent has a boiling point, and wherein combining is conducted below the melting point of the polymer in the slurry, and below the boiling point of the solvent.

4. The method of claim 1 , wherein inducing phase separation includes thermally induced phase separation.

5. The method of claim 1 , wherein the polymer in the slurry has a melting point, and wherein inducing phase separation is conducted at less than the melting point of the polymer in the slurry.

6. The method of claim 1 , further comprising removing at least a portion of the solvent from the formed article after inducing phase separation of the thermoplastic polymer from the solvent.

7. The method of claim 1 , wherein no solvent is removed from the formed article.

8. The method of claim 1 , further comprising compressing the polymer matrix composite.

9. The method of claim 8 , further comprising applying vibratory energy to the polymer matrix composite simultaneously with compressing the polymer matrix composite.

10. A method of making the polymer matrix composite of claim 1 , the method comprising:
combining a thermoplastic polymer having a number average molecular weight from 5×10 6 to 8×10 6 g/mol, a solvent for the thermoplastic, and a plurality of intumescent particles to form a suspension of intumescent particles in a miscible thermoplastic polymer-solvent solution wherein the intumescent particles are present in a range from 50 to 98 weight percent based on the total weight of the intumescent particles and the thermoplastic polymer;
inducing phase separation of the thermoplastic polymer from the solvent; and
removing at least a portion of the solvent to provide the polymer matrix composite, wherein the polymer matrix composite volumetrically expands at least 2 times its initial volume when exposed to at least one temperature greater than 135° C.

11. The method of claim 10 , wherein the thermoplastic polymer comprises an ultra high molecular weight polyethylene.

12. The method of claim 10 , wherein the intumescent particles are present in a range from 75 to 98 weight percent based on the total weight of the intumescent particles and the thermoplastic polymer.

13. The method of claim 10 , wherein the intumescent particles comprise at least one of sodium silicate, intercalated graphite, aluminum hydroxide, magnesium hydroxide, ammonium polyphosphate, clay, or vermiculite.

14. The method of claim 10 , wherein inducing phase separation includes at least one of thermally induced phase separation or solvent induced phase separation.

15. The method of claim 10 , wherein the polymer in the miscible thermoplastic polymer-solvent solution has a melting point, and wherein inducing phase separation is conducted at less than the melting point of the polymer in the miscible thermoplastic polymer-solvent solution.

16. The method of claim 10 , further comprising forming the miscible thermoplastic polymer-solvent solution into an article; and then inducing phase separation.

17. The method of claim 10 , further comprising compressing the polymer matrix composite.

18. The method of claim 17 , further comprising applying vibratory energy to the polymer matrix composite simultaneously with compressing the polymer matrix composite.

Assignees

• 3M Innovative Properties Co

Inventors

• Acharya Bharat R
• Bartling Brandon A
• Dehn Derek J
• Hines Paul T
• Waller Jr Clinton P
• Nayar Satinder K

Classifications

• C08J3/203 Primary

  Solid polymers with solid and/or liquid additives · CPC title

• C08J3/212

  and solid additives · CPC title

• C08J2323/06

  Polyethene · CPC title

• C08J9/0066 Primary

  Use of inorganic compounding ingredients · CPC title

• C08K2003/2227

  of aluminium · CPC title