Process for preparing polymers

Patent metadata

Field	Value
Publication number	US-10927217-B2
Application number	US-201916283001-A
Country	US
Kind code	B2
Filing date	Feb 22, 2019
Priority date	Feb 23, 2018
Publication date	Feb 23, 2021
Grant date	Feb 23, 2021

Abstract

The present disclosure relates to a process for preparing polymers using a plug flow reactor. The process includes providing an aqueous monomer solution comprising amide monomers; evaporating the aqueous monomer solution to form a concentrated monomer solution; and polymerizing the concentrated monomer solution in a plug flow reactor comprising a shell side and a tube side to form a first process fluid comprising polymers. The concentrated monomer solution flows on the shell side from the inlet to the outlet.

First claim

We claim:

1. A process for preparing polyamides, the process comprising:
providing an aqueous monomer solution comprising amide monomers;
evaporating the aqueous monomer solution to form a concentrated monomer solution; and
polymerizing the concentrated monomer solution in a plug flow reactor comprising a shell side and a tube side to form a first process fluid comprising polyamides, wherein the shell side comprises an inlet and an outlet,
wherein the concentrated monomer solution flows on the shell side from the inlet to the outlet.

2. The process of claim 1 , wherein the tube side comprises a plurality of U-tubes each including an inlet and an outlet for conveying a heating fluid therethrough, and wherein the tube side has a heat transfer area, and wherein the heating fluid has a specific enthalpy, H value at atmospheric pressure, less than 2,900 kJ/kg.

3. The process of claim 2 , wherein a ratio of the heat transfer area (ft 2 ) to a total volume (ft 3 ) of the concentrated monomer solution ranges from 3:1 to 30:1.

4. The process of claim 2 , wherein a ratio of the heat transfer area (ft 2 ) to a total volume (ft 3 ) of heat transfer fluid ranges from 5:1 to 200:1.

5. The process of claim 2 , wherein a skin temperature of the plug flow reactor is less than 290° C.

6. The process of claim 1 , wherein the process has a heat flux rate less than 11400 BTU/hr-ft 2 .

7. The process of claim 1 , wherein a residence time distribution varies by +/−8%, based on an average residence time.

8. The process of claim 1 , wherein conversion of amide monomer to polyamides is at least 85%.

9. The process of claim 1 , further comprising:
separating water from the concentrated monomer solution to form a water vapor during polymerization; and
supplying the water vapor to a disengagement region of the plug flow reactor.

10. The process of claim 9 wherein the disengagement region has a height of at least 0.05 m.

11. The process of claim 10 , wherein the vapor stream comprises less than 15.0×10 −7 wt % of entrained liquid.

12. A process for retrofitting a polycondensation process including an existing evaporator for concentrating a monomer solution and an existing reactor for forming polyamides, the process comprising:
polymerizing the concentrated monomer solution in a plug flow reactor comprising a shell side and a tube side to form a first process fluid, wherein the shell side has an inlet and an outlet;
feeding the first process fluid to the existing reactor; and
polymerizing the first process fluid to form a second process fluid,
wherein the monomer solution flows on a shell side from the inlet to the outlet.

13. The process of claim 12 , wherein the plug flow reactor and the existing reactor are arranged in series.

14. The process of claim 12 , wherein the tube side comprises a plurality of U-tubes each comprising an inlet and an outlet for conveying a heating fluid therethrough, and wherein the tube side has a heat transfer area, and wherein the heating fluid has a specific enthalpy, H value at atmospheric pressure, less than 2,900 kJ/kg.

15. The process of claim 12 , wherein a ratio of the heat transfer area to a total volume of the concentrated monomer solution is in a range from 3:1 to 30:1.

16. The process of claim 12 , wherein a ratio of the heat transfer area to a total volume of heat transfer fluid is in a range from 5:1 to 200:1.

17. A system for preparing polymers, comprising:
a vessel including an aqueous monomer solution;
an evaporator for concentrating the aqueous monomer solution to form a concentrated monomer solution;
a plug flow reactor comprising a shell side and a tube side for polymerizing the concentrated monomer solution to form polyamides, wherein the shell side comprises an inlet and an outlet, and
wherein the concentrated monomer solution flows on a shell side from the inlet to the outlet.

18. The system of claim 17 , wherein the tube side comprises a plurality of U-tubes comprising an inlet and an outlet for conveying a heating fluid therethrough, and wherein the tube side has a heat transfer area.

19. The system of claim 17 , further comprising a second reactor downstream from the plug flow reactor, wherein the plug flow reactor and second reactor are arranged in series.

20. A process for preparing polyamides in a plug flow reactor, the process comprising:
selecting a desired first process fluid molecular weight in a range between 700 g/mol and 150,000 g/mol;
providing an aqueous monomer solution comprising amide monomers;
evaporating the aqueous monomer solution to form a concentrated monomer solution;
polymerizing the concentrated monomer solution in a plug flow reactor comprising a shell side and a tube side to form a first process fluid comprising polyamides,
controlling a heat flux rate of the process to be less than 11400 BTU/hr-ft 2 ; and
maintaining a residence time of a concentrated monomer solution in the plug flow reactor from 2 minutes to 100 minutes;
wherein the residence time distribution varies by +/−4%; or
wherein the first process fluid molecular weight corresponds to the desired first process fluid molecular weight.

Assignees

• Ascend Performance Mat Operations Llc

Inventors

• Sutton James P
• Zabcik John M
• Schwier Chris
• Uzunpinar Cihan
• Akbari Shahram

Classifications

• B01J2219/00768

  vertical · CPC title

• B01J19/006

  Baffles · CPC title

• C08G69/28 Primary

  Preparatory processes · CPC title

• B01J2219/182

  horizontal · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title